公开(公告)号：US20230062801A1

公开(公告)日：2023-03-02

申请号：US17685002

申请日：2022-03-02

Applicant: FUJIFILM Corporation

Inventor： Wataru HOSHINO ,  Yuki HIRAI ,  Hiroshi MATSUYAMA ,  Naoya SHIBATA

IPC: C09K19/30 ,  C09K19/34

Abstract: Provided is a composition that is capable of forming a polarizer layer having an excellent degree of alignment and excellent adhesiveness to another layer in a case of being applied to a laminate, a polarizer layer, a laminate, and an image display device. The composition of the present invention is a composition including at least a polymer liquid crystal compound, a dichroic material, and a low-molecular-weight liquid crystal compound, in which the polymer liquid crystal compound is a copolymer having a repeating unit (1) represented by Formula (1), the low-molecular-weight liquid crystal compound is a compound represented by Formula (LC), and relationships represented by Expressions |log P(SP1)−log P(SPL1)|≤2.0 (11), |log P(MG1)−log P(SP1)|≥4.5 (12), and |log P(ML)−log P(SPL1)|≥4.0 (13) are satisfied.

公开(公告)号：US20220025266A1

公开(公告)日：2022-01-27

申请号：US17494307

申请日：2021-10-05

Applicant: FUJIFILM Corporation

Inventor： Wataru HOSHINO ,  Hiroshi MATSUYAMA

IPC: C09K19/38 ,  C09K19/60 ,  G02B5/30

Abstract: Provided is a polarizer-forming composition from which a polarizer with a high degree of alignment and excellent heat resistance can be formed, a polarizer, and an image display device. The polarizer-forming composition includes a liquid crystal compound, and a dichroic material, in which the liquid crystal compound is a polymer liquid crystal compound, and a content of a component having a number average molecular weight of 1000 or less which is contained in the polymer liquid crystal compound is in a range of 0.10% to 5.0% by mass.

公开(公告)号：US20210309915A1

公开(公告)日：2021-10-07

申请号：US17331377

申请日：2021-05-26

Applicant: FUJIFILM Corporation

Inventor： Wataru HOSHINO ,  Hiroshi MATSUYAMA

IPC: C09K19/38 ,  C09K19/60 ,  C09K19/56 ,  G02B5/30

Abstract: The present invention provides a liquid crystal composition with a light absorption anisotropic film that has a high alignment degree, a light absorption anisotropic film, a laminate, and an image display device. The liquid crystal composition contains a high-molecular weight liquid crystal compound, and a dichroic substance, where the liquid crystal compound is a copolymer having a repeating unit (1) represented by Formula (1) and a repeating unit (2) represented by Formula (2), where P1 and P2 represent the main chain of the repeating unit, L1 represents a single bond or a divalent linking group, L2 represents a single bond, a divalent alicyclic group or an aromatic group, which may have a substituent, SP1 represents a spacer group, SP2 represents an alkylene group having 10 or more atoms in the main chain, M1 represents a mesogenic group, and T1 and T2 represent a terminal group.

公开(公告)号：US20200369962A1

公开(公告)日：2020-11-26

申请号：US16992657

申请日：2020-08-13

Applicant: FUJIFILM Corporation

Inventor： Daisuke HAYASHI ,  Hiroshi MATSUYAMA ,  Keita TAKAHASHI ,  Keisuke YOSHIMASA ,  Nobuyuki AKUTAGAWA

IPC: C09K19/38 ,  C08F222/24 ,  G02B5/30

Abstract: Provided is a polymerizable liquid crystal composition used for formation of an optically anisotropic film having excellent durability, an optically anisotropic film, an optical film, a polarizing plate, and an image display device. The polymerizable liquid crystal composition contains a polymerizable liquid crystal compound represented by Formula (1) and an acidic compound, in which a pKa of the acidic compound is more than −10 and 5 or less, and a content of the acidic compound is 20 parts by mass or less with respect to 100 parts by mass of the polymerizable liquid crystal compound.

