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公开(公告)号：US12029108B2
公开(公告)日：2024-07-02
申请号：US17232764
申请日：2021-04-16
发明人： Bin Ma , Walter Yeager , Edward Barron , Alan Deangelis , Chuanjun Xia , Vadim Adamovich , Scott Beers , Harvey Wendt , Suman Layek
IPC分类号： C07F15/00 , C09K11/06 , H10K50/11 , H10K50/16 , H10K50/18 , H10K85/30 , H10K85/40 , H10K85/60 , H10K101/10
CPC分类号： H10K85/342 , C07F15/0033 , C09K11/06 , H10K85/40 , H10K85/622 , H10K85/654 , H10K85/6572 , H10K85/6576 , C09K2211/1029 , C09K2211/1033 , C09K2211/185 , H10K50/11 , H10K50/16 , H10K50/18 , H10K2101/10
摘要： A compound having the formula Ir(LA)n(LB)3-n is disclosed wherein LA is an aza-DBF ligand and LB is an alkyl-substituted phenylpyridine ligand, wherein the compound has a structure according to Formula I:
wherein each of A1 to A8 comprise carbon or nitrogen; wherein at least one of A1 to A8 is nitrogen; wherein ring B is bonded to ring A through a C—C bond; wherein the iridium is bonded to ring A through a Ir—C bond; wherein X is O, S, or Se; wherein R′ and R″ each independently represent mono-, di-substitution, or no substitution; wherein any adjacent substitutions in R′, R″, R1, R2, R3, R4, R5, and R6 are optionally linked together to form a ring; wherein R1, R2, R′, and R″ are each independently selected from a variety of substituents; wherein R3, R4, R5, and R6 are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, and combinations thereof; wherein n is an integer from 1 to 3; and wherein total number of carbons in at least one of the pairs R3 and R4, and R5 and R6 is at least four.-
公开(公告)号：US11342515B2
公开(公告)日：2022-05-24
申请号：US16734845
申请日：2020-01-06
发明人： Lichang Zeng , Suman Layek , Chuanjun Xia , Zhiqiang Ji , Edward Barron
摘要： Ligands with fused spirocyclic substitutions and metal complexes formed with such ligands and having improved performance in OLED applications are disclosed.
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公开(公告)号：US11276829B2
公开(公告)日：2022-03-15
申请号：US15706118
申请日：2017-09-15
摘要： A compound having a first ligand LA having the Formula: Formula I is disclosed, wherein rings A is a 5- or 6-membered carbocyclic or heterocyclic ring; wherein RA and RB each independently represent mono to the possible maximum number of substitution, or no substitution; wherein Z1 is carbon or nitrogen; wherein each RA and RB is independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein any two substituents are optionally joined or fused into a ring; wherein X1 to X4 each independently represent a carbon or nitrogen; wherein at least one of X1 to X4 is nitrogen; wherein the ligand LA is coordinated to a metal M; wherein the metal M can be coordinated to other ligands; and wherein the ligand LA is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.
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公开(公告)号：US10355227B2
公开(公告)日：2019-07-16
申请号：US14450865
申请日：2014-08-04
发明人： Bin Ma , Edward Barron , Alan Deangelis , Walter Yeager , Zeinab Elshenawy , Harvey Wendt , Ting-Chih Wang , Kwang-Ohk Cheon , Chuanjun Xia
摘要： The present disclosure relates to novel iridium complexes that can be used in organic light emitting devices (OLEDs). The present disclosure also relates to devices and formulations that incorporate the iridium complexes. The iridium complex can be a compound having the formula (LA)mIr(LB)3-m (I); wherein LA is and wherein LB can be one of:
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公开(公告)号：US10144867B2
公开(公告)日：2018-12-04
申请号：US15013559
申请日：2016-02-02
发明人： Bin Ma , Mingjuan Su , Alan Deangelis , Edward Barron , Chuanjun Xia
摘要： A compound having a Pt tetradentate structure selected from the group consisting of is provided. In the structures of Formula 1 and Formula 2, rings C and D each independently represent 5- or 6-membered carbocyclic or heterocyclic ring; L1, L2, and L3 are each independently a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2, SiRR′, GeRR′, alkyl, cycloalkyl, or a combination thereof; the sum of n1 and n2 is 1 or 2; X is selected from NRE, O, S, and Se; X3 and X4 each independently carbon or nitrogen; and one of Q1, Q3, and Q4 is oxygen, and the remaining two of Q1, Q3, and Q4 each represents a direct bond. Formulations and devices, such as an OLEDs, that include the compound of Formulas 1 and 2 are also described.
