公开(公告)号：US20060048672A1

公开(公告)日：2006-03-09

申请号：US11217456

申请日：2005-09-02

申请人： Junichiro Sugimoto ,  Masaya Fujioka ,  Kazuma Goto ,  Narumi Koga ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masaya Fujioka ,  Kazuma Goto ,  Narumi Koga ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/40

摘要： In a water base ink set for ink-jet recording including a pigment-based black ink and a dye-based yellow ink, a first water-soluble dye in which a number of counter ion or ions per one molecule is not more than 3 and a hue angle h* is 95° to 105° is used, as the dye used in the yellow ink, together with a second water-soluble dye in which a number of counter ion or ions per one molecule is not more than 3 and a hue angle h* is 75° to 85°; or 30° to 70°; or 0° to 30° or 350° to 360°. When the ink set is applied to a general ink-jet printer with a simple maintenance system, the coagulation of black pigment in the printer and the blurring or bleeding on the printing paper are prevented, thereby realizing a satisfactory and complex coloring of the dye-based yellow ink.

摘要翻译： 在包含颜料系黑色油墨和染料类黄色油墨的喷墨记录用水基油墨组中，每分子数多个抗衡离子或离子数不超过3的第一水溶性染料和 作为在黄色墨水中使用的染料，使用色相角h *为95°〜105°，以及每分子数多个抗衡离子或离子数为3以下的第二水溶性染料， 色调角h *为75°至85°; 或30°至70°; 或0°至30°或350°至360°。 当将油墨组施加到具有简单维护系统的普通喷墨打印机时，防止了打印机中黑色颜料的凝结和打印纸上的模糊或渗色，从而实现了染色剂的令人满意且复杂的着色， 基于黄色墨水。

公开(公告)号：US20050235868A1

公开(公告)日：2005-10-27

申请号：US11108635

申请日：2005-04-19

申请人： Kazuma Goto ,  Narumi Koga ,  Hideto Yamazaki ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Kazuma Goto ,  Narumi Koga ,  Hideto Yamazaki ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/326 ,  C09D11/328 ,  C09D11/38 ,  C09D11/40 ,  C09D11/02

CPC分类号： C09D11/324 ,  C09D11/40

摘要： A water base ink set for ink-jet recording includes a black ink containing a negatively charged self-dispersing black pigment and a water-soluble polyvalent alcohol alkyl ether; and a yellow ink containing a water-soluble anionic yellow dye in which a number of counter ion or ions per one molecule is not more than 3, a surfactant based on amine represented by the following general formula (1), and a water-soluble polyvalent alcohol alkyl ether; R—N—(CH2CH2O)xH(CH2CH2O)yH  (1) wherein R represents an alkyl group or an alkenyl group having a number of carbons of 8 to 18, and x+y is 5 to 15. Accordingly, the water ink set in which no bleeding or no coagulation of the pigment occur is provided.

摘要翻译： 用于喷墨记录的水基油墨组包括含有带负电荷的自分散黑色颜料和水溶性多元醇烷基醚的黑色油墨; 和含有水分子性阴离子性黄色染料的黄色墨水，其中每分子中的多个抗衡离子或离子数不超过3个，由以下通式（1）表示的基于胺的表面活性剂和水溶性 多元醇烷基醚; <？in-line-formula description =“In-line Formulas”end =“lead”？> RN-（CH 2）2 H（CH 2 CH 2 CH 2）H（1）<βin-line-formula description =“In-line 式“end =”tail“？>其中R表示烷基或碳原子数为8〜18的烯基，x + y为5〜15。因此，没有渗色或无 提供颜料的凝结。

公开(公告)号：US06938999B2

公开(公告)日：2005-09-06

申请号：US10642206

申请日：2003-08-18

申请人： Narumi Koga ,  Kazuma Goto ,  Naomichi Kobayashi ,  Michiko Aoyama ,  Shunichi Higashiyama ,  Masaya Fujioka

发明人： Narumi Koga ,  Kazuma Goto ,  Naomichi Kobayashi ,  Michiko Aoyama ,  Shunichi Higashiyama ,  Masaya Fujioka

