Addition of severely-hindered amine salts and/or aminoacids to
non-hindered amine solutions for the absorption of H.sub.2 S
    28.
    发明授权
    Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H.sub.2 S 失效
    向非受阻胺溶液中加入严重受阻的胺盐和/或氨基酸以吸收H2S

    公开(公告)号:US4892674A

    公开(公告)日:1990-01-09

    申请号:US106805

    申请日:1987-10-13

    IPC分类号: B01D53/14

    CPC分类号: B01D53/1493

    摘要: A new alkaline absorbent solution containing the additive of a severely-hindered amine salt and/or a severely-hindered aminoacid to a non-hindered amine such as N-methyldiethanolamine (MDEA) is provided. A process for the removal of H.sub.2 S from fluid mixtures using this absorbent solution to produce a very low level of H.sub.2 S in the treated fluid is also provided. The process is also suitable for the selective removal of H.sub.2 S from fluid mixtures comprising H.sub.2 S and CO.sub.2. Use of the above absorbent solution leads to higher selectivity for H.sub.2 S than observed when MDEA is used alone without the additives.

    摘要翻译: 提供了将含有严重受阻胺盐和/或严重受阻氨基酸的添加剂添加到非受阻胺如N-甲基二乙醇胺(MDEA)的新型碱性吸收剂溶液。 还提供了使用该吸收剂溶液从流体混合物中除去H 2 S以在处理过的流体中产生非常低水平的H 2 S的方法。 该方法也适用于从包含H 2 S和CO 2的流体混合物中选择性除去H 2 S. 使用上述吸收剂溶液导致对于H 2 S的选择性高于当单独使用MDEA而没有添加剂时所观察到的选择性。

    Process for neutralization of petroleum acids
    29.
    发明授权
    Process for neutralization of petroleum acids 失效
    中和石油酸的工艺

    公开(公告)号:US5683626A

    公开(公告)日:1997-11-04

    申请号:US519555

    申请日:1995-08-25

    IPC分类号: C10G19/073 C09K3/00 C09K15/00

    CPC分类号: C10G19/073 Y10S507/939

    摘要: The invention relates to a process for treating naphthenic acid--containing whole crudes or fractions thereof to reduce or eliminate their acidity by contacting the acidic whole crude or fraction at a temperature of from about 50.degree. C. to 350.degree. C. with a neutralizing amount of tetraalkylammonium hydroxide, preferably tetramethyl-ammonium hydroxide. The process has the additional benefits of reducing materials handling problems associated with treating oils using liquid solvents and in reducing emulsion formation.

    摘要翻译: 本发明涉及一种用于处理含环烷酸的整个原油或其馏分以通过使酸性全部原料或馏分在约50℃至350℃的温度下以中和量接触来降低或消除其酸度的方法 的四烷基氢氧化铵,优选四甲基氢氧化铵。 该方法具有减少与使用液体溶剂处理油和减少乳液形成相关的材料处理问题的附加益处。