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21.发明授权1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, process for producing same, intermediates useful in said process and organoleptic uses of same 失效1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇，其制备方法，可用于所述方法的中间体和其相同的感官用途
公开(公告)号：US4549972A
公开(公告)日：1985-10-29
申请号：US671406
申请日：1984-11-14
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , C07C35/22 , C11D9/44
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译： 描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：
和 其用于增强或增强香料组合物，香料制品和古龙水的香气。 还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮： 图像>该酮与CH 3 M反应，其中M表示Li或MgX，并且其中X是氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感官有用的 本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义： -
22.发明授权1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, process for producing same, intermediates useful in said process and organoleptic uses of same 失效1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇，其制备方法，可用于所述方法的中间体和其相同的感官用途
公开(公告)号：US4532359A
公开(公告)日：1985-07-30
申请号：US602570
申请日：1984-04-20
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C12C11/02 , C07C2102/44
摘要： Described is a novel process for preparing 1,2,3,3,5,6-hexamethyl- bicyclo [2,2,2.] oct-5-en-2-ol by using 2,6,6-trimethylcyclohexa-2,4-diene-1-one as a starting material.
摘要翻译： 描述了一种制备1,2,3,3,5,6-六甲基 - 双环[2,2,2]辛-5-烯-2-醇的新方法，其中使用2,6,6-三甲基环己烷-2 ，4-二烯-1-酮作为起始原料。
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23.发明授权1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, and organoleptic uses of same 失效1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇及其感官用途
公开(公告)号：US4514324A
公开(公告)日：1985-04-30
申请号：US602569
申请日：1984-04-20
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译： 描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：
和 其用于增强或增强香料组合物，香料制品和古龙水的香气。 还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮： 图像>该酮与CH 3 M反应，其中M表示Li或MgX，其中X为氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感光有用的 本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义： -
24.发明授权Perfume or cologne containing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]-oct-5-en-2-ol 失效含有1,2,3,3,5,6-六甲基 - 双环[2.2.2] - 辛-5-烯-2-醇的香水或古龙水
公开(公告)号：US4434085A
公开(公告)日：1984-02-28
申请号：US371930
申请日：1982-04-26
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译： 描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：
和 其用于增强或增强香料组合物，香料制品和古龙水的香气。 还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮： 图像>该酮与CH 3 M反应，其中M表示Li或MgX，并且其中X是氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感官有用的 本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义：
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