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/324 ,  C09D11/328 ,  C09D11/38 ,  G01D11/00

CPC分类号： C09D11/38

摘要： A water base ink for ink-jet recording comprises water, a coloring agent, a water-soluble organic solvent, and a benzotriazole-based metal-inactivating agent and alkanolamine. When the ink is used in an ink-jet recording apparatus which has the metal member containing nickel or nickel alloy in an ink supply passage, nickel is eluted from the metal member in an amount of not more than 50 ppm. The ink makes it possible to perform stable jetting operation for a long term without causing any deterioration of metal members of a discharge head due to the metallic corrosion and the elution of nickel into the ink.

摘要翻译： 用于喷墨记录的水性墨水包括水，着色剂，水溶性有机溶剂和苯并三唑类金属灭活剂和链烷醇胺。 当油墨用于具有在供墨通道中含有镍或镍合金的金属构件的喷墨记录装置中时，镍以不大于50ppm的量从金属构件中洗脱出来。 该油墨使得可以长时间地进行稳定的喷射操作，而不会由于金属腐蚀和镍向油墨中的溶出而导致排出头的金属构件的任何劣化。

公开(公告)号：US06790266B2

公开(公告)日：2004-09-14

申请号：US10103746

申请日：2002-03-25

申请人： Narumi Koga ,  Kazuma Goto ,  Naomichi Kobayashi ,  Michiko Aoyama ,  Shunichi Higashiyama ,  Masaya Fujioka

发明人： Narumi Koga ,  Kazuma Goto ,  Naomichi Kobayashi ,  Michiko Aoyama ,  Shunichi Higashiyama ,  Masaya Fujioka

IPC分类号： C09D1102

CPC分类号： C09D11/328 ,  C09D11/40

摘要： An ink set for ink-jet recording comprises a yellow ink, a magenta ink, and a cyan ink. Changes of colors &Dgr;EY, &Dgr;EM, &Dgr;EC of the yellow ink, the magenta ink, and the cyan ink satisfy the following relationship when the yellow ink, the magenta ink, and the cyan ink are deposited on regular paper, followed by being irradiated with light having a wavelength of 300 nm to 400 nm and an illuminance of 100 W/m2 for 30 hours by using a xenon lamp: |&Dgr;EY−&Dgr;EM|≦5, |&Dgr;EM−&Dgr;EC|≦5, |&Dgr;EC−&Dgr;EY|≦5. The ink set is excellent in color balance after the fading.

摘要翻译： 用于喷墨记录的油墨组包括黄色油墨，品红色油墨和青色油墨。 颜色的变化当黄色墨水，品红色墨水和青色墨水沉积在普通纸上时，黄色墨水，品红色墨水和青色墨水的DeltaEY，DeltaEM，DeltaEC满足以下关系，然后用光照射 通过使用氙灯，具有300nm至400nm的波长和100W / m 2的照度30小时：该油墨组在褪色之后的色彩平衡优异。

公开(公告)号：US20100141723A1

公开(公告)日：2010-06-10

申请号：US12705657

申请日：2010-02-15

申请人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： B41J2/17 ,  C09D11/02

CPC分类号： C09D11/40

摘要： A water-based ink for ink-jet recording and an ink-jet recording method allow the formation of sharp text and lines in high density black, and the formation of a high quality gradation image in which the graininess is reduced in a black image of a medium lightness to a high lightness (e.g., an achromatic image in dark gray to light gray) in ink-jet recording. The water-based ink combination for ink-jet recording comprises a black ink, and a color ink (A) and a color ink (B) that satisfy a color relationship of the following expression (I): about 120°≦|α-β|≦about 240°  (I) wherein α is the hue angle of the color ink (A) and β is the hue angle of the color ink (B).

