公开(公告)号：US4251495A

公开(公告)日：1981-02-17

申请号：US64679

申请日：1979-08-08

申请人： Andre Deschamps ,  Sigismond Franckowiak ,  Andre Sugier

发明人： Andre Deschamps ,  Sigismond Franckowiak ,  Andre Sugier

IPC分类号： B01D53/52 ,  C10K1/20 ,  B01D53/34

CPC分类号： B01D53/52 ,  C10K1/20 ,  Y10S502/517

摘要： Process for purifying a gas containing hydrogen sulfide, optionally with carbon dioxide, particularly adapted to the purification of gases of relatively low hydrogen sulfide content, e.g. not in excess of 1% of H.sub.2 S by volume, comprising contacting the gas with an absorption mass containing copper, at a temperature of from 250.degree. to 550.degree. C., to absorb the hydrogen sulfide and form copper sulfide; wherein the absorption mass is regenerated by interrupting the contact of the gas with the mass when the mass is at least partially saturated, contacting the mass with an oxidizing gas containing from 0.5 to 5% by volume of oxygen, at a temperature of from 250.degree. to 345.degree. C., to convert the copper sulfide substantially to copper sulfate, and then contacting the mass with a reducing gas containing from 5 to 20% by volume of hydrogen, at a temperature of from 300.degree. to 450.degree. C., to convert the copper sulfate substantially to sulfur dioxide and metallic copper, thereby regenerating the mass, which is then contacted again by the hydrogen sulfide containing gas.

摘要翻译： 任选地用二氧化碳净化含有硫化氢的气体的方法，特别适用于净化相对低的硫化氢含量的气体，例如， 不超过体积的H 2 S的1％，包括在250-550℃的温度下使气体与含有铜的吸收物质接触以吸收硫化氢并形成硫化铜; 其中吸收质量通过在质量至少部分饱和时中断气体与质量的接触来再生，该物质与含有0.5至5体积％氧气的氧化气体在250℃的温度下接触 至345℃，将硫化铜基本上转化为硫酸铜，然后将该物质与含有5〜20体积％氢气的还原气体在300〜450℃的温度下接触至 将硫酸铜基本上转化为二氧化硫和金属铜，从而再生质量，然后再通过含硫化氢的气体接触。

公开(公告)号：US4122110A

公开(公告)日：1978-10-24

申请号：US846486

申请日：1977-10-28

申请人： Andre Sugier ,  Edouard Freund

发明人： Andre Sugier ,  Edouard Freund

IPC分类号： B01J23/78 ,  B01J23/84 ,  C07C29/151 ,  C07C29/156 ,  C07C29/00 ,  C07C31/06 ,  C07C31/08

CPC分类号： B01J23/868 ,  B01J23/78 ,  B01J23/84 ,  B01J23/8472 ,  B01J23/8892 ,  C07C29/1512 ,  C07C29/156 ,  Y02P20/52

摘要： Alcohols, particularly linear saturated primary alcohols, are manufactured from CO and H.sub.2 in the presence of a catalyst comprising at least 4 essential elements, copper, cobalt, a third metal selected from chromium, iron, vanadium and manganese, and at least one alkali metal. A preferred method for manufacturing the catalyst is also described; it comprises the use of a complexant, such as citric acid.

摘要翻译： 醇，特别是直链饱和伯醇由CO和H 2在催化剂存在下制备，催化剂包含至少4种必需元素，铜，钴，选自铬，铁，钒和锰的第三种金属，以及至少一种碱金属 。 还描述了制造催化剂的优选方法; 它包括使用络合剂，例如柠檬酸。

公开(公告)号：US4029738A

公开(公告)日：1977-06-14

申请号：US524880

申请日：1974-11-18

申请人： Philippe Courty ,  Andre Sugier ,  Bernard Raynal ,  Georges Berrebi

发明人： Philippe Courty ,  Andre Sugier ,  Bernard Raynal ,  Georges Berrebi

IPC分类号： B01D53/94 ,  B01J21/00 ,  B01J23/86 ,  B01D53/00

CPC分类号： B01D53/945 ,  B01J21/005 ,  B01J23/866 ,  Y02T10/22

摘要： Catalyst for the decomposition of nitrogen oxides, particularly for use in catalytic exhaust boxes in view of decomposing the nitrogen oxides contained in the exhaust gases from internal combustion engines, comprising, deposited on a carrier, from 3 to 20% of an active phase of the formula Ni.sub.x (Fe.sub.y Cr.sub.z)O.sub.t, in which x has a value from 0.5 to 1.5, y + z a value from 1.5 to 3, the ratio ##EQU1## A VALUE FROM 0.01 TO 0.9 AND T A VALUE LOWER THAN 10.

摘要翻译： 考虑到分解来自内燃机的排气中含有的氮氧化物，包括沉积在载体上的活性相的3至20％，特别是用于催化排气箱中的氮氧化物的分解催化剂， 公式Nix（FeyCrz）Ot，其中x的值为0.5至1.5，y + za值为1.5至3，比率为0.01至0.9，TA值低于10。