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公开(公告)号：US4314051A
公开(公告)日：1982-02-02
申请号：US146210
申请日：1980-05-05
摘要： Described herein is a process for preparing crystalline polyarylates which comprises (a) forming a crystalline polyarylate prepolymer having a reduced viscosity of from 0.05 to about 0.4 dl/g by reacting at least one diester derivative of a dihydric phenol with at least one aromatic dicarboxylic acid in the presence of a solvent, at a temperature of from about 250.degree. to about 300.degree. C., and (b) heating the prepolymer so formed below its melting point to form a crystalline polyarylate having a reduced viscosity of from about 0.45 to about 1.2 dl/g.
摘要翻译： 本文描述的是制备结晶多芳基化合物的方法，其包括（a）通过使二元酚的至少一种二酯衍生物与至少一种芳族二羧酸反应形成具有0.05至约0.4dl / g的比浓粘度的结晶多芳基化合物预聚物 在溶剂存在下，在约250℃至约300℃的温度下，和（b）加热在其熔点以下形成的预聚物以形成结晶多芳基化合物，其具有约0.45至约 1.2 dl / g。
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公开(公告)号：US5216091A
公开(公告)日：1993-06-01
申请号：US929668
申请日：1992-08-13
申请人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
发明人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00 , Y10T428/31786 , Y10T428/3179
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
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33.发明授权Process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers) 失效用聚（芳基醚）制备聚碳酸酯和/或聚芳酯嵌段共聚物的方法
公开(公告)号：US5159028A
公开(公告)日：1992-10-27
申请号：US700489
申请日：1991-05-15
申请人： Markus Matzner , George T. Kwiatkowski , Robert A. Clendinning , Selvaraj Savariar , Mohammad J. El-Hibri , Charles N. Merriam , Robert J. Cotter
发明人： Markus Matzner , George T. Kwiatkowski , Robert A. Clendinning , Selvaraj Savariar , Mohammad J. El-Hibri , Charles N. Merriam , Robert J. Cotter
IPC分类号： C08G81/00
CPC分类号： C08G81/00
摘要： The invention describes a novel process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers). The process is comprised of the steps:(a) the reaction of a dihydroxy-terminated poly(aryl ether) oligomer with a high molecular weight polycarbonate, or a high molecular weight polyarylate, or a high molecular weight poly(arylate-carbonate) to yield a block copolymer; followed by(b) the coupling of the material obtained in step (a) to the required molecular weight, using a diaryl ester of carbonic acid or of a dicarboxylic acid.Both steps are performed in the presence of a catalyst. The copolymerizations can be run in bulk under vacuum in a single or twin screw extruder. Using the above conditions high molecular weight, high quality block copolymers having a combination of excellent properties are obtained in a matter of minutes.
摘要翻译： 本发明描述了用聚（芳基醚）制备聚碳酸酯和/或聚芳酯嵌段共聚物的新方法。 该方法包括以下步骤：（a）二羟基封端的聚（芳基醚）低聚物与高分子量聚碳酸酯或高分子量聚芳酯或高分子量聚芳基酯 - 碳酸酯的反应与 得到嵌段共聚物; （b）使用碳酸或二羧酸的二芳基酯将步骤（a）中获得的材料与所需的分子量的偶联。 两个步骤都在催化剂存在下进行。 共聚可以在单螺杆或双螺杆挤出机中在真空下大量运行。 使用上述条件可以在几分钟内获得具有优异性能的组合的高分子量的高质量嵌段共聚物。
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34.发明授权Process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers) 失效用聚芳醚（ARYL ETHERS）制备聚碳酸酯和/或多烯酸酯嵌段共聚物的方法
公开(公告)号：US5077351A
公开(公告)日：1991-12-31
申请号：US332880
申请日：1989-04-03
申请人： Markus Matzner , George T. Kwiatkowski , Robert A. Clendinning , Selvaraj Savariar , Mohammad J. El-Hibri , Charles N. Merriam , Robert J. Cotter
发明人： Markus Matzner , George T. Kwiatkowski , Robert A. Clendinning , Selvaraj Savariar , Mohammad J. El-Hibri , Charles N. Merriam , Robert J. Cotter
IPC分类号： C08G65/40 , C08G63/64 , C08G63/66 , C08G64/00 , C08G64/18 , C08G64/42 , C08G65/28 , C08G75/00 , C08G75/23 , C08G81/00
CPC分类号： C08G81/00
摘要： The invention describes a novel process for the preparation of polycarbonate and/or polyarylate block copolymers with poly(aryl ethers). The process is comprised of the steps:(a) the reaction of a dihydroxy-terminated poly(aryl ether) oligomer with a high molecular weight polycarbonate, or a high molecular weight polyarylate, or a high molecular weight poly(arylate-carbonate) to yield a block copolymer; followed by(b) the coupling of the material obtained in step (a) to the required molecular weight, using a diaryl ester of carbonic acid or of a dicarboxylic acid.Both steps are performed in the presence of a catalyst. The copolymerizations can be run in bulk under vacuum in a single or twin screw extruder. Using the above conditions high molecular weight, high quality block copolymers having a combination of excellent properties are obtained in a matter of minutes.
