公开(公告)号：US20160046546A1

公开(公告)日：2016-02-18

申请号：US14819807

申请日：2015-08-06

Applicant: THE CHEMOURS COMPANY FC LLC

Inventor： SHENG PENG ,  Mario Joseph Nappa

IPC: C07C17/25

CPC classification number: C07C17/25 ,  C07C21/18

Abstract: A method of producing a fluoropropane of formula CF3CH═CHF, comprising contacting a mixture of 1,1,1,3,3-pentafluoropropane and Z-1,3,3,3-tetrafluoropropene in the gas phase with a catalyst comprising at least one catalyst selected from the group consisting of fluorinated Cr2O3 or Cr/Ni on fluoride alumina, in the presence of an oxygen containing gas, to form a mixture comprising Z-1,3,3,3-tetrafluoropropane, E-1,3,3,3,-tetrafluoropropene, hydrogen fluoride, and optionally unreacted 1,1,1,3,3-pentafluoropropane, separating the E-1,3,3,3-tetrafluoropropene from the Z-isomer and any unreacted 1,1,1,3,3-pentafluoropropane, if present, and recovering said E-1,3,3,3-tetrafluoropropene.

Abstract translation: 一种制备式CF 3 CH = CHF氟代丙烷的方法，包括使气相中的1,1,1,3,3-五氟丙烷和Z-1,3,3,3-四氟丙烯的混合物与至少包含 在含氧气体的存在下，在氟化矾土上选自氟化Cr 2 O 3或Cr / Ni的一种催化剂，以形成包含Z-1,3,3,3-四氟丙烷，E-1,3， 3,3,3-四氟丙烯，氟化氢和任选的未反应的1,1,1,3,3-五氟丙烷，从Z-异构体中分离出E-1,3,3,3-四氟丙烯和任何未反应的1,1， 如果存在1,3,3-五氟丙烷，并回收所述E-1,3,3,3-四氟丙烯。

公开(公告)号：US20240167734A1

公开(公告)日：2024-05-23

申请号：US18426929

申请日：2024-01-30

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C17/357 ,  C07C19/08 ,  C07C21/18

CPC classification number: F25B13/00 ,  C07C17/357 ,  C07C19/08 ,  C07C21/18

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US11904301B2

公开(公告)日：2024-02-20

申请号：US17273342

申请日：2019-09-06

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui Sun ,  Mario Joseph Nappa ,  Karl Krause

IPC: B01J27/32 ,  B01J27/10 ,  C01G30/00

CPC classification number: B01J27/32 ,  B01J27/10 ,  C01G30/007

Abstract: A method of chlorinating a antimony fluorohalide catalyst is disclosed. In one embodiment the method comprises contacting an antimony fluorohalide catalyst that contains one or more fluorines with a regenerating agent chosen from 2-chloro-3,3,3-trifluoropropene (1233xf), 1,1,1,3-tetrachloropropane (250fb), 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) and combinations of 1233xf, 250fb, and 244bb, under conditions effective to exchange at least one fluorine in the antimony fluorohalide catalyst with chlorine. The method can be used to regenerate spent antimony fluorohalide catalyst, for example regenerating SbCl5 from SbF5.

公开(公告)号：US11661389B2

公开(公告)日：2023-05-30

申请号：US17285134

申请日：2019-10-10

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Viacheslav A Petrov ,  Mario Joseph Nappa ,  Robert D Lousenberg ,  Jonathan P Stehman

IPC: C07C43/16 ,  C07C41/09 ,  C09K5/04 ,  C11D7/28 ,  C11D7/50 ,  H01B3/44

CPC classification number: C07C43/16 ,  C07C41/09 ,  C09K5/048 ,  C11D7/28 ,  C11D7/5022 ,  H01B3/441

Abstract: An alkoxyvinyl ether is disclosed having the chemical structure RfC(OR)═CHRf′, wherein Rf is an at least partially fluorinated functional group having at least one carbon atom, Rf′ is an at least partially fluorinated functional group having at least two carbon atoms, and R is a functional group. A method for preparing an alkoxyvinyl ether is disclosed, comprising RfCFHCFHRf′+KOH/ROH→RfC(OR)═CHRf′, wherein Rf is a perfluoro functional group, Rf′ is a perfluoro functional group, and R is an alkyl functional group. Another method for preparing an alkoxyvinyl ether is disclosed, comprising RfCF═CHRf′+KOH/ROH→RfC(OR)═CHRf′, wherein Rf is a perfluoro functional group, Rf′ is a perfluoro functional group, and R is an alkyl functional group.

