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    Method of making alpha, omega-diiodoperfluoroalkanes
    3.
    发明授权
    Method of making alpha, omega-diiodoperfluoroalkanes 有权
    制备α，ω-二碘全氟烷烃的方法

    公开(公告)号：US09212119B2

    公开(公告)日：2015-12-15

    申请号：US14434981

    申请日：2013-10-09

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： Steven J. Martin ,  Luke T. Dressel ,  Aaron E. Hutt ,  Eric A. Schotz ,  Terence D. Spawn ,  Miguel A. Guerra ,  Tatsuo Fukushi ,  Jeremy A. Miller ,  Christopher M. Geise ,  James A. McDonell

    IPC: C07C21/18 ,  C07C45/58 ,  C07C17/26 ,  C07C17/093

    CPC classification number: C07C45/58 ,  C07C17/00 ,  C07C17/093 ,  C07C17/26 ,  C07C19/16

    Abstract: A method of making α,ω-diiodoperfluoroalkanes includes combining: diatomic iodine, at least one perfluoroalkylene oxide represented by the formula wherein Rf represents a perfluoroalkyl group; and at least one of: a) a first metallic compound comprising nickel, and a second metallic compound comprising molybdenum that is compositionally different from the first metallic compound; or b) a metallic alloy comprising from 50 to 70 percent by weight of nickel and from 20 to 40 percent by weight of molybdenum, based on the total weight of the metallic alloy, thereby producing at least one product represented by the formula I(CF2)nI, wherein n independently represents an integer in the range of from 1 to 11. The total weight of the at least one product wherein n is 3 or greater exceeds the total weight of the at least one product wherein n is 1 or 2 by a factor of at least 4.

    Abstract translation: 制备α，ω-二碘全氟烷烃的方法包括组合：双原子碘，至少一种由下式表示的全氟氧化烯，其中Rf表示全氟烷基; 和至少一种：a）包含镍的第一金属化合物和包含与第一金属化合物成分不同的钼的第二金属化合物; 或b）金属合金，其包含基于金属合金的总重量的50-70重量％的镍和20至40重量％的钼，由此产生至少一种由式I表示的产物（CF 2 ）nI，其中n独立地表示1至11范围内的整数。其中n为3或更大的至少一种产物的总重量超过至少一种产物的总重量，其中n为1或2，其中n为1或2， 至少4的因素。

    SYNTHESIS OF METAL ALKOXIDES
    5.
    发明申请
    SYNTHESIS OF METAL ALKOXIDES 有权
    金属烷氧化物的合成

    公开(公告)号：US20140336406A1

    公开(公告)日：2014-11-13

    申请号：US13889399

    申请日：2013-05-08

    Applicant: John E. STAUFFER

    Inventor： John E. STAUFFER

    IPC: C07C67/08

    CPC classification number: C07C67/08 ,  C07C17/00 ,  C07C17/093 ,  C07F7/00 ,  C07F7/188 ,  C07F7/28 ,  C07C69/40 ,  C07C19/043

    Abstract: A process for preparing metal alkoxides starting with a metal chloride and esters of either succinic acid or glutaric acid to produce metal alkoxide, an acid anhydride and alkyl chloride. Esterification of the acid anhydride with alcohol regenerates the ester of organic acid. The first step is carried out under anhydrous conditions. By regenerating the organic acid esters in the process, the only byproduct is an alkyl chloride.

    Abstract translation: 由金属氯化物和琥珀酸或戊二酸的酯开始制备金属醇盐以制备金属醇盐，酸酐和烷基氯的方法。 酸酐与醇的酯化再生有机酸的酯。 第一步是在无水条件下进行。 通过在该方法中再生有机酸酯，唯一的副产物是烷基氯。

    PROCESSES FOR THE PRODUCTION OF FLUOROPROPANES AND HALOPROPENES AND AZEOTROPIC COMPOSITIONS OF 2-CHLORO-3,3,3-TRIFLUORO-1-PROPENE WITH HF AND OF 1,1,1,2,2-PENTAFLUOROPROPANE WITH HF
    6.
    发明申请
    PROCESSES FOR THE PRODUCTION OF FLUOROPROPANES AND HALOPROPENES AND AZEOTROPIC COMPOSITIONS OF 2-CHLORO-3,3,3-TRIFLUORO-1-PROPENE WITH HF AND OF 1,1,1,2,2-PENTAFLUOROPROPANE WITH HF 有权

    公开(公告)号：US20100072415A1

    公开(公告)日：2010-03-25

    申请号：US12444470

    申请日：2007-10-31

    Applicant: Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    Inventor： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC: C09K5/06 ,  C07C21/18 ,  C07C19/08 ,  C07C17/20

