摘要:
The present invention relates to a process for selectively preparing severely sterically hindered secondary aminoether alcohols by reacting a primary amino compound with a polyalkenyl ether glycol in the presence of a hydrogenation catalyst at elevated temperatures and pressures. The severely sterically hindered secondary aminoether alcohols are useful in acid gas scrubbing processes, particularly in the selective removal of H.sub.2 S from gaseous streams containing CO.sub.2 and H.sub.2 S.
摘要:
Disclosed is a process for producing di-amino-polyalkenyl ethers by reacting (a) one or more acyclic or heterocyclic amino compounds with (b) one or more polyalkenyl ether glycols or polyalkenyl amino ether alcohols, in the presence of a hydrogenation catalyst, at elevated temperatures and pressures.
摘要:
The conversion of hydrocarbons in the presence of hydrogen occurs under hydrocarbon conversion conditions in the presence of a subgroup of a certain class of metal-substituted semi-crystalline aluminosilicates which are synthetic and which are predominantly ordered in two directions, that is, which are laminar or have a layered or stacked sheet structure. The metal substituted for the aluminum in the trioctahedral sites is nickel, cobalt, or mixtures thereof. The catalysts are preferably used in hydroisomerization and hydrocracking processes.
摘要:
A process for the hydrodesulfurization of hydrocarbons employing a catalyst comprising Group VI and Group VIII metals supported on alumina and promoted with a minor amount of a Group IV-B metal. The process is particularly advantageous in the treatment of stocks containing substantial quantities of residual components, asphaltic materials and metalliferous contaminants, specifically stocks, such as, residual stocks.
摘要:
The conversion of hydrocarbons in the presence of hydrogen occurs under hydrocarbon conversion conditions in the presence of a subgroup of a certain class of metal-substituted semi-crystalline aluminosilicates which are synthetic and which are predominantly ordered in two directions, that is, which are laminar or have a layered or stacked sheet structure. The metal substituted for the aluminum in the trioctahedral sites is nickel, cobalt, or mixtures thereof. Hydrocarbon conversion catalysts are also claimed comprising the metal-substituted laminar 2:1 layer lattice aluminosilicate minerals containing in addition a hydrogenation component such as palladium. The catalysts are preferably used in hydroisomerization and hydrocracking processes.
摘要:
A two-stage process for hydrodesulfurization of a metal-containing hydrocarbon oil employing a hydrodesulfurization catalyst in the second stage having an activated support prepared by drying and calcining a crystalline alumina containing 1.2 to 2.6 mols of water of hydration per mol of alumina.
摘要:
A composition of matter comprising a mixture of (i) a sulfide of at least one promoter metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixtures thereof with Fe, (ii) an amorphous sulfide of trivalent chromium and (iii) microcrystallites of metal sulfide of a metal selected from the group consisting of molybdenum, tungsten and mixture thereof. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as cobalt-molybdate on alumina.
摘要:
Disclosed is a method for preparing dual colloid catalyst compositions wherein a gel, or colloidal suspension is formed by admixing (a) a 0.6 to 10M aqueous solution containing one or more soluble salts or complexes of one or more transition metals, wherein at least one of the transition metals is reducible and hydrolyzable, and one or more elements selected from Cr, Al, Si, Th, U, the lanthanides, and elements from Groups IA and IIA of the Periodic Table of the Elements, with (b) a 0.5 to 10N aqueous base solution. The solid material is separated from the resulting gel, or colloidal suspension and washed and dried.
摘要:
The use of relatively stable iron carbonyl complexes e.g. Bis(dicarbonylcyclopentadienyliron), and lower melting cobalt carbonyl complexes, facilitates production of mixed metal catalysts for conversion of CO/H.sub.2 to alpha-olefins. The decomposition of these materials can be achieved in a controlled manner resulting in an excellent alpha-olefins synthesis catalyst in Fischer-Tropsch processes.
摘要翻译:使用相对稳定的羰基络合物,例如 双(二羰基环戊二烯基锡)和较低熔点的羰基钴配合物有助于生产用于将CO / H 2转化为α-烯烃的混合金属催化剂。 这些材料的分解可以以受控的方式实现,从而在费 - 托工艺中产生优异的α-烯烃合成催化剂。
摘要:
A process comprising passing a residual oil through a plurality of hydrodesulfurization stages in series to produce a relatively low sulfur hydrodesulfurizer residual oil effluent. A portion of desulfurized oil flowing between stages is passed through a thermal cracking zone containing a packed bed of inert solids to produce middle distillates and a cracked residual oil which is relatively high in sulfur but which contains less than 7 weight percent pentane insolubles. Because of its low aromaticity, the relatively high sulfur cracked residual oil is compatible for blending with the relatively low sulfur hydrodesulfurizer residual oil effluent.