公开(公告)号：US4828873A

公开(公告)日：1989-05-09

申请号：US194619

申请日：1988-05-16

Applicant: Fulvio J. Vara ,  Lowell R. Anderson ,  James A. Dougherty

Inventor： Fulvio J. Vara ,  Lowell R. Anderson ,  James A. Dougherty

IPC: C07C43/16 ,  C07D303/22 ,  C07D303/24 ,  C08F16/32

CPC classification number: C07D303/22 ,  C07C43/16 ,  C07D303/24 ,  C08F16/32 ,  Y10T428/26

Abstract: This invention relates to the use of rapidly curable, non-degradable protective coating compositions containing a divinylether alkene or epoxide having the formula ##STR1## wherein Y is --CH.dbd.CH-- or ##STR2## R is hydrogen or methyl and x and x' are integers each having a value of from 0 to 24, a cross-linkable base resin and a catalytic amount of a cross-linking initiator; to provide a metal or plastic coating which possesses high resistance to solvents and improved flexibility.

Abstract translation: 本发明涉及使用含有具有式“IMAGE”的二亚乙基醚烯烃或环氧化物的可快速固化的不可降解保护涂料组合物，其中Y为-CH = CH-或R为氢或甲基，x和x' 是各自具有0至24的整数，可交联的基础树脂和催化量的交联引发剂; 以提供具有高耐溶剂性和改善柔性的金属或塑料涂层。

公开(公告)号：US5360882A

公开(公告)日：1994-11-01

申请号：US192079

申请日：1994-02-04

Applicant: James A. Dougherty ,  Donald J. Shugard ,  Lowell R. Anderson

Inventor： James A. Dougherty ,  Donald J. Shugard ,  Lowell R. Anderson

IPC: C08F226/06 ,  C09D4/00 ,  C08F22/40

CPC classification number: C08F226/06 ,  C09D4/00

Abstract: Eutectic compositions of vinyl caprolactam (VCL) and divinyl imidazolidone (DVI) which are liquids at room temperature are described. These compositions are useful as reactive diluents in curable coating formulations.

Abstract translation: 描述了在室温下为液体的乙烯基己内酰胺（VCL）和二乙烯基咪唑烷酮（DVI）的共晶组成。 这些组合物可用作可固化涂料制剂中的反应性稀释剂。

公开(公告)号：US5274148A

公开(公告)日：1993-12-28

申请号：US926426

申请日：1992-08-10

Applicant: James A. Dougherty ,  James V. Crivello

Inventor： James A. Dougherty ,  James V. Crivello

IPC: C07C323/20 ,  C07C381/12 ,  C07F9/90 ,  C07F9/92 ,  C08F2/00 ,  C08F2/48 ,  C08F2/54 ,  C08F4/00 ,  C09D5/20 ,  G03F7/029 ,  C07F9/02

CPC classification number: G03F7/029 ,  C07C381/12 ,  C07F9/902

Abstract: This invention relates to C.sub.14 to C.sub.20 alkoxy monophenyl sulfonium salt initiators having the formula ##STR1## wherein R is C.sub.14 to C.sub.20 alkyl; R.sub.1 and R.sub.2 are each independently C.sub.4 to C.sub.20 alkyl and X.sup.- is a non-basic, nonnucleophilic anion, which initiators are employed in the polymerization of mono- and poly- functional glycidyl ethers, alpha-olefin oxides and vinyl monomers or oligomers.

Abstract translation: 本发明涉及具有下式的C14至C20烷氧基单苯基锍盐引发剂：其中R为C14至C20烷基; R1和R2各自独立地为C4至C20烷基，X-是非碱性，非亲核阴离子，其引发剂用于单官能和多功能缩水甘油醚，α-烯烃氧化物和乙烯基单体或低聚物的聚合。

公开(公告)号：US5262449A

公开(公告)日：1993-11-16

申请号：US936470

申请日：1992-08-28

Applicant: Kolazi S. Narayanan ,  Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kolazi S. Narayanan ,  Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C07D317/36 ,  C08F2/50 ,  C09D4/00 ,  C08F16/18 ,  C08F16/32 ,  C08F24/00

CPC classification number: C07D317/36 ,  C09D4/00

Abstract: This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having the formula ##STR1## wherein R is hydrogen or lower alkyl; R' is C.sub.2 to C.sub.4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate.

