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    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof
    31.
    发明授权
    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof 失效
    磺化三芳基膦的季铵盐及其制备方法

    公开(公告)号：US4673535A

    公开(公告)日：1987-06-16

    申请号：US738868

    申请日：1985-05-29

    Applicant: Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    Inventor： Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    IPC: B01J31/24 ,  C07F9/50 ,  C07C87/30

    CPC classification number: C07F9/5022

    Abstract: The invention relates to new quaternary ammonium salts of di and trisulfonated triarylphosphines as well as a process for their preparation. The salts are of Formula I ##STR1## wherein Ar.sub.1, Ar.sub.2, and Ar.sub.3 are each independently an aryl; X.sup.1, X.sup.2, and X.sup.3 are each independently a sulfo group; y.sup.1, y.sup.2, and y.sup.3 are each independently 0 or 1, provided that their sum is at least 1; A is an alkyl, hydroxyalkyl, aralkyl, or aryl having 6-25 carbon atoms; B, C, and D are straight chain or branched alkyl having 1-4 carbons; and n is a whole number of 1-3.

    Abstract translation: 本发明涉及二和三磺化三芳基膦的新季铵盐及其制备方法。 该盐具有式I的化合物，其中Ar 1，Ar 2和Ar 3各自独立地为芳基; X 1，X 2和X 3各自独立地为磺基; y1，y2和y3各自独立地为0或1，条件是它们的和为至少1; A是具有6-25个碳原子的烷基，羟基烷基，芳烷基或芳基; B，C和D是具有1-4个碳的直链或支链烷基; n为1-3的整数。

    Process for the preparation of sulfonated aryl phosphine
    32.
    发明授权
    Process for the preparation of sulfonated aryl phosphine 失效
    磺化芳基膦的制备方法

    公开(公告)号：US4483802A

    公开(公告)日：1984-11-20

    申请号：US534089

    申请日：1983-09-20

    Applicant: Roderich Gartner ,  Boy Cornils ,  Helmut Springer ,  Peter Lappe

    Inventor： Roderich Gartner ,  Boy Cornils ,  Helmut Springer ,  Peter Lappe

    IPC: C07F9/50 ,  C07C143/24

    CPC classification number: C07F9/5054 ,  C07F9/5095

    Abstract: A process for the preparation of mono, di or trisulfonated aryl phosphines whereby triaryl phosphine is sulfonated with oleum at 0.degree. to 40.degree. C. After dilution of the reaction product with water, the sulfonated triaryl phosphine is extracted with an amine dissolved in an organic solvent; both the amine and organic solvent being insoluble in water. From the organic phase the sulfonated phosphine is transferred to the aqueous phase by treatment with an aqueous solution of a base.

    Abstract translation: 一种制备单，二或三磺化芳基膦的方法，其中三芳基膦在0-40℃下用发烟硫酸磺化。在用水稀释反应产物后，将磺化的三芳基膦用溶解在有机物中的胺萃取 溶剂; 胺和有机溶剂都不溶于水。 从有机相中，通过用碱的水溶液处理将磺化膦转移到水相中。

    Process for preparing 2-methyl-2-sec.butyl-1,3-propanediol
    34.
    发明授权
    Process for preparing 2-methyl-2-sec.butyl-1,3-propanediol 失效
    制备2-甲基-2-间丁基-1,3-丙二醇的方法

    公开(公告)号：US4317945A

    公开(公告)日：1982-03-02

    申请号：US178396

    申请日：1980-08-15

    Applicant: Wolfgang Bernhagen ,  Jurgen Weber ,  Helmut Bahrmann ,  Helmut Springer

    Inventor： Wolfgang Bernhagen ,  Jurgen Weber ,  Helmut Bahrmann ,  Helmut Springer

    IPC: B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/38 ,  C07C31/20 ,  C07C45/50 ,  C07C45/62 ,  C07C45/75 ,  C07C47/02 ,  C07C67/00 ,  C07C29/14

    CPC classification number: C07C47/02 ,  C07C29/38 ,  C07C45/50 ,  C07C45/62 ,  C07C45/75

    Abstract: A process for the preparation of 2-methyl-2-sec.butyl-1,3-propanediol comprising hydroformylating 2-methyl-1-butene with carbon monoxide and hydrogen in the presence of a first catalyst to form the substance 3-methyl-pentanal, condensing said substance with formaldehyde, or a compound which forms formaldehyde under the conditions of condensation in a basic medium to form alpha-sec.butyl-acrolein, partially hydrogenating said acrolein in the presence of a second catalyst to form the material 2,3-dimethyl pentanal, and converting said material into said diol by treatment with formaldehyde, or a compound which forms formaldehyde under the conditions of conversion, in the presence of a strong base as a third catalyst.The compound of the present invention is useful as an intermediate in the production of pharmaceuticals and drugs; in particular, the production of carbamates which are useful as tranquilizers and blood pressure lowering agents.