公开(公告)号：US20200347304A1

公开(公告)日：2020-11-05

申请号：US16935700

申请日：2020-07-22

Applicant: FUJIFILM Corporation

Inventor： Hiroshi MATSUYAMA ,  Wataru HOSHINO ,  Teruki NIORI

IPC: C09K19/38 ,  C09K19/20 ,  C09K19/60

Abstract: A side chain type polymer liquid crystalline compound with which a light absorption anisotropic film having a high alignment degree can be formed, which includes a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition contains a side chain type polymer liquid crystalline compound and a dichroic substance, the side chain type polymer liquid crystalline compound is a copolymer having repeating units 1 and 2, the repeating unit 1 has a mesogenic group and an electron-withdrawing group having a Hammett's substituent constant σp of greater than 0 at a terminal of the mesogenic group, and the repeating unit 2 has a mesogenic group and a group having a Hammett's substituent constant σp of 0 or less at a terminal of the mesogenic group.

公开(公告)号：US20190322937A1

公开(公告)日：2019-10-24

申请号：US16451417

申请日：2019-06-25

Applicant: FUJIFILM Corporation

Inventor： Hiroshi MATSUYAMA ,  Wataru HOSHINO ,  Teruki NIORI ,  Naoya NISHIMURA

IPC: C09K19/38 ,  C09K19/56 ,  C09K19/60 ,  G02B5/30 ,  G02F1/1335

Abstract: An object of the invention is to provide a polymer liquid crystal compound with which a light absorption anisotropic film having a high alignment degree can be formed, a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition according to an embodiment of the invention includes a polymer liquid crystal compound which contains a repeating unit represented by Formula (1) and a dichroic substance. In Formula (1), a difference between a log P value of P1, L1, and SP1 and a log P value of M1 is 4 or greater. In Formula (1), P1 represents a main chain of the repeating unit, L1 represents a single bond or a divalent linking group, SP1 represents a spacer group, M1 represents a mesogenic group, and T1 represents a terminal group.

公开(公告)号：US20190071571A1

公开(公告)日：2019-03-07

申请号：US16183011

申请日：2018-11-07

Applicant: FUJIFILM Corporation

Inventor： Yoshiaki TAKADA ,  Wataru HOSHINO ,  Ryoji GOTO ,  Jyunko IBARAKI ,  Hiroshi MATSUYAMA ,  Masatoshi MIZUMURA

IPC: C09B31/20 ,  B32B27/20 ,  B32B27/08 ,  C09B31/062 ,  G02F1/1335 ,  G02B5/30 ,  H01L51/52

Abstract: A dichroic dye compound has an excellent alignment property when used in a light absorption anisotropic film, and has excellent solubility. A coloring composition contains the dichroic dye compound having a structure represented by Formula (1). In Formula (1), A and B represent a crosslinkable group, a and b are 0 or 1, and a+b is not less than 1. L1 and L2 represent a monovalent substituent, a single bond, or a divalent linking group. Each of Ar1 to Ar3 represents an aromatic hydrocarbon group or heterocyclic group. R1 to R3 represent a monovalent substituent. k represents an integer of 1 to 4. n1, n2, and n3 represent an integer of 0 to 4. In a case where k is 1, n1+n2+n3 is not less than 0, and in a case where k is not less than 2, n1+n2+n3 is not less than 1.

公开(公告)号：US20180267368A1

公开(公告)日：2018-09-20

申请号：US15984994

申请日：2018-05-21

Applicant: FUJIFILM Corporation

Inventor： Keita TAKAHASHI ,  Hiroshi MATSUYAMA ,  Naozumi SHIRAIWA ,  Taiji KATSUMATA ,  Yuuta FUJINO ,  Hiroshi SATO ,  Kiyoshi TAKEUCHI ,  Hiroyuki HAGIO ,  Aiko YOSHIDA ,  Hiroaki NAKATSUGAWA

