利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

92 条记录 (耗时 0.03 秒)

    Process for producing perfluorinated organic compounds
    24.
    发明申请
    Process for producing perfluorinated organic compounds 有权
    生产全氟化有机化合物的方法

    公开(公告)号：US20120095243A1

    公开(公告)日：2012-04-19

    申请号：US13378887

    申请日：2010-07-06

    申请人： Vito Tortelli ,  Marco Galimberti ,  Giuseppe Marchionni

    发明人： Vito Tortelli ,  Marco Galimberti ,  Giuseppe Marchionni

    IPC分类号： C07D317/42

    CPC分类号： C07D317/42

    摘要： A process for producing a perfluorinated functional compound is disclosed, which comprises: A. converting an at least partially hydrogenated alcohol into an at least partially hydrogenated fluoroformate compound; B. reacting said at least partially hydrogenated fluoroformate compound with fluorine in the presence of at least one (per)haloolefin comprising at least one carbon-carbon double bond and having at least one fluorine or chlorine atom on either one of the carbon atoms of said double bond, to obtain a perfluorinated fluoroformate compound.

    摘要翻译： 公开了一种制备全氟化官能化合物的方法，其包括：A.将至少部分氢化的醇转化为至少部分氢化的氟甲酸酯化合物; B.在至少一种包含至少一个碳 - 碳双键的（全）卤代烯烃存在下，使所述至少部分氢化的氟甲酸酯化合物与氟反应，并在所述的碳 - 碳双键的碳原子上具有至少一个氟或氯原子 双键，得到全氟化氟甲酸酯化合物。

    Process for the manufacture of fluorosurfactants
    25.
    发明申请
    Process for the manufacture of fluorosurfactants 有权
    制备含氟表面活性剂的方法

    公开(公告)号：US20110213182A1

    公开(公告)日：2011-09-01

    申请号：US13002779

    申请日：2009-07-07

    申请人： Giuseppe Marchionni ,  Vito Tortelli

    发明人： Giuseppe Marchionni ,  Vito Tortelli

    IPC分类号： C07C51/04

    CPC分类号： C07C51/04 ,  C07C51/367 ,  C07C51/412 ,  C07C51/58 ,  C07C59/135

    摘要： A process for the manufacture of a perfluorooxycarboxylate of formula (I): RfO—CF2CF2—O—CF2—COOXa (I), wherein Rf is a perfluoro(oxy)alkyl group, and Xa is H, a monovalent metal or an ammonium group of formula NRN4, with RN, equal or different at each occurrence, being H or a C1-6 hydrocarbon group, said process comprising: (A) reacting a perfluorovinylether of formula Rf—O—CF═CF2 with an ethylene glycol derivative selected among ethylene glycol (HO—CH2CH2—OH), glycolic acid (HO—CH2—COOH), glycolaldehyde (HO—CH2—CHO) and protected derivatives thereof, so as to yield the corresponding addition product of formula Rf—O—CFH—CF2—O—CH2-E, and E being selected among —CH2OH, —COOH and —CHO; (B) optionally protecting functional group E with suitable chemistry; (C) fluorinating the (protected) addition product to yield the corresponding perfluorinated addition product; (D) optionally deprotecting the perfluorinated addition product to yield corresponding acyl fluoride of formula Rf—O—CF2—CF2—O—CF2—C(O)F; and (E) hydrolyzing and, optionally, neutralizing, the acyl fluoride for yielding the perfluorooxycarboxylate of formula (I).

    摘要翻译： 制备式（I）的全氟氧基羧酸酯的方法：RfO-CF 2 CF 2 -O-CF 2 -COOa（I），其中Rf是全氟（氧）烷基，Xa是H，一价金属或铵基 其中每个出现时RN相同或不同，为H或C 1-6烃基，所述方法包括：（A）使式Rf-O-CF = CF 2的全氟乙烯基醚与选自以下的乙二醇衍生物： 乙醇酸（HO-CH2CH2OH），乙醇酸（HO-CH2-COOH），乙醇醛（HO-CH2-CHO）及其被保护的衍生物，得到相应的式Rf-O-CFH-CF2 -O-CH 2 -E，E选自-CH 2 OH，-COOH和-CHO; （B）任选地用合适的化学保护官能团E; （C）氟化（保护）加成产物以产生相应的全氟化加成产物; （D）任选地使全氟化加成产物脱保护，得到相应的式Rf-O-CF2-CF2-O-CF2-C（O）F的酰基氟; 和（E）水解和任选地中和酰基氟以产生式（I）的全氟氧基羧酸酯。