    Abstract translation: 一种制备2-甲基-2-仲丁基-1,3-丙二醇的方法，包括在第一催化剂存在下，将2-甲基-1-丁烯与一氧化碳和氢气进行甲酰化，形成3-甲基-2- 戊醛，用甲醛缩合所述物质，或在碱性介质中在冷凝条件下形成甲醛以形成α-仲丁基丙烯醛的化合物，在第二催化剂存在下部分氢化所述丙烯醛以形成材料2， 并通过用甲醛处理或在转化条件下形成甲醛的化合物在作为第三催化剂的强碱存在下将所述物质转化成所述二醇。 本发明化合物可用作药物和药物生产中的中间体; 特别是生产可用作镇定剂和降血压剂的氨基甲酸酯。

    Process for preparing TCD-dialdehyde
    38.
    发明授权
    Process for preparing TCD-dialdehyde 失效
    制备TCD-二醛的方法

    公开(公告)号：US07015362B2

    公开(公告)日：2006-03-21

    申请号：US10967731

    申请日：2004-10-18

    Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

    IPC: C07C45/50

    CPC classification number: C07C47/347 ,  C07C2603/68

    Abstract: A process for preparing 3(4),8(9)-bisformyltricyclo[5.2.1.02.6]decane by hydroformylating dicyclopentadiene with subsequent distillation wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in the first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Period Table of the Elements to give 8(9)-bisformyltricyclo[5.2.1.02.6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-bisformyltricyclo[5.2.1.02.6]dec-3-ene is converted, in homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02.6]decane.

    Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），8（9） - 双甲基三环[5.2.1.0]癸烷的方法，随后蒸馏，其中二环戊二烯的加氢甲酰化分两个阶段进行， 在第一加氢甲酰化阶段，反应在非均相反应体系中使用过渡金属化合物的水溶液进行，所述过渡金属化合物含有复合结合形式的水溶性有机磷（III）化合物，元素周期表 得到8（9） - 二甲基三环[5.2.1.0,26.6]癸-3-烯，并在第二加氢甲酰化阶段中，由此得到的8（9） - 二甲基三环[5.2.1.0] 在3-（4），8（9） - 二甲基三环[5.2]的元素周期表第VIII族的过渡金属化合物的存在下，在均相有机相中，将癸-3-烯转化。 1.06D癸烷。

    Method for producing aliphatic carboxylic acids from aldehydes
    39.
    发明授权
    Method for producing aliphatic carboxylic acids from aldehydes 失效
    从醛生产脂肪族羧酸的方法

    公开(公告)号：US06696582B2

    公开(公告)日：2004-02-24

    申请号：US10204286

    申请日：2002-09-10

    Applicant: Helmut Springer ,  Peter Heymanns

    Inventor： Helmut Springer ,  Peter Heymanns

    IPC: C07C5116

    CPC classification number: C07C51/235 ,  Y02P20/582 ,  C07C53/126

    Abstract: The invention relates to a method for producing aliphatic carboxylic acids from aldehydes by means of oxidation with oxygen or gases containing oxygen. This novel process is carried out in at least two stages at different temperatures, preferably in the absence of catalysts.

    Abstract translation: 本发明涉及通过氧气或含氧气体从醛制备脂族羧酸的方法。 该新方法在不同温度下进行至少两个阶段，优选在不存在催化剂的情况下进行。

    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof
    40.
    发明授权
    Quaternary ammonium salts of sulfonated triarylphosphines and process for the production thereof 失效
    磺化三芳基膦的季铵盐及其制备方法

    公开(公告)号：US4710321A

    公开(公告)日：1987-12-01

    申请号：US22274

    申请日：1987-03-05

    Applicant: Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    Inventor： Helmut Bahrmann ,  Boy Cornils ,  Wolfgang Lipps ,  Peter Lappe ,  Helmut Springer

    IPC: B01J31/24 ,  C07F9/50 ,  C07C87/30

    CPC classification number: C07F9/5022

    Abstract: The invention relates to new quaternary ammonium salts of di and trisulfonated triarylphosphines as well as a process for their preparation. The salts are of Formula I ##STR1## wherein Ar.sub.1, Ar.sub.2, and Ar.sub.3 are each independently an aryl; X.sup.1, X.sup.2, and X.sup.3 are each independently a sulfogroup; y.sup.1, y.sup.2, and y.sup.3 are each independently 0 or 1, provided that their sum is at least 1; A is an alkyl, hydroxyalkyl, aralkyl, or aryl having 6-25 carbon atoms; B, C, and D are straight chain or branched alkyl having 1-4 carbons; and n is a whole number of 1-3.

    Abstract translation: 本发明涉及二和三磺化三芳基膦的新季铵盐及其制备方法。 该盐具有式I的化合物，其中Ar 1，Ar 2和Ar 3各自独立地为芳基; X1，X2和X3各自独立地为亚磺酰基团; y1，y2和y3各自独立地为0或1，条件是它们的和为至少1; A是具有6-25个碳原子的烷基，羟基烷基，芳烷基或芳基; B，C和D是具有1-4个碳的直链或支链烷基; n为1-3的整数。

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