Abstract translation: 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 ％的具有式“IMAGE”的反应性乙烯基或烷-1-烯基醚环碳酸酯，其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值，n'具有1至4的值和约99至约25重量％的值。 通常不溶于所述可聚合化合物或其混合物的含有鎓盐引发剂的可聚合化合物的％。 本发明还涉及组合物在基材上作为保护涂层的用途。

公开(公告)号：US5254710A

公开(公告)日：1993-10-19

申请号：US13270

申请日：1993-02-03

Applicant: Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

Inventor： Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

IPC: C07C43/23 ,  C07C69/96

CPC classification number: C07C69/96 ,  C07C43/23

Abstract: This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--; R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.

Abstract translation: 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯，其中A选自低级烷基和R'HC = CHOR-; R和R“各自独立地为具有2至20个碳原子的二价基团，并且选自亚烷基，单烷氧基或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，该基团任选地 被卤素，烷基，氰基，硝基或烷氧基取代; R'是氢或低级烷基; （n）的值为1〜10，（m）为0〜10的数值。 条件是当m为0时，R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。

公开(公告)号：US5147727A

公开(公告)日：1992-09-15

申请号：US772408

申请日：1991-10-07

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C07C43/23 ,  C07C69/96 ,  C08F2/46

CPC classification number: C07C69/96 ,  C07C43/23 ,  Y10T428/31855

Abstract: This invention relates to aryloxy polyvinyl ethers having the formula ##STR1## wherein R is a radical having from 2 to 20 carbon atoms and is selected from the group of alkylene, alkyleneoxy alkylene, polyalkyleneoxy alkylene, arylene, alkarylene, alkarylalkylene and aralkylene; X is oxygen or sulfur; A is branched or linear alkylene having from 1 to 20 carbon atoms; B is halo or lower alkyl; n has a value of from 1 to 6 and p has a value of from 0 to 4. The invention also relates to the preparation and use of said aryloxy divinyl ethers.

公开(公告)号：US5106885A

公开(公告)日：1992-04-21

申请号：US431251

申请日：1989-11-03

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C08F2/50 ,  C09D4/00

CPC classification number: C09D4/00

Abstract: What is provided herein are radiation curable compositions containing(a) multifunctional vinyl ether monomers having the formula:X--R.sub.1 --Y.sub.1 --R.sub.2 --Y.sub.2).sub.n CH.dbd.CH.sub.2 ].sub.m whereX is a 5-8 membered ring, saturated or unsaturated;R.sub.1 is a direct bond or C.sub.1 -C.sub.10 straight or branched chain alkylene;Y.sub.1 and Y.sub.2 are independently oxygen or sulfur;R.sub.2 is C.sub.2 -C.sub.10 straight or branched chain alkylene;n is 0-10; andm is 3-5;(b) a cationic initiator, and, optionally,(c) a polymerizable vinyl ether, epoxide, or acrylate oligomer.

Abstract translation: 本文提供的是包含（a）具有下式的多官能乙烯基醚单体的可辐射固化组合物：X-R1-Y1-R2-Y2）nCH = CH2] m，其中X是饱和或不饱和的5-8元环; R1是直接键或C1-C10直链或支链亚烷基; Y1和Y2独立地是氧或硫; R2是C2-C10直链或支链亚烷基; n为0-10; m为3-5; （b）阳离子引发剂，和（c）可聚合乙烯基醚，环氧化物或丙烯酸酯低聚物。

公开(公告)号：US5039716A

公开(公告)日：1991-08-13

申请号：US470489

申请日：1990-01-26

Applicant: Fulvio J. Vara ,  James A. Dougherty ,  Jeffrey S. Plotkin ,  Kolazi S. Narayanan ,  Paul D. Taylor

Inventor： Fulvio J. Vara ,  James A. Dougherty ,  Jeffrey S. Plotkin ,  Kolazi S. Narayanan ,  Paul D. Taylor

IPC: C07F7/04 ,  C08F2/46 ,  C08F8/42 ,  C08G59/40 ,  C08G65/336 ,  C09D4/00

CPC classification number: C08G65/336 ,  C07F7/045 ,  C08F8/42 ,  C08G59/4085 ,  C09D4/00

Abstract: Subject invention relates to alk-1-enyl ether silicates having the formula[X].sub.4-n Si[OR.sub.1 OCH.dbd.CH--R.sub.2 ].sub.nwhereinX is halogen or --OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen;R.sub.1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of ##STR1## wherein Y is hydrogen or methyl and R.sub.2 is each hydrogen or lower alkyl and n has a value of from 1 to 4. The invention also relates to the process for preparing the above vinyl ether silicates and to their use as chemically resistant coatings.

