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51 条记录 (耗时 0.018 秒)

    Preparation of diamines
    31.
    发明授权
    Preparation of diamines 失效
    二胺的制备

    公开(公告)号：US4914241A

    公开(公告)日：1990-04-03

    申请号：US206755

    申请日：1988-06-15

    申请人： Michael Hesse ,  Wolfgang Hoelderich ,  Matthias Schwarzmann

    发明人： Michael Hesse ,  Wolfgang Hoelderich ,  Matthias Schwarzmann

    IPC分类号： C07C209/60

    CPC分类号： C07C209/60 ,  Y02P20/582

    摘要： Diamines of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl, aryl, alkoxy, aralkyl or cycloalkyl and X is a group of the formula(CR.sup.4 R.sup.5).sub.m (II)where R.sup.4 and R.sup.5 have the meanings given above for R.sup.1 and m is from 1 to 12, are prepared by a process in which a diamine of the formula ##STR2## where R.sup.1, R.sup.2 and X are the groups described above, is reacted with an olefin of the formula ##STR3## where R.sup.6 and R.sup.9 are each hydrogen or alkyl which is straight-chain in the .alpha.-position, in the presence of a zeolite as a catalyst.

    摘要翻译： 式（I）的二胺其中R 1，R 2和R 3各自为氢，烷基，芳基，烷氧基，芳烷基或环烷基，X为式（CR 4 R 5）m（II）的基团，其中R 4和R 5具有 对于R1和m给出的含义为1至12的方法通过以下方法制备：其中R1，R2和X为上述基团的式（III）的二胺与 式（VI）其中R 6和R 9各自为氢或在α位为直链的烷基，在作为催化剂的沸石存在下。

    Silver catalyst and a process for its preparation
    32.
    发明授权
    Silver catalyst and a process for its preparation 失效
    银催化剂及其制备方法

    公开(公告)号：US4829043A

    公开(公告)日：1989-05-09

    申请号：US134150

    申请日：1987-12-17

    申请人： Karl-Heinz Boehning ,  Wolf D. Mross ,  Matthias Schwarzmann ,  Hans-Juergen Becker ,  Juergen Plueckhan ,  Klaus-Christian Renner

    发明人： Karl-Heinz Boehning ,  Wolf D. Mross ,  Matthias Schwarzmann ,  Hans-Juergen Becker ,  Juergen Plueckhan ,  Klaus-Christian Renner

    IPC分类号： B01J23/66 ,  C07D301/10

    CPC分类号： C07D301/10 ,  B01J23/66

    摘要： A silver catalyst containing lithium and cesium as promoters for the direct oxidation of ethylene with oxygen to give ethylene oxide is applied to a porous carrier and essentially consists of .alpha.-alumina and contains certain amounts of soluble calcium, aluminum, potassium and sodium salts. The carrier has a BET surface area of from 0.4 to 0.8 m.sup.2 /g, a pore volume of not less than 0.45 ml/g, the pores being equally accessible to cold and warm water, a bulk density of less than 700 kg/m.sup.3 and a shape which, in the reactor, provides a geometrical surface area of not less than 600 m.sup.2 /m.sup.3, on which more than 13% by weight of silver are applied as active component and more than 115 kg of silver are available per m.sup.3 of reactor, and from 100 to 300 ppm by weight of lithium and from 200 to 600 ppm by weight of cesium are present as promoters. A process for the preparation of the silver catalyst and its use for the oxidation of ethylene are described.

    摘要翻译： 含有锂和铯作为用于直接氧化乙烯以产生环氧乙烷的促进剂的银催化剂被施加到多孔载体上，并且基本上由α-氧化铝组成并含有一定量的可溶性钙，铝，钾和钠盐。 载体的BET表面积为0.4至0.8m2 / g，孔体积不低于0.45ml / g，孔隙对于冷和热水均等可及，堆积密度小于700kg / m 3， 在反应器中，形成不小于600m 2 / m 3的几何表面积的形状，其上以13重量％以上的银作为活性组分，每立方米反应器可获得超过115kg的银 和100〜300重量ppm的锂和200〜600重量ppm的铯作为助催化剂存在。 描述了用于制备银催化剂的方法及其用于乙烯氧化的用途。

    Silver catalyst and its preparation
    33.
    发明授权
    Silver catalyst and its preparation 失效
    银催化剂及其制备

    公开(公告)号：US4740493A

    公开(公告)日：1988-04-26

    申请号：US889499

    申请日：1986-07-25

    申请人： Karl-Heinz Boehning ,  Wolf D. Mross ,  Matthias Schwarzmann ,  Hans-Juergen Becker ,  Juergen Plueckhan ,  Klaus-Christian Renner

