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37 条记录 (耗时 0.059 秒)

    Slurry process for synthesis of bisphosphites and situ use thereof for producing bisphosphite
    31.
    发明授权
    Slurry process for synthesis of bisphosphites and situ use thereof for producing bisphosphite 有权
    用于合成二亚磷酸酯的浆料方法及其用于生产双亚磷酸酯的原位应用

    公开(公告)号：US08546600B2

    公开(公告)日：2013-10-01

    申请号：US13122975

    申请日：2009-09-23

    申请人： Glenn A. Miller

    发明人： Glenn A. Miller

    IPC分类号： C07F9/141

    CPC分类号： C07F9/65746

    摘要： The present invention provides a step-wise process for preparation of a bisphosphite. In step (a) the process prepares a phosphoromonochloridite in high yield, by contacting phosphorus trichloride with an aromatic diol in a slurry under reaction conditions and in the presence of a second aromatic diol to produce a mixture comprising the phosphoromonochloridite, the second aromatic diol, and excess PCl3. The slurry comprises less than 5 mole percent of a nitrogen base, and the organic solvent is selected for its low hydrogen chloride solubility. After removing the excess PCl3, a nitrogen base is added to effect condensation of the phosphoromonochloridite with the second aromatic diol to yield the bisphosphite. The invention particularly provides a process for preparing 6,6′-(3,3′,5,5′-tetra-tert-butylbiphenyl-2,2′-diyl)bis(oxy)didibenzo[d,f][1,3,2]dioxaphosphepine by the above route.

    摘要翻译： 本发明提供了制备双亚磷酸酯的逐步方法。 在步骤（a）中，该方法通过在反应条件下和在第二芳族二醇的存在下，在淤浆中将三氯化磷与芳族二醇接触，以高产率制备一种次氯酸钠，以产生包含一氯代氯化亚锡，第二芳族二醇， 和多余的PCl3。 浆料含有小于5摩尔％的氮碱，并且为了其低氯化氢溶解度而选择有机溶剂。 除去过量的PCl3后，加入氮碱以使次氯酸亚膦酸与第二芳族二醇进行缩合，得到双亚磷酸酯。 本发明特别提供了制备6,6' - （3,3'，5,5'-四叔丁基联苯-2,2'-二基）双（氧基）二苯并[d，f] [1， 3,2] dioxaphosphepine通过上述途径。

    PROCESS OF REFINING C6-16 ALIPHATIC DIOLS
    32.
    发明申请
    PROCESS OF REFINING C6-16 ALIPHATIC DIOLS 有权
    精制C6-16二氧化碳的方法

    公开(公告)号：US20100267997A1

    公开(公告)日：2010-10-21

    申请号：US12669124

    申请日：2008-07-07

    申请人： Glenn A. Miller ,  Edward H. Yonemoto ,  Rainer Potthast

    发明人： Glenn A. Miller ,  Edward H. Yonemoto ,  Rainer Potthast

    IPC分类号： C07C31/20

    CPC分类号： C07C29/80 ,  C07B2200/09 ,  C07C2601/14 ,  C07C31/276

    摘要： A process of refining a crude C6-C16 aliphatic diol, preferably, a C6-C16 monocyclic aliphatic diol, more preferably, an isomeric mixture of cis/trans-(1,3)(1,4)-cyclohexanedimethanol, containing in addition to the diol one or more impurities selected from phenols, and aliphatic mono-ols, esters, carboxylic acids, and hemiacetals, and mixtures thereof. The refining process involves distilling the crude C6-C16 aliphatic diol in the presence of an alkali or alkaline earth metal compound, preferably, an excess thereof relative to acid equivalents present in the diol.

