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公开(公告)号：US4487967A
公开(公告)日：1984-12-11
申请号：US565097
申请日：1983-12-23
IPC分类号： B01J23/00 , B01J23/40 , B01J23/74 , C07B61/00 , C07C20060101 , C07C67/00 , C07C213/00 , C07C213/02 , C07C217/08 , C07C217/44 , C07C85/00 , C07C85/02
CPC分类号： C07C213/02
摘要： The present invention relates to a process for selectively preparing severely sterically hindered secondary aminoether alcohols by reacting a primary amino compound with a polyalkenyl ether glycol in the presence of a hydrogenation catalyst at elevated temperatures and pressures. The severely sterically hindered secondary aminoether alcohols are useful in acid gas scrubbing processes, particularly in the selective removal of H.sub.2 S from gaseous streams containing CO.sub.2 and H.sub.2 S.
摘要翻译： 本发明涉及通过在氢化催化剂的存在下在高温和高压下使伯氨基化合物与聚链烯基醚二醇反应来选择性地制备严格位阻的仲氨基醚醇的方法。 严格的空间位阻仲氨基醚醇可用于酸性气体洗涤过程，特别是从含CO 2和H 2 S的气流中选择性除去H 2 S。
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2.发明授权Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H.sub.2 S 失效含有用于吸收H 2 S的胺盐和/或氨基酸添加剂的严重受阻胺混合物的吸收剂组合物
公开(公告)号：US4961873A
公开(公告)日：1990-10-09
申请号：US398346
申请日：1989-08-24
IPC分类号： B01D53/14
CPC分类号： B01D53/1493
摘要： The present invention relates to a new alkaline absorbent solution that reduces the H.sub.2 S content in a treated gas to below 10 vppm. The absorbent solution contains two severely-hindered amines, such as bis(tertiarybutylaminoethoxy)-ethane (BTEE) and ethoxyethoxyethanol-tertiarybutylamine (EEETB), a severely hindered amine salt, and/or a severely hindered aminoacid. This invention also describes a process for the removal of H.sub.2 S from fluid mixtures using this absorbent solution to produce a very low level of H.sub.2 S in the treated fluid. The process is also suitable for the selective removal of H.sub.2 S from fluid mixtures comprising H.sub.2 S and CO.sub.2.
摘要翻译： 本发明涉及一种将处理气体中的H 2 S含量降低至低于10vppm的新的碱性吸收剂溶液。 吸收剂溶液含有两种严重受阻胺，如双（叔丁基氨基乙氧基） - 乙烷（BTEE）和乙氧基乙氧基乙醇 - 叔丁胺（EEETB），严重受阻胺盐和/或严重受阻的氨基酸。 本发明还描述了一种使用该吸收剂溶液从流体混合物中除去H 2 S的方法，以在处理过的流体中产生非常低水平的H 2 S. 该方法也适用于从包含H 2 S和CO 2的流体混合物中选择性除去H 2 S.
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3.发明授权Absorbent composition containing severely-hindered amine mixture for the absorption of H.sub.2 S 失效含有严重受阻胺混合物以吸收H 2 S的吸收剂组合物
公开(公告)号：US4894178A
公开(公告)日：1990-01-16
申请号：US106796
申请日：1987-10-13
IPC分类号： B01D53/14 , C07C217/08
CPC分类号： B01D53/1493 , C07C217/08
摘要： The present invention relates to a mixture of severely-hindered amines, such as bis-(tertiarybutylaminoethoxy)-ethane (BTEE) and ethoxyethoxyethanoltertiarybutylamine (EEETB), and a one-step synthesis method for its preparation. Besides, this invention describes the use of the mixture for the removal of H.sub.2 S, especially the selective removal of H.sub.2 S in the presence of CO.sub.2.
摘要翻译： 本发明涉及双（叔丁基氨基乙氧基） - 乙烷（BTEE）和乙氧基乙氧基乙醇叔丁胺（EEETB）等严重受阻胺的混合物及其制备的一步合成方法。 此外，本发明描述了混合物用于除去H 2 S的用途，特别是在CO 2存在下选择性除去H 2 S.
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公开(公告)号：US4405811A
公开(公告)日：1983-09-20
申请号：US339881
申请日：1982-01-18
申请人： Eugene L. Stogryn , Guido Sartori
发明人： Eugene L. Stogryn , Guido Sartori
IPC分类号： C10L3/10 , B01D53/14 , C07C67/00 , C07C213/00 , C07C215/06 , C07C217/08 , C10K1/10 , C07C91/10 , C07C91/04 , C07C91/12 , C07C93/04
CPC分类号： B01D53/1493
摘要： A novel class of severely sterically hindered tertiary amino compounds having a pK.sub.a value at 20.degree. C. greater than 8.6, preferably ranging from 9.3 to about 10.6, and a cumulative -E.sub.s value of at least 1.9 are found to be useful in selective removal of H.sub.2 S from a normally gaseous mixture containing H.sub.2 S and CO.sub.2.
摘要翻译： 发现一类新的具有pKa值在20℃，大于8.6，优选9.3至约10.6，累积-E值至少为1.9的叔氨基化合物可用于选择性除去 来自含有H 2 S和CO 2的常态气体混合物的H 2 S.