公开(公告)号：US11655406B2

公开(公告)日：2023-05-23

申请号：US17971687

申请日：2022-10-24

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Barry Asher Mahler ,  Mario Joseph Nappa

IPC: C09K5/04 ,  C07C17/04 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/04 ,  C07C21/18 ,  C08J9/14 ,  C09K3/30 ,  C09K23/00 ,  A62D1/00 ,  C09K3/00 ,  C11D7/30 ,  H01B3/56 ,  C07C17/23 ,  C09K21/08

CPC classification number: C09K5/044 ,  A62D1/0028 ,  A62D1/0057 ,  A62D1/0092 ,  C07C17/04 ,  C07C17/087 ,  C07C17/204 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/04 ,  C07C21/18 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C09K3/00 ,  C09K3/30 ,  C09K5/045 ,  C09K5/048 ,  C09K21/08 ,  C09K23/007 ,  C09K23/017 ,  C11D7/30 ,  H01B3/56 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/144 ,  C08J2203/164 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/22

Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF=CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

公开(公告)号：US11572326B2

公开(公告)日：2023-02-07

申请号：US17220427

申请日：2021-04-01

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui Sun ,  Mario Joseph Nappa ,  Karl Krause

IPC: C07C17/087 ,  C07C19/08 ,  C07C17/25 ,  C07C17/08 ,  B01J23/18 ,  B01J23/16 ,  C07C17/20 ,  C07C19/10

Abstract: A method hydrofluorinates an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, where X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo. The method includes reacting the olefin with HF in the vapor phase, in the presence of SbF5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.

公开(公告)号：US11209196B2

公开(公告)日：2021-12-28

申请号：US17193021

申请日：2021-03-05

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C17/357 ,  C07C21/18

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US20210262704A1

公开(公告)日：2021-08-26

申请号：US17193021

申请日：2021-03-05

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Sheng Peng ,  Mario Joseph Nappa

IPC: F25B13/00 ,  C07C21/18 ,  C07C17/357

Abstract: A fluoropropene composition comprising Z-1,3,3,3-tetrafluoropropene, E-1,3,3,3-tetrafluoropropene, 1,1,3,3,3-pentafluoropropene, 2,3,3,3-tetrafluoropropene, and optionally 1,1,1,3,3-pentafluoropropane wherein the 2,3,3,3-tetrafluoropropene being present in an amount of 0.00001 to 1.0%. A method of producing the fluoropropene, methods for using the fluoropropene and the composition formed are also disclosed.

公开(公告)号：US11001738B2

公开(公告)日：2021-05-11

申请号：US16747266

申请日：2020-01-20

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Barry Asher Mahler ,  Mario Joseph Nappa

IPC: C09K5/04 ,  C07C17/04 ,  C07C17/087 ,  C07C17/20 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/04 ,  C07C21/18 ,  C08J9/14 ,  C09K3/30 ,  A62D1/00 ,  B01F17/00 ,  C09K3/00 ,  C11D7/30 ,  H01B3/56 ,  C07C17/23 ,  C09K21/08

Abstract: Disclosed are compositions comprising HCFC-243db, HCFO-1233xf, HCFC-244db and/or HFO-1234yf and at least one additional compound. For the composition comprising 1234yf, the additional compound is selected from the group consisting of HFO-1234ze, HFO-1243zf, HCFC-243db, HCFC-244db, HFC-245cb, HFC-245fa, HCFO-1233xf, HCFO-1233zd, HCFC-253fb, HCFC-234ab, HCFC-243fa, ethylene, HFC-23, CFC-13, HFC-143a, HFC-152a, HFC-236fa, HCO-1130, HCO-1130a, HFO-1336, HCFC-133a, HCFC-254fb, CHF═CHCl, HFO-1141, HCFO-1242zf, HCFO-1223xd, HCFC-233ab, HCFC-226ba, and HFC-227ca. Compositions comprising HCFC-243db, HCFO-1233xf, and/or HCFC-244db are useful in processes to make HFO-1234yf. Compositions comprising HFO-1234yf are useful, among other uses, as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

公开(公告)号：US10988422B2

公开(公告)日：2021-04-27

申请号：US16847041

申请日：2020-04-13

Applicant: THE CHEMOURS COMPANY FC, LLC

Inventor： Xuehui Sun ,  Mario Joseph Nappa ,  Karl Krause

IPC: C07C19/08 ,  C07C19/10 ,  C07C21/18 ,  C07C17/087 ,  C07C17/25 ,  C07C17/20

Abstract: The disclosure relates to a method for hydrofluorination of an olefin of the formula: RCX═CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, wherein X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C1-C6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C1-C6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo, comprising reacting the olefin with HF in the liquid-phase, in the presence of SbF5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.