    发明人： Karl-Heinz Boehning ,  Wolf D. Mross ,  Matthias Schwarzmann ,  Hans-Juergen Becker ,  Juergen Plueckhan ,  Klaus-Christian Renner

    IPC分类号： B01J23/66 ,  C07D301/10 ,  B01J21/04 ,  B01J23/50

    CPC分类号： B01J23/66 ,  C07D301/10

    摘要： A silver catalyst for the direct oxidation of ethylene with oxygen to give ethylene oxide is applied on a porous carrier and essentially consists of .alpha.-alumina and contains certain amounts of soluble calcium, aluminum, potassium and sodium salts. The carrier has a BET surface area of from 0.2 to 0.8 m.sup.2 /g, a pore volume of not less than 0.5 ml/g, the pores being equally accessible to cold and warm water, and a bulk density of less than 650 kg/m.sup.3, and has a shape which, in the reactor, provides a geometric surface area of not less than 600 m.sup.2 /m.sup.3, on which more than 13% by weight of silver are applied as the active component, more than 110 kg of silver being available per m.sup.3 of reactor.

    摘要翻译： 用于用氧直接氧化乙烯以产生环氧乙烷的银催化剂被施加到多孔载体上，并且基本上由α-氧化铝组成并含有一定量的可溶性钙，铝，钾和钠盐。 载体的BET表面积为0.2至0.8m2 / g，孔体积不小于0.5ml / g，孔隙对于冷和温水均等可及，并且堆积密度小于650kg / m 3 ，并且具有在反应器中提供不小于600m 2 / m 3的几何表面积的形状，其上施加超过13重量％的银作为活性组分，可获得超过110kg的银 每立方米反应堆。

    Preparation of C.sub.2 -C.sub.4 -olefins from methanol/dimethyl ether
    35.
    发明授权
    Preparation of C.sub.2 -C.sub.4 -olefins from methanol/dimethyl ether 失效
    从甲醇/二甲醚制备C 2 -C 4烯烃

    公开(公告)号：US4503281A

    公开(公告)日：1985-03-05

    申请号：US577762

    申请日：1984-02-07

    申请人： Wolfgang Hoelderich ,  Wolf D. Mross ,  Matthias Schwarzmann

    发明人： Wolfgang Hoelderich ,  Wolf D. Mross ,  Matthias Schwarzmann

    IPC分类号： B01J29/86 ,  C07C1/20

    CPC分类号： B01J29/86 ,  C07C1/20 ,  C07C2529/86 ,  Y02P30/42

    摘要： C.sub.2 -C.sub.4 -olefins are prepared by catalytic conversion of methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures, by a process in which the catalyst used is a pure borosilicate zeolite which has been tableted or extruded without a binder and treated with hydrofluoric acid and hydrochloric acid. The treatment of the catalyst with hydrofluoric acid is carried out using 0.001-1N HF, and that with hydrochloric acid is carried out using 3-25% strength acid. The time-on-stream of the catalyst is improved.

    摘要翻译： 通过在沸石催化剂存在下在高温下通过甲醇和/或二甲醚的催化转化制备C 2 -C 4 - 烯烃，其中使用的催化剂是纯硼硅酸盐沸石，其已被压片或挤出而没有粘合剂 并用氢氟酸和盐酸处理。 用氢氟酸处理催化剂使用0.001-1N HF进行催化剂，盐酸使用3-25％强度的酸进行。 提高了催化剂的时间流动性。

    Method for preparing crystalline SiO.sub.2 modification
    37.
    发明授权
    Method for preparing crystalline SiO.sub.2 modification 失效
    制备结晶SiO2改性的方法

    公开(公告)号：US4300911A

    公开(公告)日：1981-11-17

    申请号：US124988

    申请日：1980-02-27

    申请人： Laszlo Marosi ,  Joachim Stabenow ,  Matthias Schwarzmann

    发明人： Laszlo Marosi ,  Joachim Stabenow ,  Matthias Schwarzmann

    IPC分类号： C01B37/02 ,  C01B33/12 ,  B01D9/00

    CPC分类号： C01B37/02

    摘要： A crystalline SiO.sub.2 --modification, which is characterized by an X-ray diffraction diagram having certain diffraction lines, and a process for the preparation of this crystalline SiO.sub.2 --modification by crystallizing reactive amorphous SiO.sub.2 under hydrothermal conditions in the presence of hexamethylenediamine. Sodium ions, phosphate ions and/or sulfate ions may be added for the crystallization.

    摘要翻译： 特征在于具有某些衍射线的X射线衍射图的结晶SiO 2改性，以及在六亚甲基二胺的存在下在水热条件下结晶反应性无定形SiO 2来制备该结晶SiO 2改性的方法。 可以加入钠离子，磷酸根离子和/或硫酸根离子进行结晶。