Abstract translation: 本发明涉及具有式[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐，其中X是卤素或-OR，其中R是低级烷基或卤素与OR的混合物， 的OR和氢或卤素和氢的混合物; R1含有1至8个碳原子，并且是亚烷基，亚烯基，亚炔基，任选被至多20个单元的烷氧基化，其中Y是氢或甲基，R 2各自为氢或低级烷基，n的值为1至 本发明还涉及制备上述乙烯基醚硅酸盐的方法及其作为耐化学腐蚀涂料的用途。

公开(公告)号：US5036112A

公开(公告)日：1991-07-30

申请号：US470488

申请日：1990-01-26

Applicant: James A. Dougherty ,  Jeffrey S. Plotkin ,  Fulvio J. Vara ,  Kolazi S. Narayanan

Inventor： James A. Dougherty ,  Jeffrey S. Plotkin ,  Fulvio J. Vara ,  Kolazi S. Narayanan

IPC: C08F2/46 ,  C09D4/00

CPC classification number: C09D4/00

Abstract: This invention relates to a cross-linkable, cationic radiation curable composition comprising (a) a non-volatile vinyl ether, epoxide, acrylate or an oligomer thereof (b) a cationic photoinitiator and (c) a divinyl ether polyacetal oligomer having the formula ##STR1## wherein n has a value of from 1 to 50;X is uniformly sulfur or oxygen;R is C.sub.2 to C.sub.4 alkeneoxy alkylene, poly(alkyleneoxy) alkylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene andR' is phenylene, diphenylene methane, diphenylene propane, xylylene, tolylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene optionally substituted with an ether, ester, carbonate, carbamate, C.sub.2 to C.sub.4 alkyleneoxy alkylene or poly(C.sub.2 to C.sub.4 alkyleneoxy) alkylene radical. The invention also relates to the composition cured on a substrate.

Abstract translation: 本发明涉及可交联的阳离子可辐射固化组合物，其包含（a）非挥发性乙烯基醚，环氧化物，丙烯酸酯或其低聚物（b）阳离子光引发剂和（c）二乙烯基醚聚缩醛低聚物， IMAGE>其中n具有1至50的值; X均匀硫或氧; R为C 2至C 4烯氧基亚烷基，聚（亚烷基氧基）亚烷基或支链，直链或环状的C 2至C 20亚烷基，R'为亚苯基，二亚苯基甲烷，二亚苯基丙烷，亚二甲苯，甲苯或支链， 任选被醚，酯，碳酸酯，氨基甲酸酯，C 2至C 4亚烷氧基亚烷基或聚（C 2至C 4亚烷氧基）亚烷基取代的C 20亚烷基。 本发明还涉及在基材上固化的组合物。

公开(公告)号：US4980428A

公开(公告)日：1990-12-25

申请号：US481084

申请日：1990-02-16

Applicant: Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

Inventor： Kou-Chang Liu ,  Fulvio J. Vara ,  James A. Dougherty

IPC: C08G59/14 ,  C08G59/62

CPC classification number: C08G59/62 ,  C08G59/1444

Abstract: This invention relates to epoxy vinyl ethers having the formula: ##STR1## wherein R is a polyvalent linear, branched or cyclic hydrocarbon radical having from 2 to 20 carbon atoms, optionally substituted with alkylenoxy; n has a value of from 1 to 20; p has a value of from 1 to 6; and at least one of Y and Y' is ##STR2## which any remaining Y and Y' can be ##STR3## The invention also relates to the synthesis and uses of the above polyphenyl vinyl ethers.

Abstract translation: 本发明涉及具有下式的环氧乙烯基醚：其中R是具有2至20个碳原子的多价直链，支链或环状烃基，任选被亚烷基氧基取代; n的值为1〜20; p的值为1到6; Y和Y'中的至少一个为“IMAGE”，任何剩余的Y和Y'可以是本发明还涉及上述聚苯基乙烯基醚的合成和用途。