Method for the measurement of the total content of organic carbon and
nitrogen in water
    21.
    发明授权
    Method for the measurement of the total content of organic carbon and nitrogen in water 失效
    用于测量水中有机碳和氮的总含量的方法

    公开(公告)号:US5292666A

    公开(公告)日:1994-03-08

    申请号:US880576

    申请日:1992-05-08

    Abstract: A method for measuring of the total content of organic carbon and of nitrogen in water. The total organic carbon value is obtained correctly as the sum of the liquid, dissolved, and solid materials of a sample of the water. The device comprises a non-dispersive infrared (NDIR) gas analyzer for the simultaneous measurement of the concentration of the gas components carbon dioxide CO.sub.2 and nitrogen oxide NO. The NDIR gas analyzer includes a phase separator (50), a thermal reactor (52), a double cooler (70), two valves (54, 56), as well as two amplifiers (58, 60) for the pneumatic signals of the receiver detectors (30, 36) with a display (62. 64) for the measured concentrations, total organic carbon and total nitrogen. The sample is split in a phase separator (50) into a gaseous and into a liquid part. The gaseous part, which comprises substantially the inorganic part of the carbon, the total inorganic carbon part in the form of carbon dioxide CO.sub.2 gas, is cooled in a cooler to such an extent that a substantial part its water vapor content is deposited in the cooler by condensation. The dried gaseous part is led as comparison gas through the comparison cuvette. This step serves to compensate the total inorganic carbon part of the sample and to compensate for unavoidable water vapor cross-sensitivities during the measurement of the carbon dioxide CO.sub.2 concentration and of the nitrogen oxide NO concentration.

    Abstract translation: 一种用于测量水中有机碳和氮的总含量的方法。 总有机碳值正确地作为水样品的液体,溶解和固体物质的总和获得。 该装置包括用于同时测量气体成分二氧化碳CO2和氮氧化物NO的浓度的非分散红外(NDIR)气体分析仪。 NDIR气体分析仪包括相分离器(50),热反应器(52),双重冷却器(70),两个阀(54,56)以及两个放大器(58,60),用于 接收器检测器(30,36),其具有用于测量浓度的显示器(62.64),总有机碳和总氮。 样品在相分离器(50)中分成气态并进入液体部分。 基本上包含碳的无机部分的气体部分是二氧化碳CO 2气体形式的总无机碳部分在冷却器中被冷却至使其大部分水汽含量沉积在冷却器中的程度 通过冷凝。 干燥的气体部分作为比较气体通过比较反应杯引导。 该步骤用于补偿样品的总无机碳部分并补偿在测量二氧化碳CO 2浓度和氮氧化物NO浓度期间不可避免的水蒸气交叉敏感性。

    Nondispersive infrared gas analyzer
    22.
    发明授权
    Nondispersive infrared gas analyzer 失效
    非分散型红外线气体分析仪

    公开(公告)号:US4180732A

    公开(公告)日:1979-12-25

    申请号:US953639

    申请日:1978-10-23

    CPC classification number: G01N21/37 G01N21/61

    Abstract: The sensitivity and selectivity of a two beam analyzer operating with negative filtering and differential absorption-pressure detection is improved by employing differently long cells for the sample gas in the two beam paths, which reduces the effect resulting from overlapping absorption bands of the wanted and of unwanted components in the sample gas.

    Abstract translation: 通过对两个光束路径中的样品气体采用不同长度的细胞,可以提高使用负滤波和差分吸收压力检测操作的双光束分析仪的灵敏度和选择性,从而降低了由需要的重叠吸收带和 样品气体中不需要的组分。

    Device for determining the nitrogen oxide concentration in a gaseous
mixture
    23.
    发明授权
    Device for determining the nitrogen oxide concentration in a gaseous mixture 失效
    用于测定气体混合物中氮氧化物浓度的装置

    公开(公告)号:US4176963A

    公开(公告)日:1979-12-04

    申请号:US740307

    申请日:1976-11-09

    CPC classification number: G01N21/33

    Abstract: Apparatus for determining the nitrogen oxide concentration in a gaseous mixture while minimizing measuring errors. The radiation from a hollow cathode lamp emitting the nitrogen oxide resonance radiation is modulated by a device for generating alternatively an unfiltered or test beam and a reference beam. The reference beam is filtered by a nitrogen oxide filled filter. An absorption cell is disposed in the path of the reference beam. Further, a monochromator or filter is provided and a detector for receiving the radiation from the monochromator filter. A signal processing unit is coupled to the detector for forming electric signals corresponding to the signal from the unfiltered and the reference beam and for forming the quotient thereof. A ray splitter is disposed in the path of the two beams to provide a different beam path and an additional radiation detector is disposed in the additional path. The signal processing unit has additional means for forming the quotient of the two signals generated by the additional detector and which have not passed the absorption cell. This will then provide an additional quotient of the two available quotients thus minimizing the normally occurring errors.