    Method for manufacturing perfluorovinylethers
    26.
    发明申请
    Method for manufacturing perfluorovinylethers 有权
    制造全氟乙烯基醚的方法

    公开(公告)号：US20110098512A1

    公开(公告)日：2011-04-28

    申请号：US12996351

    申请日：2009-06-04

    申请人： Stefano Millefanti ,  Vito Tortelli ,  Giuseppe Marchionni

    发明人： Stefano Millefanti ,  Vito Tortelli ,  Giuseppe Marchionni

    IPC分类号： C07C41/24

    CPC分类号： C07C41/24 ,  C07D317/34 ,  C07C43/17

    摘要： A process for the manufacture of a perfluorovinylether by hydrodehalogenation of a halofluoroether (HFE) having general formula (I-A) or (I-B): wherein Rf represents a C1-C6 perfluoro(oxy)alkyl group; Rf′, Rf″ and Rf′″, equal to or different from each other, independently represent fluorine atoms or C1-C5 perfluoro(oxy)alkyl groups; X and X′, equal to or different from each other, are independently chosen among Cl, Br or I; Rf* and Rf*′, equal to or different from each other, independently represent fluorine atoms or C1-C3 perfluoro(oxy)alkyl groups; Y1 and Y2, equal to or different from each other, independently represent fluorine atoms or C1-C3 perfluoroalkyl groups. The process comprises contacting the halofluoroether (HFE) with hydrogen in the presence of a catalyst comprising at least one transition metal of group VIII B at a temperature of at most 340° C.

    摘要翻译： 一种通过通式（I-A）或（I-B）的卤代氟醚（HFE）的加氢脱卤制备全氟乙烯基醚的方法：其中Rf代表C1-C6全氟（氧）烷基; Rf'，Rf“和Rf”“彼此相同或不同，独立地表示氟原子或C1-C5全氟（氧）烷基; X和X'彼此相同或不同，独立地选自Cl，Br或I; Rf *和Rf *'彼此相同或不同，独立地表示氟原子或C1-C3全氟（氧）烷基; Y1和Y2彼此相同或不同，独立地表示氟原子或C1-C3全氟烷基。 该方法包括在包含至少一种第ⅧB族过渡金属的催化剂存在下，在至多340℃的温度下使卤代氟醚（HFE）与氢气接触。

    Process for the synthesis of perfluorobutadiene
    27.
    发明申请
    Process for the synthesis of perfluorobutadiene 有权
    全氟丁二烯合成方法

    公开(公告)号：US20100280291A1

    公开(公告)日：2010-11-04

    申请号：US12808410

    申请日：2008-12-24

    申请人： Vito Tortelli ,  Stefano Millefanti ,  Serena Carella

    发明人： Vito Tortelli ,  Stefano Millefanti ,  Serena Carella

    IPC分类号： C07C17/23

    CPC分类号： C07C21/20 ,  C07C17/04 ,  C07C17/23 ,  C07C17/25 ,  C07C17/281 ,  Y02P20/582 ,  C07C19/10

    摘要： Process for preparing perfluoro-1,3-butadiene, comprising the following steps: A) preparation of fluoro-halo-butanes of formula: CF2 YI—CFYII—CFYII—CF2 YI  (V) in which YI and YII, which may be identical or different, may be H, Cl or Br, with the condition that YI and YII are not simultaneously hydrogen; starting with a chloroolefin having the formula: CY″Y═CY′Cl  (II) in which Y, Y′, Y″, which may be identical or different, are H, Cl or Br, with the condition that Y, Y′, Y″ are not simultaneously hydrogen; and performing the following steps: a fluorodimerization, and a fluorination with elemental fluorine, the order of the two steps also possibly being inverted, a dehalogenation or dehydrohalogenation step being performed between the two steps, B) dehalogenation or dehydrohalogenation of the fluoro-halo compounds of formula (V) to give the compound perfluoro-1,3-butadiene.

    摘要翻译： 制备全氟-1,3-丁二烯的方法，包括以下步骤：A）制备式为：CF 2 YI-CFYII-CFYII-CF 2 Y（V）的氟代 - 丁烷，其中YI和YII可以相同 或不同的，可以是H，Cl或Br，条件是YI和YII不同时为氢; 以具有下式的氯代烯烃开始：其中Y，Y'，Y“可以相同或不同，为H，Cl或Br，条件是Y，Y' ，Y“不同时为氢; 并进行以下步骤：氟代二聚和氟元素氟化，两个步骤的顺序也可能反转，在两个步骤之间进行脱卤或脱卤化氢步骤，B）氟 - 卤素化合物的脱卤或脱卤化氢 的式（V）化合物，得到化合物全氟-1,3-丁二烯。