摘要翻译： 用于喷墨记录的水性墨水和喷墨记录方法允许以高密度黑色形成尖锐的文本和线条，并且形成在黑色图像中颗粒度降低的高质量渐变图像 在喷墨记录中，具有高亮度的中等亮度（例如，深灰色至浅灰色的无彩色图像）。 用于喷墨记录的水性油墨组合包括黑色油墨和满足以下表达式（I）的颜色关系的彩色油墨（A）和彩色油墨（B）：约120°＆lt; - ＆bgr; |＆nlE;约240°（I）其中α是彩色油墨（A）的色调角和＆bgr; 是彩色墨水（B）的色调角。

公开(公告)号：US07686444B2

公开(公告)日：2010-03-30

申请号：US11403237

申请日：2006-04-13

申请人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/00

CPC分类号： C09D11/40

摘要： A water-based ink for ink-jet recording and an ink-jet recording method allow the formation of sharp text and lines in high density black, and the formation of a high quality gradation image in which the graininess is reduced in a black image of a medium lightness to a high lightness (e.g., an achromatic image in dark gray to light gray) in ink-jet recording. The water-based ink combination for ink-jet recording comprises a black ink, and a color ink (A) and a color ink (B) that satisfy a color relationship of the following expression (I): about 120°≦|α−β|≦about 240°  (I) wherein α is the hue angle of the color ink (A) and β is the hue angle of the color ink (B).

摘要翻译： 用于喷墨记录的水性墨水和喷墨记录方法允许以高密度黑色形成尖锐的文本和线条，并且形成在黑色图像中颗粒度降低的高质量渐变图像 在喷墨记录中，具有高亮度的中等亮度（例如，深灰色至浅灰色的无彩色图像）。 用于喷墨记录的水性油墨组合包括黑色油墨和满足以下表达式（I）的颜色关系的彩色油墨（A）和彩色油墨（B）：约120°＆lt; - ＆bgr; |＆nlE;约240°（I）其中α是彩色油墨（A）的色调角和＆bgr; 是彩色墨水（B）的色调角。

公开(公告)号：US07147700B2

公开(公告)日：2006-12-12

申请号：US10746429

申请日：2003-12-24

申请人： Tatsunosuke Hoshi ,  Masaya Fujioka ,  Hideo Ohira ,  Yoshito Toyoda ,  Narumi Koga ,  Shunichi Higashiyama

发明人： Tatsunosuke Hoshi ,  Masaya Fujioka ,  Hideo Ohira ,  Yoshito Toyoda ,  Narumi Koga ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/324

摘要： A water base ink for ink-jet recording comprises water, self-dispersing type carbon black, an anionic surfactant, and a nonionic surfactant. The anionic surfactant is a surfactant represented by the formula (1) and/or a surfactant represented by the formula (2). The nonionic surfactant is a surfactant represented by the formula (3) or a mixture of a surfactant represented by the formula (4) and a surfactant represented by the formula (5). No ink discharge failure occurs, the long term stability is excellent, and it is possible to obtain a high quality image without any feathering.

摘要翻译： 用于喷墨记录的水性墨水包括水，自分散型炭黑，阴离子表面活性剂和非离子表面活性剂。 阴离子表面活性剂是由式（1）表示的表面活性剂和/或由式（2）表示的表面活性剂。 非离子表面活性剂是由式（3）表示的表面活性剂或由式（4）表示的表面活性剂和由式（5）表示的表面活性剂的混合物。 不会发生墨水排出故障，长期稳定性优异，可以获得高质量的图像而不会发生羽化。

公开(公告)号：US07753999B2

公开(公告)日：2010-07-13

申请号：US11279582

申请日：2006-04-13

申请人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/40

摘要： A water-based ink for ink-jet recording enables the expression of sharp text and lines in high density black, and the formation of a high quality gradation image in which the graininess is reduced in a black image of medium to high lightness. The inks include a color ink (A) and a color ink (B) each of which independently has a lightness index L* according to the L* a* b* calorimetric system of about 60 or less. The color ink (A) and the color ink (B) satisfy the following expression (I): about 120°≦|α−β| about ≦240°  (I) wherein α is the hue angle of the color ink (A) and β is the hue angle of the color ink (B). The chroma C* of a hue obtained by the combination of the color ink (A) and the color ink (B) is about 30 or less.