    CPC classification number: C07C17/21 ,  B01J23/26 ,  B01J23/864 ,  B01J37/26 ,  C07C17/00 ,  C07C17/087 ,  C07C17/20 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/35 ,  C07C19/08 ,  C07C21/18

    Abstract: A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CHClCH2X, halopropenes of the formula CClX2CCl═CH2 and halopropenes of the formula CX2═CClCH2X, wherein each X is independently F or Cl, with HF in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2 and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture. Also disclosed is a process for making CF3CH2CHF2, CF3CH═CHF and/or CF3CH═CHCl. This process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CHClCH2X, halopropenes of the formula CX3CCl═CH2 and halopropenes of the formula CX2═CClCH2X, wherein each X is independently F or Cl, with HF in a reaction zone to produce a product mixture comprising HF, HCl, CF3CH2CHF2, CF3CH═CHF and CF3CH═CHCl; and recovering the CF3CH2CHF2, CF3CH═CHF and/or CF3CH═CHCl from the product mixture. Also disclosed is a process for making CF3CF2CH3 and/or CF3CF═CH2. This process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CHClCH2X, halopropenes of the formula CX3CCl═CH2 and halopropenes of the formula CX2═CClCH2X, wherein each X is independently F or Cl, with HF in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3 and CF3CF═CH2; and recovering the CF3CF2CH3 and/or CF3CF═CH2 from the product mixture. In each of the processes the molar ratio of HF to total amount of starting material fed to the reaction zone is at least stoichiometric. Also disclosed is an azeotropic composition comprising CF3CCl═CH2, and HF. Also disclosed is an azeotropic composition comprising CF3CF2CH3, and HF.

    1,2,3,3,3-Pentafluoropropene Production Processes
    8.
    发明申请
    1,2,3,3,3-Pentafluoropropene Production Processes 有权
    1,2,3,3,3-五氟丙烯生产工艺

    公开(公告)号：US20090264690A1

    公开(公告)日：2009-10-22

    申请号：US12301065

    申请日：2007-06-22

    Applicant: Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    Inventor： Velliyur Nott Mallikarjuna Rao ,  Mario Joseph Nappa ,  Allen Capron Sievert

    IPC: C07C17/23

    CPC classification number: C09K5/045 ,  C07C17/00 ,  C07C17/087 ,  C07C17/206 ,  C07C17/23 ,  C07C17/354 ,  C07C19/08 ,  C07C19/10 ,  C07C21/18

    Abstract: A process is disclosed for making CF3CF═CHF. The process involves reacting CF3CClFCCl2F with H2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF3CF═CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H2 to CF3CClFCCl2F fed to the reaction zone is between about 1:1 and about 5:1.Also disclosed are azeotropic compositions of CF3CClFCCl2F and HF and azeotropic composition of CF3CHFCH2F and HF.

    Abstract translation: 公开了制备CF 3 CF-CHF的方法。 该方法包括在反应区中在催化剂存在下使CF 3 CClFCCl 2 F与H 2反应，生成包含CF 3 CF-CHF的产物混合物。 催化剂具有负载在选自氧化铝，氟化氧化铝，氟化铝及其混合物的载体上的催化有效量的钯，并且进料至反应区的H 2与CF 3 CClFCCl 2 F的摩尔比为约1:1至约 5：1。 还公开了CF 3 CClFCCl 2 F和HF的共沸组合物和CF 3 CHFCH 2 F和HF的共沸组合物。

    Synthesis of hydrofluoroalkanols and hydrofluoroalkenes
    9.
    发明申请
    Synthesis of hydrofluoroalkanols and hydrofluoroalkenes 有权
    氢氟烷醇和氢氟烯烃的合成

    公开(公告)号：US20090143604A1

    公开(公告)日：2009-06-04

    申请号：US12274728

    申请日：2008-11-20

    Applicant: Mario Joseph Nappa ,  Xuehui Sun ,  Lev Moiseevich Yagupolskii ,  Andrey Anatolievich Filatov ,  Vladimir Nikolaevich Boiko ,  Yurii Lvovich Yagupolskii

    Inventor： Mario Joseph Nappa ,  Xuehui Sun ,  Lev Moiseevich Yagupolskii ,  Andrey Anatolievich Filatov ,  Vladimir Nikolaevich Boiko ,  Yurii Lvovich Yagupolskii

    IPC: C07F3/06 ,  C07C17/26 ,  C07C69/02

    CPC classification number: C07C17/00 ,  C07C17/2637 ,  C07C29/40 ,  C07C29/68 ,  C07C31/24 ,  C07C67/08 ,  C07C69/003 ,  C07F3/003 ,  C07C21/18 ,  C07C69/63 ,  C07C31/34

