Organic electroluminescent materials and devices

    公开(公告)号:US10608186B2

    公开(公告)日:2020-03-31

    申请号:US15684411

    申请日:2017-08-23

    IPC分类号: H01L51/00 H01L51/50

    摘要: A composition comprising a first compound capable of functioning as a phosphorescent emitter in an organic light emitting device at room temperature is provided. The first compound includes at least one substituent R, where each of the at least one substituent R has the formula of: - - -G1-G2, where the dashed line denotes the bond through which R is attached in the first compound; G1 is a non-aromatic cyclic or polycyclic group; G2 is selected from aryl and heteroaryl; and G1 and G2 are independently, optionally further substituted with a substituent selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof. Organic light emitting devices, consumer products, and formulations containing the first compound are also provided.

    Organic electroluminescent materials and devices

    公开(公告)号:US10043987B2

    公开(公告)日:2018-08-07

    申请号:US14805693

    申请日:2015-07-22

    摘要: A compound having a structure according Formula Ir(LA)n(LB)3−n: is described. In the structure of Formula Ir(LA)n(LB)3−n: A1, A2, A3, A4, A5, A6, A7, and A8 are each carbon or nitrogen; at least one of A1, A2, A3, A4, A5, A6, A7, and A8 is nitrogen; ring B is bonded to ring A through a C—C bond; the iridium is bonded to ring A through an Ir—C bond; X is O, S, or Se; R1, R2, R3, and R4 each independently represent no substitutions up to the maximum possible substitutions; any adjacent substitutions in R1, R2, R3, and R4 are optionally linked together to form a ring; each R1, R2, R3, R4, and R5 is independently selected from a variety of substituents; and n is an integer from 1 to 2. Formulations and devices, such as an OLEDs, that include the compound of Formula Ir(LA)n(LB)3−n are also described.

    Organic electroluminescent materials and devices

    公开(公告)号:US11535797B2

    公开(公告)日:2022-12-27

    申请号:US17117901

    申请日:2020-12-10

    摘要: A compound having a Pt tetradentate structure of Formula 1, is provided. In the structure of Formula 1, rings C and D each independently represent 5- or 6-membered carbocyclic or heterocyclic ring; L1, L2, and L3 are each independently a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2, SiRR′, GeRR′, alkyl, cycloalkyl, or a combination thereof; the sum of n1 and n2 is 1 or 2; X is selected from NRE, O, S, and Se; X3 and X4 each independently carbon or nitrogen; and one of Q1, Q3, and Q4 is oxygen, and the remaining two of Q1, Q3, and Q4 each represents a direct bond. Formulations and devices, such as an OLEDs, that include the compound of Formula 1 are also described.

    Organic electroluminescent materials and devices

    公开(公告)号:US10236456B2

    公开(公告)日:2019-03-19

    申请号:US15468469

    申请日:2017-03-24

    摘要: A compound that includes a ligand L, having the formula, is provided. In the structure of Formula I, each R1, R2, R3, R4, R4, R5, R6, R7, and R8 is independently selected from a variety of substituents; any adjacent substituents are optionally joined or fused into a ring; at least one of R3, R4, and R5 is not hydrogen; “a” is an integer from 0 to 10; (i) when a is 0, at least one of R7, R8, and an R2 adjacent to ring B, is not hydrogen, and (ii) when a is 1 to 10, at least one of an R2 adjacent to ring A and an R6 adjacent to ring C is not hydrogen; ligand L is coordinated to a metal M having an atomic weight greater than 40; and ligand L is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.