IPC: G02F1/1337 ,  F21V8/00 ,  C09K19/14 ,  G02F1/1335

CPC classification number: G02F1/133723 ,  C07C67/14 ,  C07C67/30 ,  C07C2601/14 ,  C09K19/14 ,  C09K19/3068 ,  C09K2019/0448 ,  C09K2219/03 ,  G02B5/3033 ,  G02B6/0056 ,  G02F1/133528 ,  G02F1/13363 ,  G02F1/133788 ,  G02F2001/133637 ,  H01L51/5281 ,  C07C69/75

Abstract: An object of the present invention is to provide an optical film having an optically-anisotropic layer having excellent durability, a polarizing plate and an image display device in which the optical film is used, a polymerizable compound used in the optical film, and a method for manufacturing a 1,4-cyclohexanedicarboxylic acid monoaryl ester. The optical film of the present invention is an optical film having at least an optically-anisotropic layer, in which the optically-anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a polymerizable compound which has a specific structure, a liquid crystal compound which has a specific structure, and a polymerization initiator.

公开(公告)号：US20180079958A1

公开(公告)日：2018-03-22

申请号：US15825737

申请日：2017-11-29

Applicant: FUJIFILM Corporation

Inventor： Takahiro OHNO ,  Makoto ISHIGURO ,  Yoshiaki HISAKADO ,  Hiroshi SATO ,  Keita TAKAHASHI ,  Naozumi SHIRAIWA ,  Taiji KATSUMATA ,  Hiroshi MATSUYAMA

IPC: C09K19/38 ,  G02B5/30 ,  C08F236/20

CPC classification number: C09K19/3823 ,  C08F236/20 ,  C09K19/3491 ,  C09K19/3497 ,  C09K19/54 ,  C09K2019/0448 ,  G02B5/3016 ,  G02B5/305 ,  G02B5/3058 ,  G02B5/3083 ,  G02F1/133528 ,  G02F1/13363 ,  G02F2001/133633 ,  G02F2001/133637 ,  G02F2001/133638 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041 ,  Y10T428/105

Abstract: The present invention is to provide an optical film having optically anisotropic layer having excellent durability, and a polarizing plate and an image display device using the same. An optical film of the present invention is an optical film having at least an optically anisotropic layer, in which the optically anisotropic layer is a layer obtained by polymerizing a polymerizable liquid crystal composition containing a predetermined liquid crystal compound and a polymerization initiator, and an extrapolated glass transition starting temperature of the optically anisotropic layer is 70° C. or higher.

公开(公告)号：US20140138580A1

公开(公告)日：2014-05-22

申请号：US14163901

申请日：2014-01-24

Applicant: FUJIFILM Corporation

Inventor： Masatoshi MIZUMURA ,  Shunya KATOH ,  Minoru UEMURA ,  Yasuhiro ISHIWATA ,  Masaru YOSHIKAWA ,  Hiroshi MATSUYAMA

IPC: C09K19/54

CPC classification number: C09K19/54 ,  C07C69/92 ,  C09K19/2007 ,  C09K19/322 ,  C09K19/3475 ,  C09K19/588 ,  C09K2019/0429 ,  C09K2019/044 ,  C09K2019/2078

Abstract: A compound represented by the following formula (1) has sufficient solubility, a wide usable concentration range, and excellent haze-lowering performance. In the formula, L1 to L6 represent a single bond, —O—, —CO—, —COO—, etc; Sp1 to Sp4 represent a single bond or alkylene of 1 to 10 carbon atoms; A1 and A2 represent trivalent or tetravalent aromatic hydrocarbon or heterocyclic; T represents the following formulae, etc; Hb represent perfluoroalkyl of 2 to 30 carbon atoms; m and n are 2 or 3; and o and p are an integer of 0 or more.

Abstract translation: 由下式（1）表示的化合物具有足够的溶解性，宽的可用浓度范围和优异的雾度降低性能。 在该式中，L 1至L 6表示单键，-O - ， - CO - ， - COO-等; Sp1至Sp4表示单键或1至10个碳原子的亚烷基; A1和A2表示三价或四价芳烃或杂环; T表示以下公式等; Hb表示2〜30个碳原子的全氟烷基; m和n为2或3; o和p为0以上的整数。