公开(公告)号：US20050202967A1

公开(公告)日：2005-09-15

申请号：US11073618

申请日：2005-03-08

申请人： Frank Hoefer ,  Norbert Asprion ,  Iven Clausen ,  Hans Hasse

发明人： Frank Hoefer ,  Norbert Asprion ,  Iven Clausen ,  Hans Hasse

IPC分类号： B01D53/14 ,  C05F17/00 ,  B01J20/22

CPC分类号： B01D53/1493 ,  Y02C10/08 ,  Y02E50/343 ,  Y02W30/43

摘要： A description is given of an absorption medium for deacidifying fluid streams which has improved oxidation stability and comprises at least one aliphatic amine, in particular an alkanolamine, and at least one non-hydroquinoid antioxidant. The absorption medium serves for deacidifying a fluid stream, in particular an oxygen-containing fluid stream, the fluid stream being brought into intimate contact with the absorption medium in at least one absorption step.

摘要翻译： 给出了一种用于脱酸流体物流的吸收介质，其具有改善的氧化稳定性，并且包含至少一种脂族胺，特别是链烷醇胺和至少一种非氢醌抗氧化剂。 吸收介质用于使流体流，特别是含氧流体流脱酸，在至少一个吸收步骤中使流体流与吸收介质紧密接触。

公开(公告)号：US06939393B2

公开(公告)日：2005-09-06

申请号：US10343001

申请日：2001-07-24

申请人： Norbert Asprion ,  Christoph Grossmann

发明人： Norbert Asprion ,  Christoph Grossmann

IPC分类号： B01D3/00 ,  B01D11/04 ,  B01D53/14

CPC分类号： B01D53/1493 ,  B01D53/1456

摘要： A description is given of the use of an alkylenediamine of the type R1HN—X—NHR2, where X is an alkylene radical having from 2 to 9 carbons, R1 is a hydrocarbon radical having from 1 to 6 carbons and R2 is a hydrocarbon radical having from 1 to 6 carbons or is hydrogen (H) for removing sour gases from a sour-gas-containing fluid stream, and of a process for deacidifying a fluid stream of this type and a wash liquid or absorption liquid for use in such a process. According to the invention, in at least one absorption step, the fluid stream is brought into intimate contact with a wash liquid, the wash liquid comprising an aqueous amine solution which comprises at least one tertiary aliphatic alkanolamine having from 2 to 12 carbons and an activator of the above type R1HN—X—NHR2. The fluid stream which is substantially freed from sour gases and the sour-gas-loaded wash liquid are then separated from one another.

摘要翻译： 给出了使用R 1 HN-X-NHR 2 N型亚烷基二胺的方法，其中X是具有2至9个碳的亚烷基，R 1是具有1至6个碳的烃基，R 2 2是具有1至6个碳的烃基或者是用于从一个或多个碳上除去酸性气体的氢（H） 含酸气流体流，以及用于使这种流体流脱酸的方法和用于这种方法的洗涤液体或吸收液体。 根据本发明，在至少一个吸收步骤中，流体物流与洗涤液体紧密接触，洗涤液体包含胺水溶液，其包含至少一种具有2至12个碳的叔脂族链烷醇胺和活化剂 的上述类型的R 1 HN-X-NHR 2。 然后将基本上不含有酸性气体的流体流和含有负载气体的洗涤液体彼此分离。

公开(公告)号：US06436174B1

公开(公告)日：2002-08-20

申请号：US09720783

申请日：2000-12-29

申请人： Christoph Grossmann ,  Karl-Heinz Hänzel ,  Dieter Kolassa ,  Norbert Asprion

发明人： Christoph Grossmann ,  Karl-Heinz Hänzel ,  Dieter Kolassa ,  Norbert Asprion

IPC分类号： B01D5314

CPC分类号： B01D53/1487 ,  B01D53/1456 ,  B01D53/1493 ,  C10K1/10 ,  C10K1/143 ,  C10L3/10

摘要： A process for removing acidic gas constituents, of the group consisting of CO2, H2S, COS, CS2 and mercaptans, from gases, in which, in an absorption step, a dirty gas rich in acidic gas constituents is brought into contact with an absorption medium, as a result of which a clean gas low in acidic gas constituents and an absorption medium laden with acidic gas constituents are obtained, the absorption medium used being a mixture comprising a) from 0.1 to 50% by weight of one or more mono-cyclic or bicyclic nitrogen heterocycles which are unsubstituted and/or monosubstituted or poly-substituted on the carbon by OH, C1-C3 alkyl and/or C1-C3 hydroxyalkyl and which have from 5 to 14 ring atoms and 1 or 2 heterocyclically bound nitrogen atoms per ring as component A, b) from 1 to 60% by weight of a monohydric and/or polyhydric alcohol as component B, c) from 0 to 60% by weight of an aliphatic aminoalcohol as component C, d) from 0 to 98.9% by weight of water as component D, e) from 0 to 35% by weight of K2CO3 as component E, where the sum of components A, B, C, D and E is 100% by weight.

摘要翻译： 从气体中除去由CO 2，H 2 S，COS，CS 2和硫醇组成的组中的酸性气体组分的方法，其中在吸收步骤中富含酸性气体成分的脏气与吸收介质接触 其结果是，获得了酸性气体成分低的清洁气体和充满酸性气体组分的吸收介质，所用吸收介质是一种混合物，其包含a）0.1至50重量％的一种或多种单环或 在碳上由OH，C1-C3烷基和/或C1-C3羟基烷基未取代和/或单取代或多取代并且每个环具有5至14个环原子和1或2个杂环结合的氮原子的双环氮杂环 作为组分A，b）1至60重量％的作为组分B的一元和/或多元醇，c）0至60重量％的作为组分C的脂族氨基醇，d）0至98.9％由 作为组分D的水的重量，e）从0到35％ 作为组分E的K 2 CO 3，其中组分A，B，C，D和E的总量为100重量％。