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5.发明授权Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary amino compounds 失效从具有严格位阻的仲氨基化合物的气态混合物中选择性除去硫化氢的方法
公开(公告)号：US4405581A
公开(公告)日：1983-09-20
申请号：US339901
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a severely sterically hindered secondary amino compound having a cumulative .sup.- E.sub.s value (Taft's steric hindrance constant) greater than about 1.75 whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含具有大于约1.75的累积-E值（塔夫脱空位阻抗常数）的严重空间位阻的仲氨基化合物的吸收剂溶液接触来实现从含有H 2 S和CO 2的常规气态混合物中选择性除去H 2 S气体。 从而从混合物中选择性地吸收H2S。
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6.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 with tertiary amino azabicyclic alcohols 失效从含有H 2 S和CO 2的混合物中选择性除去H 2 S与叔氨基氮杂双环醇的方法
公开(公告)号：US4405580A
公开(公告)日：1983-09-20
申请号：US339898
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a tertiary amino azabicyclic alcohol whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气态混合物与包含叔氨基氮杂二醇的吸收剂溶液接触，从而从混合物中选择性吸收H 2 S，可以将H2S气体从含有H 2 S和CO 2的常规气态混合物中选择性地除去。
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7.发明授权Process for the selective removal of hydrogen sulfide from gaseous mixtures with severely sterically hindered secondary aminoether alcohols 失效从具有严格位阻的仲氨基醚醇的气态混合物中选择性除去硫化氢的方法
公开(公告)号：US4405585A
公开(公告)日：1983-09-20
申请号：US339891
申请日：1982-01-18
CPC分类号： B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a severely sterically hindered secondary aminoether alcohol having a cumulative .sup.- -E.sub.s value (Taft's steric hindrance constant) greater than about 1.75 whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含严重空间位阻的仲氨基醚醇的吸收剂溶液接触来实现H 2 S气体的选择性除去，该混合物的累积-E值（塔夫脱的空间位阻常数）大于约 从而从混合物中选择性地吸收H2S。
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8.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 using di-severely sterically hindered secondary aminoethers 失效使用二重立体位阻仲氨基醚从含有H 2 S和CO 2的混合物中选择性除去H 2 S的方法
公开(公告)号：US4405583A
公开(公告)日：1983-09-20
申请号：US339900
申请日：1982-01-18
IPC分类号： B01D53/14 , C07D295/088 , B01D53/34 , C09K3/00
CPC分类号： C07D295/088 , B01D53/1468 , B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a di-secondary aminoether wherein each amino group has a severely sterically hindered secondary amino moiety whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气体混合物与包含二仲氨基醚的吸收剂溶液接触来实现从含有H 2 S和CO 2的常规气态混合物中选择性除去H 2 S气体，其中每个氨基具有严格位阻的仲氨基部分，由此H 2 S从 混合物。
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9.发明授权Process for selective removal of H.sub.2 S from mixtures containing H.sub.2 .sub.2 using diaminoether solutions 失效使用二氨基醚溶液从含有H 2 S和CO 2的混合物中选择性除去H 2 S的方法
公开(公告)号：US4405582A
公开(公告)日：1983-09-20
申请号：US339883
申请日：1982-01-18
IPC分类号： B01D53/52 , B01D53/14 , B01D53/77 , C07C67/00 , C07C213/00 , C07C217/08 , C07D207/06 , C07D295/08 , C07D295/088 , C10K1/14 , B01D53/34 , C09K3/00
CPC分类号： C07D295/088 , B01D53/1468 , B01D53/1493
摘要： The selective removal of H.sub.2 S gas from a normally gaseous mixture containing H.sub.2 S and CO.sub.2 is accomplished by contacting the gaseous mixture with an absorbent solution comprising a diaminoether wherein at least one amino group is a tertiary amine whereby H.sub.2 S is selectively absorbed from the mixture.
摘要翻译： 通过将气态混合物与包含二氨基醚的吸收剂溶液接触，其中至少一个氨基是叔胺，从而从混合物中选择性地吸收H 2 S，从而将H 2 S气体从含有H 2 S和CO 2的常规气态混合物中选择性地除去。
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公开(公告)号：US4762934A
公开(公告)日：1988-08-09
申请号：US567569
申请日：1984-01-03
申请人： Eugene L. Stogryn , Guido Sartori
发明人： Eugene L. Stogryn , Guido Sartori
IPC分类号： B01D53/14 , C07D295/088 , C07D211/14 , C07D207/08 , C07D223/04 , C07D225/02
CPC分类号： C07D295/088 , B01D53/1468 , B01D53/1493
摘要： A novel class of diaminoether compounds wherein one amino group thereof is a tertiary amine in N-heterocyclic form and the other amino group is a severely sterically hindered secondary amino group may be prepared by a three-step process and are useful in the selective removal of H.sub.2 S from mixtures containing H.sub.2 S and CO.sub.2.
摘要翻译： 一类新的二氨基醚化合物，其中一个氨基是N-杂环形式的叔胺，另一个氨基是严格位阻的仲氨基，可以通过三步法制备，可用于选择性除去 来自含H2S和CO2混合物的H2S。
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