Alkenyl ether polycarbonates
    2.
    发明授权
    Alkenyl ether polycarbonates 失效
    烯基醚聚碳酸酯

    公开(公告)号:US5358978A

    公开(公告)日:1994-10-25

    申请号:US13269

    申请日:1993-02-03

    CPC分类号: C07C69/96 C07C43/23

    摘要: This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--, R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.

    摘要翻译: 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯,其中A选自低级烷基和R'HC = CHOR-,R和R“各自独立地为具有2-20个碳原子的二价基团 选自亚烷基,单 - 或多 - 烷氧基化亚烷基,亚烯基,亚炔基,亚芳基,亚烷芳基和亚芳基,该基团任选被卤素,烷基,氰基,硝基或烷氧基取代; R'是氢或低级烷基; (n)的值为1〜10,(m)为0〜10的数值。 条件是当m为0时,R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。

    Alk-1-enyl ether silicates
    3.
    发明授权
    Alk-1-enyl ether silicates 失效
    烷基-1-烯基醚硅酸盐

    公开(公告)号:US5094917A

    公开(公告)日:1992-03-10

    申请号:US672249

    申请日:1991-03-20

    摘要: Subject invention relates to alk-1-enyl ether silicates having the formula[X].sub.4-n Si[OR.sub.1 OCH.dbd.CH--R.sub.2 ].sub.nwherein X is halogen or --OR wherein R is lower alkyl or a mixture of halogen and OR, a mixture of OR and hydrogen or a mixture of halogen and hydrogen;R.sub.1 contains from 1 to 8 carbon atoms and is alkylene, alkenylene, alkynylene, optionally alkoxylated with up to 20 units of ##STR1## wherein Y is hydrogen or methyl and R.sub.2 is each hydrogen or lower alkyl and n has a value of from 1 to 4. The invention also relates to the process for preparing the above vinyl ether silicates and to their use as chemically resistant coatings.

    摘要翻译: 本发明涉及具有式[X] 4-nSi [OR 1 OCH = CH-R 2] n的烷-1-烯基醚硅酸盐,其中X是卤素或-OR,其中R是低级烷基或卤素与OR的混合物, 的OR和氢或卤素和氢的混合物; R1含有1至8个碳原子,并且是亚烷基,亚烯基,亚炔基,任选被至多20个单元的烷氧基化,其中Y是氢或甲基,R 2各自为氢或低级烷基,n的值为1至 本发明还涉及制备上述乙烯基醚硅酸盐的方法及其作为耐化学腐蚀涂料的用途。

    Alkenyl ether polycarbonates
    4.
    发明授权
    Alkenyl ether polycarbonates 失效
    烯基醚聚碳酸酯

    公开(公告)号:US5254710A

    公开(公告)日:1993-10-19

    申请号:US13270

    申请日:1993-02-03

    IPC分类号: C07C43/23 C07C69/96

    CPC分类号: C07C69/96 C07C43/23

    摘要: This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--; R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.

    摘要翻译: 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯,其中A选自低级烷基和R'HC = CHOR-; R和R“各自独立地为具有2至20个碳原子的二价基团,并且选自亚烷基,单烷氧基或多烷氧基化亚烷基,亚烯基,亚炔基,亚芳基,亚烷基和亚芳基,该基团任选地 被卤素,烷基,氰基,硝基或烷氧基取代; R'是氢或低级烷基; (n)的值为1〜10,(m)为0〜10的数值。 条件是当m为0时,R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。

    Radiation curable coating compositions
    6.
    发明授权
    Radiation curable coating compositions 失效
    可辐射固化涂料组合物

    公开(公告)号:US5262449A

    公开(公告)日:1993-11-16

    申请号:US936470

    申请日:1992-08-28

    CPC分类号: C07D317/36 C09D4/00

    摘要: This invention relates to a coating composition which can be cured by exposure to radiation energy in the presence of a cationic photoinitiator. The composition comprises a mixture of between about 1 and about 75 wt. % of a reactive vinyl or alk-1-enyl ether cyclocarbonate having the formula ##STR1## wherein R is hydrogen or lower alkyl; R' is C.sub.2 to C.sub.4 alkylene; n has a value of from 0 to 4 and n' has a value of from 1 to 4 and between about 99 and about 25 wt. % of a polymerizable compound containing an onium salt initiator which is normally insoluble in said polymerizable compound or a mixture thereof. The invention also relates to the use of the composition as a protective coating on a substrate.

    摘要翻译: 本发明涉及可在阳离子光引发剂存在下通过暴露于辐射能固化的涂料组合物。 组合物包含约1至约75wt。 %的具有式“IMAGE”的反应性乙烯基或烷-1-烯基醚环碳酸酯,其中R是氢或低级烷基; R'是C 2至C 4亚烷基; n具有0至4的值,n'具有1至4的值和约99至约25重量%的值。 通常不溶于所述可聚合化合物或其混合物的含有鎓盐引发剂的可聚合化合物的%。 本发明还涉及组合物在基材上作为保护涂层的用途。

    Cross-linkable vinyl ether polyacetal oligomers
    7.
    发明授权
    Cross-linkable vinyl ether polyacetal oligomers 失效
    可交联乙烯基醚缩醛低聚物

    公开(公告)号:US5036112A

    公开(公告)日:1991-07-30

    申请号:US470488

    申请日:1990-01-26

    IPC分类号: C08F2/46 C09D4/00

    CPC分类号: C09D4/00

    摘要: This invention relates to a cross-linkable, cationic radiation curable composition comprising (a) a non-volatile vinyl ether, epoxide, acrylate or an oligomer thereof (b) a cationic photoinitiator and (c) a divinyl ether polyacetal oligomer having the formula ##STR1## wherein n has a value of from 1 to 50;X is uniformly sulfur or oxygen;R is C.sub.2 to C.sub.4 alkeneoxy alkylene, poly(alkyleneoxy) alkylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene andR' is phenylene, diphenylene methane, diphenylene propane, xylylene, tolylene, or a branched, linear or cyclic C.sub.2 to C.sub.20 alkylene optionally substituted with an ether, ester, carbonate, carbamate, C.sub.2 to C.sub.4 alkyleneoxy alkylene or poly(C.sub.2 to C.sub.4 alkyleneoxy) alkylene radical. The invention also relates to the composition cured on a substrate.

    摘要翻译: 本发明涉及可交联的阳离子可辐射固化组合物,其包含(a)非挥发性乙烯基醚,环氧化物,丙烯酸酯或其低聚物(b)阳离子光引发剂和(c)二乙烯基醚聚缩醛低聚物, IMAGE>其中n具有1至50的值; X均匀硫或氧; R为C 2至C 4烯氧基亚烷基,聚(亚烷基氧基)亚烷基或支链,直链或环状的C 2至C 20亚烷基,R'为亚苯基,二亚苯基甲烷,二亚苯基丙烷,亚二甲苯,甲苯或支链, 任选被醚,酯,碳酸酯,氨基甲酸酯,C 2至C 4亚烷氧基亚烷基或聚(C 2至C 4亚烷氧基)亚烷基取代的C 20亚烷基。 本发明还涉及在基材上固化的组合物。