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31.发明申请Method for Producing 1,2-Diamino-3-Methylcyclohexane and/or 1,2-Diamino-4-Methylcyclohexane 失效1,2-二氨基-3-甲基环己烷和/或1,2-二氨基-4-甲基环己烷的生产方法公开(公告)号：US20090253938A1
公开(公告)日：2009-10-08
申请号：US11721588
申请日：2005-12-14
申请人： Friederike Osswald , Karl Heinz Brauch , Arnd Bottcher , Jochem Henkelmann , Frederik Van Laar , Till Gerlach
发明人： Friederike Osswald , Karl Heinz Brauch , Arnd Bottcher , Jochem Henkelmann , Frederik Van Laar , Till Gerlach
IPC分类号： C07C209/00
CPC分类号： C07C209/72 , C07C2601/14 , C07C211/36
摘要： A process for preparing 1,2-diamino-3-methylcyclohexane and/or 1,2-diamino-4-methylcyclohexane by reacting 2,3- and/or 3,4-diaminotoluene with hydrogen at elevated pressure and elevated temperature in the presence of a heterogeneous rhodium catalyst, wherein a mixture comprising 2,3- and/or 3,4-diaminotoluene, a dialkyl ether and/or alicyclic ether as a solvent and ammonia is initially charged in an autoclave in the presence of the catalyst and subsequently hydrogenated while supplying hydrogen.
摘要翻译： 通过使2,3-和/或3,4-二氨基甲苯与氢在升高的压力和升高的温度下反应制备1,2-二氨基-3-甲基环己烷和/或1,2-二氨基-4-甲基环己烷的方法， 的异相铑催化剂，其中包含2,3-和/或3,4-二氨基甲苯，二烷基醚和/或脂环族醚作为溶剂和氨的混合物最初在催化剂的存在下装入高压釜中，随后 氢化同时供应氢气。
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公开(公告)号：US07034181B1
公开(公告)日：2006-04-25
申请号：US10130821
申请日：2000-11-27
申请人： Roland Götz , Norbert Götz , Michael Keil , Bernd Wolf , Adrian Steinmetz , Armin Stamm , Jochem Henkelmann
发明人： Roland Götz , Norbert Götz , Michael Keil , Bernd Wolf , Adrian Steinmetz , Armin Stamm , Jochem Henkelmann
IPC分类号： C07C51/58
摘要： The invention relates to a method for producing o-chloromethyl benzoic acid chlorides of formula (I), in which R1 to R4 can be the same or different and represent hydrogen C1–C4 alkyl, halogen or trifluoromethyl, by reaction benzo condensed lactones of formula (II), in which R1 to R4 have the above-mentioned meaning, with thionyl chloride. The inventive method is characterized in that the reaction is carried out in the presence of catalytic quantities of a Lewis acid and in the presence of catalytic quantities of a phosphine derivative.
摘要翻译： 本发明涉及一种制备式（I）的邻氯甲基苯甲酰氯的方法，其中R 1至R 4可以相同或不同，表示氢 C 1 -C 4烷基，卤素或三氟甲基，通过反应式（II）的苯并稠合内酯，其中R 1至R 4， SUP> 4 具有上述含义，与亚硫酰氯。 本发明的方法的特征在于反应在催化量的路易斯酸存在下和在催化量的膦衍生物的存在下进行。
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公开(公告)号：US20050113602A1
公开(公告)日：2005-05-26
申请号：US10977449
申请日：2004-11-01
CPC分类号： C07F9/4015
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel and (b) a phosphine having at least two trivalent phosphorus atoms and/or (c) a phosphine having one trivalent phosphorus atom and the alkyne is added only after the phosphonic acid derivative has been brought into contact with the catalyst complex system for at least one minute.
摘要翻译： 在催化剂络合物体系存在下使膦酸衍生物与炔烃反应制备烯基膦酸衍生物的方法，其中催化剂络合物体系包含（a）镍和（b）具有至少两个三价磷原子的膦和/ 或者（c）仅在使膦酸衍生物与催化剂络合物体系接触至少1分钟后才加入具有一个三价磷原子的膦和炔烃。
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公开(公告)号：US20050113593A1
公开(公告)日：2005-05-26
申请号：US10977436
申请日：2004-11-01
CPC分类号： C07F9/4015
摘要： Process for preparing an alkenylphosphonic acid derivative by reacting a phosphonic acid derivative with an alkyne in the presence of a catalyst complex system, wherein the catalyst complex system comprises (a) nickel, (b) a phosphine having at least two trivalent phosphorus atoms and in addition (c) a phosphine having one trivalent phosphorus atom.
摘要翻译： 在催化剂络合物体系存在下使膦酸衍生物与炔烃反应制备链烯基膦酸衍生物的方法，其中所述催化剂络合物体系包含（a）镍，（b）具有至少两个三价磷原子的膦和 加入（c）具有一个三价磷原子的膦。
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公开(公告)号：US06464954B2
公开(公告)日：2002-10-15
申请号：US09529404
申请日：2000-04-26
IPC分类号： C01B15023
CPC分类号： C01B15/013 , C01B15/023 , C07C37/07 , C07C2603/24 , C07C39/12
摘要： A process for hydrogenating an anthraquinone compound or a mixture of two or more thereof utilizes specific catalysts comprising, as active metal, a metal of transition group VIII of the Periodic Table of the Elements.