    Abstract translation: 用于确定气体混合物中的氮氧化物浓度同时最小化测量误差的装置。 来自发射氮氧化物共振辐射的空心阴极灯的辐射由用于另外产生未过滤或测试光束和参考光束的装置调制。 参考光束被氮氧化物填充的过滤器过滤。 吸收单元设置在参考光束的路径中。 此外,提供单色仪或滤光器,以及用于接收来自单色器滤光器的辐射的检测器。 信号处理单元耦合到检测器,用于形成对应于未滤波和参考光束的信号的电信号并形成其商。 光束分离器设置在两个光束的路径中以提供不同的光束路径,并且另外的辐射检测器设置在附加路径中。 信号处理单元具有用于形成由附加检测器产生并且没有通过吸收单元的两个信号的商的附加装置。 这将提供两个可用商的附加商,从而最小化正常发生的错误。

    Non-Dispersive Infrared Gas Analyzer
    24.
    发明申请
    Non-Dispersive Infrared Gas Analyzer 审中-公开
    非分散红外气体分析仪

    公开(公告)号:US20080011952A1

    公开(公告)日:2008-01-17

    申请号:US11630919

    申请日:2005-06-09

    CPC classification number: G01N21/37 G01N21/3504 G01N21/61

    Abstract: The invention relates to a non-dispersive infrared gas analyzer (1) for identifying a test gas containing a number of gas constituents, comprising a radiation source (2), a modulating device (3), a measuring cell (4), which has a measuring chamber (4a) and a comparing chamber (4b), and comprising an optopneumatic detector unit (5) that has a first detector (5a), which, for measuring gas constituent A, is filled with gas constituent A, and has a second detector (5b), which is situated behind the first detector (5a) and which, for measuring gas constituent B, is filled with the isotope B* thereof.

    Abstract translation: 本发明涉及一种用于识别含有多种气体成分的测试气体的非分散红外线气体分析仪(1),其包括辐射源(2),调制装置(3),测量单元(4),其具有 测量室(4a)和比较室(4b),并且包括具有第一检测器(5a)的操作气动检测器单元(5),其用于测量气体成分A,填充有气体成分A, 并且具有位于第一检测器(5a)后面的第二检测器(5b),并且用于测量气体成分B的第二检测器填充有其同位素B *。

    Method for measuring NOx
    25.
    发明授权
    Method for measuring NOx 有权
    测量NOx的方法

    公开(公告)号:US06493087B1

    公开(公告)日:2002-12-10

    申请号:US09915013

    申请日:2001-07-25

    CPC classification number: G01N21/3504

    Abstract: A method for measuring NOx having a specific discharge lamp. The method controls a photometric analysis device, in which an electrically rotatable filter wheel or shutter wheel is used to change various shutters and/or filters in a beam path with beam source, cuvette and detector. The filter and/or shutter wheel is controlled in such a way that the measurement time is greater than the transfer time. This control improves the detection limit of the NOx resonance absorption method.

    Abstract translation: 一种用于测量具有特定放电灯的NOx的方法。 该方法控制光度分析装置,其中使用电动旋转的滤光轮或快门轮来改变具有光束源,比色杯和检测器的光束路径中的各种快门和/或滤光器。 过滤器和/或快门轮以这样的方式进行控制,使得测量时间大于传送时间。 该控制提高了NOx共振吸收法的检测限。

    Apparatus for the measurement of the total content of organic carbon and
nitrogen in water
    26.
    发明授权
    Apparatus for the measurement of the total content of organic carbon and nitrogen in water 失效
    用于测量水中有机碳和氮的总含量的装置

    公开(公告)号:US5340542A

    公开(公告)日:1994-08-23

    申请号:US71106

    申请日:1993-06-04

    Abstract: The invention relates to a method for measuring of the total content of organic carbon and of nitrogen in water. The total organic carbon value is obtained correctly as the sum of the liquid, dissolved, and solid materials of a sample of the water. The device comprises a non-dispersive infrared (NDIR) gas analyzer for the simultaneous measurement of the concentration of the gas components carbon dioxide CO.sub.2 and nitrogen oxide NO. The NDIR gas analyzer includes a phase separator (50), a thermal reactor (52), a double cooler (70), two valves (54, 56), as well as two amplifiers (58, 60) for the pneumatic signals of the receiver detectors (30, 36) with a display (62. 64) for the measured concentrations, total organic carbon and total nitrogen. The sample is split in a phase separator (50) into a gaseous and into a liquid part. The gaseous part, which comprises substantially the inorganic part of the carbon, the total inorganic carbon part in the form of carbon dioxide CO.sub.2 gas, is cooled in a cooler to such an extent that a substantial part its water vapor content is deposited in the cooler by condensation. The dried gaseous part is led as comparison gas through the comparison cuvette. This step serves to compensate the total inorganic carbon part of the sample and to compensate for unavoidable water vapor cross-sensitivities during the measurement of the carbon dioxide CO.sub.2 concentration and of the nitrogen oxide NO concentration.