摘要翻译： 本发明描述了用聚（芳基醚）制备聚碳酸酯和/或聚芳酯嵌段共聚物的新方法。 该方法包括以下步骤：（a）二羟基封端的聚（芳基醚）低聚物与高分子量聚碳酸酯或高分子量多芳基化合物或高分子量聚芳基酯 - 碳酸酯的反应与 得到嵌段共聚物; （b）使用碳酸或二羧酸的二芳基酯将步骤（a）中获得的材料与所需的分子量的偶联。 两个步骤都在催化剂存在下进行。 共聚可以在单螺杆或双螺杆挤出机中在真空下大量运行。 使用上述条件可以在几分钟内获得具有优异性能的组合的高分子量的高质量嵌段共聚物。
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35.发明授权Poly(aryl ether sulfone)-poly(aryl ether ketone) block copolymers block copolymers 失效聚（芳基醚砜） - 聚（芳基醚酮）嵌段共聚物嵌段共聚物
公开(公告)号：US4968758A
公开(公告)日：1990-11-06
申请号：US234760
申请日：1988-08-22
申请人： Markus Matzner , James H. Botkin , Paul A. Winslow
发明人： Markus Matzner , James H. Botkin , Paul A. Winslow
CPC分类号： C08G61/127 , C08G75/23 , Y10S525/905 , Y10S525/906
摘要： Novel poly(aryl ether sulfone)-poly(aryl ether ketone) block copolymers are described. They are prepared by the nucleophilic polycondensation of a hydroxy- or halo-terminated poly(aryl ether ketone) oligomer with the poly(aryl ether sulfone) forming reagents; alternatively, a preformed poly(aryl ether sulfone) block may be used.The novel copolymers are tough materials with excellent heat, solvent, and stress-crack resistanced. They display high HDT's (heat distortion temperatures) and are useful in molding, extrusion and composites applications.
摘要翻译： 描述了新的聚（芳基醚砜） - 聚（芳醚酮）嵌段共聚物。 它们通过羟基或卤素封端的聚（芳基醚酮）低聚物与聚（芳基醚砜）形成试剂的亲核缩聚制备; 或者，可以使用预制的聚（芳基醚砜）嵌段。 新型共聚物是具有优异的耐热，耐溶剂和耐应力裂纹性能的坚韧材料。 它们显示出高HDT（热变形温度），并且可用于成型，挤出和复合材料应用。
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公开(公告)号：US4870153A
公开(公告)日：1989-09-26
申请号：US111344
申请日：1987-10-22
CPC分类号： C08G65/4012 , C08G61/127
摘要： Described herein are novel poly(aryl ether) polymers that contain naphthalene, terephenylene and/or anthracenylene units within their chains. Representative polymers are tough materials having excellent high temperature, oxidative and chemical resistance, and easy melt fabricability.