    摘要翻译： 精制C6-C16脂族二醇，优选C 6 -C 16单环脂族二醇，更优选顺式/反式 - （1,3）（1,4） - 环己烷二甲醇的异构体混合物的方法， 二醇一种或多种选自苯酚和脂族单酯，酯，羧酸和半缩醛的杂质及其混合物。 精制方法包括在碱或碱土金属化合物的存在下，相对于存在于二醇中的酸当量，优选过量蒸馏粗制C 6 -C 16脂族二醇。

    ISOTHERMAL PROCESS FOR PHOSPHOROMONOCHLORIDITE SYNTHESIS
    33.
    发明申请
    ISOTHERMAL PROCESS FOR PHOSPHOROMONOCHLORIDITE SYNTHESIS 有权
    磷酸二氢钙合成的同位素过程

    公开(公告)号：US20090247790A1

    公开(公告)日：2009-10-01

    申请号：US12405335

    申请日：2009-03-17

    申请人： Glenn A. Miller

    发明人： Glenn A. Miller

    IPC分类号： C07F9/06

    CPC分类号： C07F9/65744 ,  C07F9/146 ,  C07F9/65746

    摘要： The present invention relates to a process for preparation of a phosphoromonochloridite in high yield by contacting phosphorus trichloride (PCl3) with an aromatic diol in a solution of one or more organic solvents under reaction conditions sufficient to produce the phosphoromonochloridite. The reaction is carried out by adding a feed solution containing the aromatic diol dissolved in a first organic solvent into a reaction zone containing PCl3, and optionally one or more second organic solvents, the addition being conducted so as to maintain substantially isothermal process conditions. The reaction solution comprises greater than 0.01 to less than 5 mole percent of a nitrogen base.

    摘要翻译： 本发明涉及一种通过在一个或多个有机溶剂的溶液中将三氯化磷（PCl3）与芳族二醇接触的反应条件足以产生一氯代氯酸盐，以高产率制备一种多氯代磷酸酯的方法。 通过将含有溶解在第一有机溶剂中的芳族二醇的进料溶液加入到含有PCl 3的反应区和任选的一种或多种第二有机溶剂中进行反应，进行添加以保持基本上等温的工艺条件。 反应溶液包含大于0.01至小于5摩尔％的氮碱。

    High viscosity surfactants for the manufacture of polyurethane foams
    37.
    发明授权
    High viscosity surfactants for the manufacture of polyurethane foams 失效
    用于制造聚氨酯泡沫的高粘度表面活性剂

    公开(公告)号：US5489617A

    公开(公告)日：1996-02-06

    申请号：US436788

    申请日：1995-05-08

    申请人： Glenn A. Miller ,  David L. Kirchner ,  Susan B. McVey

    发明人： Glenn A. Miller ,  David L. Kirchner ,  Susan B. McVey

    IPC分类号： C08G77/46 ,  C08J9/02

    CPC分类号： C08G77/46

    摘要： The present invention discloses high viscosity surfactants which may be used, when diluted to a viscosity below 2500 cP at 25.degree. C., as surfactants for the production of polyuretahne foam. Specifically, the surfactants of the present invention have the generalized average formula M*D.sub.x D".sub.y M* whereinM* is (CH.sub.3).sub.3 SiO.sub.1/2 or R(CH.sub.3).sub.2 SiO.sub.1/2 ;M" is R(CH.sub.3).sub.2 SiO.sub.1/2 ;D is (CH.sub.3).sub.2 SIO.sub.2/2 ;D" is (CH.sub.3)(R)SiO.sub.2/2 ;x is 81-220, y is 8-40 and D/(D"+M").ltoreq.10;R is a polyether-containing substituent derived from a blend of C.sub.n H.sub.2n -started polyethers selected from two different groups such that the average molecular mass is 1100-1800.

    摘要翻译： 本发明公开了当在25℃下稀释至低于2500cP的粘度时可以使用的高粘度表面活性剂作为生产聚氨酯泡沫的表面活性剂。 具体而言，本发明的表面活性剂具有通式M * DxD''YM *，其中M *为（CH3）3SiO1 / 2或R（CH3）2SiO1 / 2; M“是R（CH 3）2 SiO 1/2; D为（CH3）2SiO2 / 2; D“是（CH 3）（R）SiO 2/2; x为81-220，y为8-40，D /（D“+ M”）为10; R是衍生自选自两个不同基团的C n H 2n起始聚醚的共混物的聚醚的取代基，使得平均分子量为1100-1800。