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31.发明申请POLYESTER POLYCARBONATE COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM 有权聚酯聚碳酸酯组合物，制备方法和形成的制品公开(公告)号：US20080269399A1
公开(公告)日：2008-10-30
申请号：US11741959
申请日：2007-04-30
IPC分类号： C08F283/02 , C08L67/02
CPC分类号： C08L67/02 , C08K3/01 , C08K5/0008 , C08L69/00 , C08L69/005 , C08L2666/02 , C08L2666/18
摘要： A composition comprises a polyester-polycarbonate polymer comprising isophthalate-terephthalate-resorcinol ester units and carbonate units, a first polyester selected from poly(ethylene terephthalate), poly(ethylene isophthalate), or a combination thereof, and a second polyester comprising butylene terephthalate units, cyclohexanedimethylene terephthalate units, or a combination of cyclohexanedimethylene terephthalate units and ethylene terephthalate units. The composition can be extruded into pellets that are clear and colorless. The composition can further be molded into articles having a percent haze value less than or equal to 10 percent, and total luminous transmittance value of greater than or equal to 70 percent, measured in accordance with ASTM D1003-00. Also disclosed is a method for forming the compositions, and articles prepared therefrom.
摘要翻译： 组合物包含含有间苯二甲酸酯 - 对苯二甲酸酯 - 间苯二酚酯单元和碳酸酯单元的聚酯 - 聚碳酸酯聚合物，选自聚（对苯二甲酸乙二醇酯），聚（乙烯间苯二甲酸酯）或其组合）的第一聚酯和包含对苯二甲酸丁二醇酯单元的第二聚酯 ，对苯二甲酸环己烷二甲酸酯单元，或环己烷二亚甲基对苯二酸酯单元和对苯二甲酸乙二醇酯单元的组合。 该组合物可以挤出成为澄清和无色的颗粒。 根据ASTM D1003-00测量，组合物可以进一步模塑成具有小于或等于10％的雾度值百分比，总透光率值大于或等于70％的制品。 还公开了形成组合物的方法及其制备的制品。
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公开(公告)号：US20080149165A1
公开(公告)日：2008-06-26
申请号：US11615413
申请日：2006-12-22
IPC分类号： H01L31/042
CPC分类号： C09K11/02 , C09K11/06 , C09K2211/1011 , C09K2211/1044 , H01L31/02322 , H01L31/0547 , H01L31/055 , Y02E10/52
摘要： A luminescent solar collector is provided comprising a substrate and a light energy converter, such as a photocell, operatively connected thereto. The substrate is molded from a thermoplastic composition comprising a polymer and a fluorescent dye or quantum dot dispersed therein. The polymer comprises a polycarbonate unit and a polyester unit derived from the reaction of isophthalic acid, terephthalic acid, and resorcinol (ITR). In further embodiments, the substrate comprises two or more layers including a fluorescent layer and an overcoat layer. The fluorescent layer comprises the fluorescent dye or quantum dot and a polycarbonate polymer. The overcoat layer comprises the ITR unit. The substrate, in single layer or multiple layer form, has reduced haze levels over a prolonged period of time.
摘要翻译： 提供了一种发光太阳能收集器，其包括基板和与其可操作地连接的诸如光电池的光能转换器。 基材由包含聚合物和分散在其中的荧光染料或量子点的热塑性组合物模制而成。 聚合物包含聚碳酸酯单元和衍生自间苯二甲酸，对苯二甲酸和间苯二酚（ITR）的反应的聚酯单元。 在另外的实施例中，衬底包括两层或更多层，包括荧光层和覆盖层。 荧光层包括荧光染料或量子点和聚碳酸酯聚合物。 外涂层包括ITR单元。 单层或多层形式的底物在较长时间内具有降低的雾度水平。
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公开(公告)号：US07211690B2
公开(公告)日：2007-05-01
申请号：US10966774
申请日：2004-10-15
IPC分类号： C07C313/00 , C07C309/00
CPC分类号： C07C303/32 , C08K5/50 , Y10S524/912 , C07C309/06
摘要： A method for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising combining in an aqueous medium a compound of generic formula (2): wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3): (R)4P-Z (3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium.
摘要翻译： 制备通式（1）的鏻磺酸盐的方法：其中每个X独立地为卤素或氢，条件是卤素与氢的摩尔比大于约0.90; p为0或1，q和r为0至约7的整数，条件是q + r小于8，如果p不为零，则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基，该方法包括在水性介质中混合通式（2）的化合物：其中M是Li或Na，X，q，p和 r如上所定义，化学计量过量的通式（3）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”→（R） PZ（3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z是卤素，R如上定义; 和将式（1）的产物与介质分离。
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