摘要翻译： 本文描述的是在其链中含有萘，三苯基和/或蒽基单元的新型聚（芳基醚）聚合物。 代表性的聚合物是具有优异的耐高温，耐氧化和耐化学性以及易熔融可加工性的坚韧材料。
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公开(公告)号：US4668744A
公开(公告)日：1987-05-26
申请号：US787122
申请日：1985-10-15
申请人： Markus Matzner , Donald M. Papuga
发明人： Markus Matzner , Donald M. Papuga
CPC分类号： C08G61/127 , C08G63/66
摘要： Described herein are novel block copolymers wherein one block is a poly(aryl ether ketone) oligomer and the other block is a liquid crystalline polyester oligomer. Processes for the preparation of the subject copolymers are also described. The novel block copolymers display excellent mechanical properties, good high temperatures stability and excellent solvent and chemical resistance.
摘要翻译： 本文描述的是新的嵌段共聚物，其中一个嵌段是聚（芳基醚酮）低聚物，另一个嵌段是液晶聚酯低聚物。 还描述了制备目标共聚物的方法。 新型嵌段共聚物显示出优异的机械性能，良好的高温稳定性和优异的溶剂和耐化学性。
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公开(公告)号：US4536543A
公开(公告)日：1985-08-20
申请号：US537849
申请日：1983-09-30
申请人： Markus Matzner , Donald M. Papuga
发明人： Markus Matzner , Donald M. Papuga
IPC分类号： C08G65/48 , C08L25/06 , C08L51/04 , C08L55/02 , C08L71/00 , C08L71/12 , C08L81/06 , C08L61/04
CPC分类号： C08L71/00 , C08G65/485 , C08L25/06 , C08L51/04 , C08L55/02 , C08L71/123 , C08L81/06 , C08L2205/05 , Y10S525/905
摘要： Described are novel copolymers of polyphenylene oxides and poly(aryl ether)s. These copolymers are readily compatible with styrene polymers and copolymers and give tough blends.
摘要翻译： 描述了聚苯醚和聚（芳基醚）的新型共聚物。 这些共聚物容易与苯乙烯聚合物和共聚物相容，并产生韧性混合物。
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公开(公告)号：US4443581A
公开(公告)日：1984-04-17
申请号：US296870
申请日：1981-08-27
申请人： Lloyd M. Robeson , Markus Matzner
发明人： Lloyd M. Robeson , Markus Matzner
IPC分类号： C08L27/00 , C08G18/00 , C08L1/00 , C08L33/00 , C08L33/02 , C08L33/04 , C08L67/00 , C08L67/02 , C08L67/03 , C08L75/00 , C08L77/00 , C08L83/00 , C08L83/04 , C08L69/00 , C08L83/06
CPC分类号： C08L67/03
摘要： Described herein are polyarylate molding compositions having improved notched izod impact values after molding, which composition comprises a blend of a polyarylate and a siloxane-polyarylene polyether block copolymer and/or a siloxane polycarbonate block copolymer.
摘要翻译： 本文描述的是在模制之后具有改进的缺口izod冲击值的聚芳酯模塑组合物，该组合物包含多芳基化合物和硅氧烷 - 聚亚芳基聚醚嵌段共聚物和/或硅氧烷聚碳酸酯嵌段共聚物的共混物。
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40.发明授权Preparation of polyarylates from dihydric phenols, aromatic dicarboxylic acid and a chlorinating agent 失效由二元酚，芳族二羧酸和氯化剂制备多芳基化合物
公开(公告)号：US4229565A
公开(公告)日：1980-10-21
申请号：US37991
申请日：1979-05-14
申请人： Hugh C. Gardner , Markus Matzner
发明人： Hugh C. Gardner , Markus Matzner
摘要： High molecular weight, thermally stable polyarylates are prepared directly from dihydric phenols, aromatic dibasic acids and a chlorinating agent without isolating an acyl halide intermediate. An organic phosphite can be added to reduce color formation.
摘要翻译： 直接从二元酚，芳族二元酸和氯化剂直接制备高分子量，热稳定的聚芳酯，而不分离酰卤中间体。 可以加入有机亚磷酸酯以减少颜色的形成。
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