    Process for preparing fluorohalogenethers
    28.
    发明授权
    Process for preparing fluorohalogenethers 有权
    制备氟卤醚的方法

    公开(公告)号：US07795477B2

    公开(公告)日：2010-09-14

    申请号：US11636509

    申请日：2006-12-11

    申请人： Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

    发明人： Vito Tortelli ,  Pierangelo Calini ,  Alberto Zompatori ,  Emanuela Antenucci

    IPC分类号： C07C41/22

    CPC分类号： C07C41/06 ,  C07C17/04 ,  C07C17/23 ,  C07C17/25 ,  C07C41/24 ,  C07C19/12 ,  C07C19/14 ,  C07C21/18 ,  C07C43/123 ,  C07C43/17

    摘要： A process for preparing perfluorovinylethers having general formula: RfO—CF═CF2  (IA) where Rf is a C1-C3 alkyl perfluorinated substituent, comprises the steps of: 1a) fluorinating olefins of formula: CY″Y═CY′Cl  (II) where Y, Y′ and Y″, equal to or different from each other, are H, Cl, Br, and are not contemporaneously hydrogen; and obtaining fluorohalogencarbons of formula: FCY″Y—CY′ClF  (III) where Y, Y′ and Y″ are as above; 2a) dehalogenating or dehydrohalogenating fluorohalogencarbons (III) and obtaining fluorohalogenolefins of formula: FCYI═CYIIF  (IV) where YI and YII, equal to or different from each other, are H, Cl, Br and are not contemporaneously H; 3a) reacting a hypofluorite of formula RfOF and a fluorohalogenolefin (IV), and obtaining the fluorohalogenethers of formula: RfO—CFYI—CF2YII  (I) where YI, YII, equal to or different from each other, are Cl, Br, H and are not be contemporaneously H; and 4a) dehalogenating or dehydrohalogenating compounds (I) and obtaining perfluorovinylethers (IA).

    摘要翻译： 一种制备具有以下通式的全氟乙烯基醚的方法：RfO-CF = CF2（IA）其中Rf为C1-C3烷基全氟取代基，包括以下步骤：1a）氟化式：CY“Y = C''Cl（II） 其中Y，Y'和Y“彼此相同或不同，为H，Cl，Br，并非同时为氢; 并获得式：FCY“Y-CY'ClF（III）的氟代卤素，其中Y，Y'和Y”如上所述; 2a）脱卤或脱卤化氢氟代烃（III）并得到式（Ⅳ）的氟卤代烯烃，其中YI和YII彼此相同或不同，为H，Cl，Br，不同时为H; 3a）使式RfOF的次氟化物与氟代卤代烯烃（IV）反应，得到其中YI，YII彼此相同或不同的式RfO-CFYI-CF2YII（I）的氟代醚，为Cl，Br，H和 不是同时H 和4a）脱卤或脱卤化氢化合物（I）并获得全氟乙烯基醚（IA）。

    TFE-based thermoprocessable copolymers
    29.
    发明授权
    TFE-based thermoprocessable copolymers 失效
    基于TFE的热可加工共聚物

    公开(公告)号：US07544752B2

    公开(公告)日：2009-06-09

    申请号：US11191031

    申请日：2005-07-28

    申请人： Francesco Triulzi ,  Marco Apostolo ,  Vito Tortelli ,  Marco Galimberti

    发明人： Francesco Triulzi ,  Marco Apostolo ,  Vito Tortelli ,  Marco Galimberti

    IPC分类号： C08F116/12 ,  C07C43/17

    CPC分类号： C08F214/262

    摘要： TFE-based thermoprocessable copolymers having the following composition, expressed in percentage by moles on the total of the monomers: A) from 0.01 to 15% of the monomer of formula: CF2═CFOCF2OCF3  (a); A1) tetrafluoroethylene from 99.99 to 85%; optionally B) one or more (per)fluorinated comonomers having at least one unsaturation of ethylene type, different from TFE; the sum of the molar percentages A)+B) being such as to give polymers showing at least one melting peak at the thermogravimetric analysis (DSC).

    摘要翻译： 具有以下组成的基于TFE的热可加工共聚物，以单体总量的百分比表示：A）0.01至15％的式的单体：<？在线公式描述=“在线式” end =“lead”？> CF2-CFOCF2OCF3（a）; <？in-line-formula description =“In-line formula”end =“tail”？> A1）从99.99到85％的四氟乙烯; 任选地B）一种或多种具有不同于TFE的乙烯类型的至少一个不饱和键的（全）氟化共聚单体; 摩尔百分比A）+ B）的总和使得在热重分析（DSC）下显示出至少一个熔融峰的聚合物。