摘要翻译： 用于喷墨记录的水性墨水能够以高密度黑色表现清晰的文本和线条，并且形成在中等至高亮度的黑色图像中颗粒度降低的高质量渐变图像。 油墨包括根据L * a * b *量热系统独立地具有约60或更小的亮度指数L *的彩色油墨（A）和彩色油墨（B）。 彩色油墨（A）和彩色油墨（B）满足以下表达式（I）：约120°＆lt; 约＆lt; nlE; 240°（I）其中α是彩色油墨（A）和＆bgr的色调角; 是彩色墨水（B）的色调角。 通过彩色墨水（A）和彩色墨水（B）的组合获得的色调的色度C *为约30或更小。

公开(公告)号：US07416590B2

公开(公告)日：2008-08-26

申请号：US11296430

申请日：2005-12-08

申请人： Junichiro Sugimoto ,  Masaya Fuijoka ,  Ryuji Kato ,  Narumi Koga ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masaya Fuijoka ,  Ryuji Kato ,  Narumi Koga ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/40

摘要： A water-based ink set for ink-jet recording includes at least a yellow ink, a magenta ink and a cyan ink. At least one color ink of the yellow, magenta and cyan inks includes a first ink and a second ink which have different hue angles h having therebetween the color range of the normal color of the color ink. Preferably, the yellow ink includes a greenish yellow ink having a hue angle h of about 95° to about 110° and a reddish yellow ink having a hue angle h of about 70° to about 85°; the magenta ink includes a reddish magenta ink having a hue angle h of about 0° to about 10° and a violetish magenta ink having a hue angle h of about 340° to about 350°; and the cyan ink includes a bluish cyan ink having a hue angle h of about 250° to about 260° and a greenish cyan ink having a hue angle h of about 230° to about 240°.

摘要翻译： 用于喷墨记录的水性油墨组至少包括黄色油墨，品红色油墨和青色油墨。 黄色，品红色和青色墨水中的至少一种彩色墨水包括第一墨水和第二墨水，其具有不同的色相角h，其间具有彩色墨水的正常颜色的颜色范围。 优选地，黄色油墨包括具有约95°至约110°的色调角h的浅黄色油墨和具有约70°至约85°的色相角h的红黄色油墨; 品红色油墨包括具有约0°至约10°的色调角h的红色品红色油墨和具有约340°至约350°的色相角h的紫红色品红色油墨; 并且青色墨水包括具有约250°至约260°的色调角h的蓝绿色墨水和具有约230°至约240°的色相角h的绿青色墨水。

公开(公告)号：US20060232650A1

公开(公告)日：2006-10-19

申请号：US11279582

申请日：2006-04-13

申请人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Junichiro Sugimoto ,  Masashi Tsuda ,  Ryuji Kato ,  Narumi Koga ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： G01D11/00 ,  C09D11/02

CPC分类号： C09D11/40

摘要： A water-based ink for ink-jet recording enables the expression of sharp text and lines in high density black, and the formation of a high quality gradation image in which the graininess is reduced in a black image of medium to high lightness. The inks include a color ink (A) and a color ink (B) each of which independently has a lightness index L* according to the L* a* b* calorimetric system of about 60 or less. The color ink (A) and the color ink (B) satisfy the following expression (I): about 120°≦|α−β| about ≦240°  (I) wherein α is the hue angle of the color ink (A) and β is the hue angle of the color ink (B). The chroma C* of a hue obtained by the combination of the color ink (A) and the color ink (B) is about 30 or less.

摘要翻译： 用于喷墨记录的水性墨水使得能够以高密度黑色表现尖锐的文本和线条，并且形成在中等至高亮度的黑色图像中颗粒度降低的高质量渐变图像。 油墨包括根据L * a * b *量热系统独立地具有约60或更小的亮度指数L *的彩色油墨（A）和彩色油墨（B）。 彩色墨水（A）和彩色墨水（B）满足下列表达式（I）：<？in-line-formula description =“In-line formula”end =“lead”？>约120°<= | alpha -beta | 其中α是彩色油墨（A）的色调角，β是色调角度， 彩色墨水（B）。 通过彩色墨水（A）和彩色墨水（B）的组合获得的色调的色度C *为约30或更小。