    Abstract: Described herein is a process for the manufacture of hydrofluoroalkanols of the structure RfCFClCHROH, comprising reacting a halofluorocarbon of the structure RfCFX2, wherein each X is independently selected from Cl, Br, and I, with an aldehyde and a reactive metal in a reaction solvent to generate a reaction product comprising a metal hydrofluoroalkoxide, neutralizing said metal hydrofluoroalkoxide to produce a hydrofluoroalkanol, and recovering the hydrofluoroalkanol. Also described herein are methods of manufacturing hydrofluoroalkenes of the structure RfCF═CHR from halofluorocarbons of the structure RfCFX2, wherein each X is independently selected from Cl, Br, and I, comprising (1) reacting halofluorocarbons of the structure RfCFX2, wherein each X is independently selected from Cl, Br, and I, with an aldehyde and a reactive metal to generate a reaction product comprising a metal hydrofluoroalkoxide, and reductively dehydroxyhalogenating said metal hydrofluoroalkoxide to produce a hydrofluoroalkene or (2) reacting a hydrofluoroalkanol of the structure RfCFXCHROH or a hydrofluoroalkoxide of the structure RfCFXCHROMX, wherein M is a reactive metal in the +2 oxidation state, with a carboxylic acid anhydride and a reactive metal in a reaction solvent to form a hydrofluoroalkene and isolating the hydrofluoroalkene. In particular, 2,3,3,3,-tetrafluoro-1-propene may be manufactured with this process. Also described are compounds of the formula RfCFClCHROC(═O)R′.

    Abstract translation: 本文描述了制备结构RfCFClCHROH的氢氟烷醇的方法，包括使结构RfCFX2的卤氟烃，其中每个X独立地选自Cl，Br和I与反应溶剂中的醛和反应性金属反应 产生包含金属氢氟烷氧化物的反应产物，中和所述金属氢氟烷氧化物以产生氢氟烷醇，并回收氢氟烷醇。 本文还描述了由结构RfCFX2的卤代氟化物制备结构RfCF-CHR的氢氟烯烃的方法，其中每个X独立地选自Cl，Br和I，其包括（1）使结构RfCFX2的卤代碳氟化合物，其中每个X是 独立地选自Cl，Br和I，与醛和活性金属反应生成包含金属氢氟烷氧化物的反应产物，还原性地将所述金属氢氟烷氧化物脱羟基卤化以产生氢氟烯烃，或（2）使结构RfCFXCHROH的氢氟烷醇或 结构RfCFXCHROMX的氢氟烷氧化物，其中M是+2氧化态的活性金属，在反应溶剂中与羧酸酐和反应性金属反应形成氢氟烯烃并分离氢氟烯烃。 特别地，可以用该方法制造2,3,3,3-四氟-1-丙烯。 还描述了式RfCFClCHROC（-O）R'的化合物。

    Processes for synthesis of 1,3,3,3-tetrafluoropropene
    10.
    发明授权
    Processes for synthesis of 1,3,3,3-tetrafluoropropene 有权
    合成1,3,3,3-四氟丙烯的方法

    公开(公告)号：US07371904B2

    公开(公告)日：2008-05-13

    申请号：US11118504

    申请日：2005-04-29

    Applicant: Jing Ji Ma ,  Sudip Mukhopadhyay ,  Haridasan K. Nair ,  Hsueh S. Tung ,  Michael Van Der Puy

    Inventor： Jing Ji Ma ,  Sudip Mukhopadhyay ,  Haridasan K. Nair ,  Hsueh S. Tung ,  Michael Van Der Puy

    IPC: C07C21/18 ,  C07C17/26 ,  C07C17/263 ,  C07C17/269

    CPC classification number: C07C17/206 ,  C07C17/00 ,  C07C17/26 ,  C07C17/269 ,  C07C17/272 ,  C07C17/278 ,  C07C21/18

    Abstract: Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H═CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH═CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).

    Abstract translation: 公开了一种用于合成1,3,3,3-四氟丙烯的方法，其包括在一个实施方案中使CF 3 N 1 X 1的化合物与 CX 2 H-CHX 3其中X 1，X 2和X 3， SUP>各自独立地选自氟，氯，溴和碘，以产生包含CF 3 CH-CH 3 3的化合物的反应产物，其中 X 3如上所述; 当X 3不是氟时，氟化该化合物以产生1,3,3,3-四氟丙烯。 在另一个实施方案中的方法包括制备四氟丙烯，其包括热裂化一种或多种能够产生反应混合物的化合物，所述化合物优选包含二氟甲基和偏二氟乙烯，并将所述反应混合物转化为四氟丙烯（1,3,3,3-四氟丙烯）。

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