摘要翻译： 用于氢化蒽醌化合物或其两种或更多种的混合物的方法利用包含作为活性金属的元素周期表第八族金属的特定催化剂。
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公开(公告)号：US06369282B1
公开(公告)日：2002-04-09
申请号：US09577127
申请日：2000-05-24
申请人： Alois Kindler , Thomas Preiss , Jochem Henkelmann
发明人： Alois Kindler , Thomas Preiss , Jochem Henkelmann
IPC分类号： C07C3118
CPC分类号： C07C29/42 , C07C33/044 , C07C33/046
摘要： The process for preparing alkynediols of the formula (I) R1R2C(OH)—C≡C—C(OH)R1R2 (I) where R1, R2 are each independently H, or a C1-20-hydrocarbon radical which may be substituted by one or more C1-6-alkyls and/or be interrupted by nonadjacent heteroatoms and/or contain C—C double or triple bonds, by reacting compounds of the formula (II) R1—C(═O)—R2 (II) with acetylene in a polar aprotic solvent is carried out in the presence of basic alkali metal salts as catalysts.
摘要翻译： 制备式（I）的炔二醇的方法，其中R 1，R 2各自独立地为H，或可被一个或多个C 1-6 - 烷基取代和/或被不相邻的杂原子中断的C 1-20烃基和/ 或含有CC双键或三键，通过使式（II）化合物与极性非质子溶剂中的乙炔反应，在碱性碱金属盐作为催化剂的存在下进行。
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公开(公告)号：US06353127B1
公开(公告)日：2002-03-05
申请号：US09830349
申请日：2001-04-25
申请人： Armin Stamm , Jakob Fischer , Jochem Henkelmann , Wolfgang Siegel
发明人： Armin Stamm , Jakob Fischer , Jochem Henkelmann , Wolfgang Siegel
IPC分类号： C07C25500
CPC分类号： C07C253/30 , C07C255/10 , C07C255/35
摘要： The invention relates to a process for the preparation of &agr;-chloronitriles by reaction of cyanohydrins of aldehydes or ketones with phosgene using a phosphine oxide as catalyst.
摘要翻译： 本发明涉及通过使用氧化膦作为催化剂使醛或酮与氰基氰醇反应制备α-氯腈的方法。
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公开(公告)号：US06337425B1
公开(公告)日：2002-01-08
申请号：US09646186
申请日：2000-09-14
申请人： Armin Stamm , Jochem Henkelmann
发明人： Armin Stamm , Jochem Henkelmann
IPC分类号： C07C1702
摘要： In a process for chlorinating ketones which, apart from the carbonyl group, are inert in respect of triarylphosphine dichlorides, except for cyclopropyl methyl ketone, in which the ketones are reacted with a chlorinating agent in the presence of triarylphosphine oxides, the amount of triarylphosphine oxide is from 0.1 to 10 mol %, based on the amount of ketone. The ketones preferably have a least one CH-acid proton in the &agr; position to the carbonyl group.
摘要翻译： 在氯化酮的过程中，除了在三芳基氧化膦存在下酮与氯化剂反应的环丙基甲基酮以外，除了羰基外，它们是三芳基膦二氯化物是惰性的，三芳基氧化膦 基于酮的量为0.1〜10摩尔％。 酮优选在羰基的α位置具有至少一个CH-酸质子。
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公开(公告)号：US06297407B1
公开(公告)日：2001-10-02
申请号：US09744437
申请日：2001-01-24
IPC分类号： C07C3118
CPC分类号： C07C29/42 , C07C33/042 , C07C33/044
摘要： The invention relates to a method for producing alkyne diols by reacting ketones with acetylenic hydrocarbons in an organic solvent in the presence of a base which contains potassium alcoholates of primary and/or secondary alcohols. The alkyne diols are produced while forming adducts which precipitate out of the reaction mixture and which are comprised of alkyne monoalcohols and/or alkyne diols and a base. The stoichiometries of the reaction partners are selected such that gelatinous adducts are formed which comprise a spherical surface, whereby the reaction mixture remains agitable during the entire reaction.
摘要翻译： 本发明涉及一种在含有伯醇和/或仲醇的醇钾的碱存在下，通过酮与炔烃在有机溶剂中反应制备炔烃的方法。 产生炔二醇，同时形成从反应混合物中沉淀的加合物，其由炔一醇和/或炔二醇和碱组成。 选择反应伴侣的化学计量，使得形成包含球形表面的凝胶状加合物，由此在整个反应期间反应混合物保持敏感。
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40.发明授权
公开(公告)号：US5840986A
公开(公告)日：1998-11-24
申请号：US923557
申请日：1997-09-04
IPC分类号： C07D295/04 , B01J31/26 , C07C209/60 , C07C211/08 , C07C211/23 , C07C211/25 , C07C211/26 , C07C211/43 , C07C211/54 , C07C209/26
CPC分类号： C07C209/60
摘要： A process for preparing N-alkyl-substituted aminoalkynes by reacting an alkyne with a carbonyl compound and an amine with heterogeneous catalysis in which an unsupported copper acetylide derived from malachite is used as the catalyst. The N-alkyl-substituted aminoalkyne have a wide variety of uses including their use as precursors for pharmaceuticals, their use in electroplating processes and their use as corrosion inhibitors.
摘要翻译： 通过使炔与羰基化合物和胺与非均相催化反应制备N-烷基取代的氨基炔烃的方法，其中使用源自孔雀石的未负载的乙炔化铜作为催化剂。 N-烷基取代的氨基炔具有多种用途，包括它们作为药物前体的用途，它们在电镀方法中的应用及其作为腐蚀抑制剂的用途。
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