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公开(公告)号：US10008678B2
公开(公告)日：2018-06-26
申请号：US14330351
申请日：2014-07-14
发明人： Jui-Yi Tsai , Walter Yeager , Jason Brooks , Scott Beers , Gregory S. Kottas , Edward Barron , Raymond Kwong
CPC分类号： H01L51/0085 , C07F15/0033 , C09K11/06 , C09K2211/1044 , C09K2211/1048 , C09K2211/1051 , C09K2211/185 , H01L51/0072 , H01L51/0074 , H01L51/5016 , H05B33/14
摘要： Imidazo[1,2-f]phenanthridine compounds are provided. The compounds have a twisted aryl moiety further substituted by alkyl having four or more atoms. The compounds may be used in organic light emitting devices, particularly as emissive dopants, providing devices with improved efficiency, stability, and manufacturing. In particular, the compounds provided herein may be used in blue devices having high efficiency.
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公开(公告)号：US09761807B2
公开(公告)日：2017-09-12
申请号：US14174396
申请日：2014-02-06
发明人： Bin Ma , Walter Yeager , Edward Barron , Kwang-Ohk Cheon , Lichang Zeng , Chuanjun Xia
IPC分类号： H01L51/50 , H01L51/00 , C07D405/10 , C07D409/04 , C07D409/10 , C07D409/14
CPC分类号： H01L51/0054 , C07D405/10 , C07D409/04 , C07D409/10 , C07D409/14 , H01L51/0072 , H01L51/0073 , H01L51/0074 , H01L51/0081 , H01L51/0085 , H01L51/5016
摘要： The present invention relates to novel organic compounds containing a triphenylene and a carbazole. The compounds are useful for organic light-emitting diodes. The compounds are also useful for charge-transport and charge-blocking layers, and as hosts in the light-emissive layer for organic light emitting devices (OLEDs).
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公开(公告)号：US11825734B2
公开(公告)日：2023-11-21
申请号：US17711313
申请日：2022-04-01
发明人： Lichang Zeng , Suman Layek , Chuanjun Xia , Zhiqiang Ji , Edward Barron
IPC分类号： H10K85/30 , C09K11/07 , H10K85/40 , H10K85/60 , C07F15/00 , C09K11/02 , C09K11/06 , H10K50/11 , H10K101/10
CPC分类号： H10K85/342 , C07F15/0033 , C09K11/025 , C09K11/06 , C09K11/07 , H10K85/40 , H10K85/615 , H10K85/622 , H10K85/626 , H10K85/654 , H10K85/657 , H10K85/6572 , H10K85/6576 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1059 , C09K2211/1088 , C09K2211/1092 , C09K2211/185 , H10K50/11 , H10K2101/10
摘要： Ligands with fused spirocyclic substitutions and metal complexes formed with such ligands and having improved performance in OLED applications are disclosed.
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公开(公告)号：US11795385B2
公开(公告)日：2023-10-24
申请号：US17982828
申请日：2022-11-08
发明人： Bin Ma , Mingjuan Su , Alan Deangelis , Edward Barron , Chuanjun Xia
CPC分类号： C09K11/025 , C07F15/0033 , C07F15/0086 , C09K11/06 , H05B33/14 , H10K85/346 , C09K2211/1007 , C09K2211/1029 , C09K2211/1033 , C09K2211/1044 , C09K2211/185 , H10K85/626 , H10K85/654 , H10K85/6572
摘要： A compound having a Pt tetradentate structure of Formula 1,
is provided. In the structure of Formula 1, rings C and D each independently represent 5- or 6-membered carbocyclic or heterocyclic ring; L1, L2, and L3 are each independently a direct bond, BR, NR, PR, O, S, Se, C═O, S═O, SO2, SiRR′, GeRR′, alkyl, cycloalkyl, or a combination thereof; the sum of n1 and n2 is 1 or 2; X is selected from NRE, O, S, and Se; X3 and X4 each independently carbon or nitrogen; and one of Q1, Q3, and Q4 is oxygen, and the remaining two of Q1, Q3, and Q4 each represents a direct bond. Formulations and devices, such as an OLEDs, that include the compound of Formula 1 are also described.-
公开(公告)号：US11605789B2
公开(公告)日：2023-03-14
申请号：US16438819
申请日：2019-06-12
发明人： Chuanjun Xia , Chun Lin , Pierre-Luc T. Boudreault , Jui-Yi Tsai , Mingjuan Su , Lichang Zeng , Zhiqiang Ji , Edward Barron , Walter Yeager , Alexey Borisovich Dyatkin
摘要： A composition including a first compound capable of functioning as a phosphorescent emitter in an OLED is provided. The first compound has at least one aromatic ring and at least one substituent R directly bonded to one of the at least one aromatic rings. Each substituent R has the formula of where (a) G1 is selected from NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; and G2 is a non-aromatic polycyclic group; (b) G1 is a direct bond; and G2 is a non-aromatic spiro polycyclic group; or (c) G1 is selected from direct bond, NR1, SiR1R2, GeR1R2, alkyl, cycloalkyl, and combinations thereof; G2 is a non-aromatic polycyclic group; and R is directly bonded to a phenyl, pyridine, or triazine. R1, R2, and R3 are a variety of substituents. Formulations and devices, such as an OLEDs, that include the first compound are also described.
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