    Abstract translation: 本发明涉及一种测量水中有机碳和氮的总含量的方法。 总有机碳值正确地作为水样品的液体,溶解和固体物质的总和获得。 该装置包括用于同时测量气体成分二氧化碳CO2和氮氧化物NO的浓度的非分散红外(NDIR)气体分析仪。 NDIR气体分析仪包括相分离器(50),热反应器(52),双重冷却器(70),两个阀(54,56)以及两个放大器(58,60),用于 接收器检测器(30,36),其具有用于测量浓度的显示器(62.64),总有机碳和总氮。 样品在相分离器(50)中分成气态并进入液体部分。 基本上包含碳的无机部分的气体部分是二氧化碳CO 2气体形式的总无机碳部分在冷却器中被冷却至使其大部分水汽含量沉积在冷却器中的程度 通过冷凝。 干燥的气体部分作为比较气体通过比较反应杯引导。 该步骤用于补偿样品的总无机碳部分并补偿在测量二氧化碳CO 2浓度和氮氧化物NO浓度期间不可避免的水蒸气交叉敏感性。

    Multicomponent infrared gas analyzer
    27.
    发明授权
    Multicomponent infrared gas analyzer 失效
    多组分红外气体分析仪

    公开(公告)号:US5055688A

    公开(公告)日:1991-10-08

    申请号:US605512

    申请日:1990-10-30

    Inventor: Walter Fabinski

    CPC classification number: G01N21/37 G01N2021/3133 G01N21/61

    Abstract: Nondispersive infrared gas analyzer for the concurrent measurement in the concentration of several components contained in a gas sample, and including a source of and modulator for infrared radiation, a measuring and reference chamber are traversed by said beams, at least two serially pneumatic radiation detectors each having a front and a rear chamber filled with a respective component and each provided for measuring the pressure differential between the respective chambers, a filter disposed between the first detectors upstream and having opaque range which covers at least a major absorption band of the component filling the downstream detector but having a region of transparency which includes at least one secondary absorption band of that component.

    Abstract translation: 用于同时测量包含在气体样品中的若干组分的浓度并且包括用于红外辐射的源和调制器用于红外辐射的测量和参考室的非分散型红外气体分析仪,所述光束穿过测量和参考室,至少两个串联气体辐射检测器 具有填充有相应部件的前室和后室,每个分别设置用于测量各室之间的压力差;过滤器,设置在上游的第一检测器之间并具有不透明范围,该范围至少覆盖填充该室的部件的主要吸收带 下游检测器,但是具有包括该部件的至少一个次级吸收带的透明区域。

    Photometer
    28.
    发明授权
    Photometer 失效
    光度计

    公开(公告)号:US4714832A

    公开(公告)日:1987-12-22

    申请号:US753659

    申请日:1985-07-10

    Inventor: Walter Fabinski

    CPC classification number: G01N21/3504 G01J5/34

    Abstract: Photometer with at least one measuring beam traversing a space that contains measuring gas is improved by a solid state detector made of a foil which is specifically made of polyvinyl-idene-fluoride or polyvinyl-fluoride or polyvinyl-chloride, and having an area, being at least as large as the cross-sectional area of the radiation that leaves the measuring and gas containing chamber; a measuring signal is extracted from the foil. The foil is preferably blackened and has a thickness between 6-10 micrometers.

    Abstract translation: 具有穿过包含测量气体的空间的至少一个测量光束的光度计由通过由聚偏氟乙烯 - 氟化物或聚氟乙烯或聚氯乙烯特别制成的箔制成的固态检测器改进,并且具有面积 至少与离开测量和气体容纳室的辐射的横截面面积一样大; 从箔提取测量信号。 箔优选变黑并且具有6-10微米的厚度。

    Nondispersive infrared gas analyzer
    30.
    发明授权
    Nondispersive infrared gas analyzer 失效
    非分散型红外线气体分析仪

    公开(公告)号:US4288693A

    公开(公告)日:1981-09-08

    申请号:US46549

    申请日:1979-06-07

    CPC classification number: G01N21/37

    Abstract: The cross sensitivity of a two-beam infrared gas analyzer is eliminated by using two differently long cells for the measuring gas in the two beam paths and by using an interference filter at least in the beam path containing the longer cell; the filter, however, does not filter the entire beam in that path.

    Abstract translation: 双光束红外线气体分析仪的交叉灵敏度通过使用两个不同长度的单元用于两个光束路径中的测量气体并且至少在包含较长单元的光束路径中使用干涉滤光器来消除; 然而,滤波器不会过滤该路径中的整个波束。

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