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    Hydroxylamine derivatives which are intermediates for making herbicidal compounds
    3.
    发明授权
    Hydroxylamine derivatives which are intermediates for making herbicidal compounds 失效
    作为制造除草剂化合物的中间体的羟甲基胺衍生物

    公开(公告)号：US5081301A

    公开(公告)日：1992-01-14

    申请号：US429160

    申请日：1989-10-30

    Applicant: Jochen Wild ,  Albrecht Harreus ,  Ulrich Schirmer ,  Norbert Meyer ,  Juergen Kast ,  Dieter Kolassa

    Inventor： Jochen Wild ,  Albrecht Harreus ,  Ulrich Schirmer ,  Norbert Meyer ,  Juergen Kast ,  Dieter Kolassa

    IPC: C07C239/20 ,  C07C323/19 ,  C07D209/48

    CPC classification number: C07D209/48 ,  C07C239/20

    Abstract: Hydroxylamine derivatives have the general formula IAryl--A--O--B IwhereAryl is an unsubstituted or substituted, mononuclear or binuclear, isocyclic radical;A is a 1,4-butenylene group of the general formulae IIa or IIb ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each hydrogen, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkenyl;B is NH.sub.2 or a dicarboximide group of the general formula III ##STR2## where Z is unsubstituted or substituted phenylene, naphthylene, pyridinylene, cyclopentylene, cyclohexylene, cyclohexenylene, C.sub.2 -C.sub.4 -alkenylene or C.sub.2 -C.sub.4 -alkylene. The dicarboximides are intermediates for the compounds wherein B is NH.sub.2. The latter are used in synthesizing herbicidal compounds.

    Abstract translation: 羟胺衍生物具有通式I Aryl-A-O-B I，其中芳基是未取代或取代的单核或双核，环状基团; A是通式IIa或IIb的1,4-亚丁烯基IIa其中R 1，R 2，R 3，R 4和R 5各自是氢，卤素，C 1 -C 6烷基或C 1 -C 6 - 烯基; B是NH 2或通式III III的二羧酰亚胺基，其中Z是未取代或取代的亚苯基，亚萘基，亚
    苄基，亚环戊基，亚环己基，亚环己烯基，C 2 -C 4亚烯基或C 2 -C 4亚烷基。 二羧酰亚胺是其中B是NH 2的化合物的中间体。 后者用于合成除草化合物。

    Herbicidal tetrahydropyran-2,4-diones
    6.
    发明授权
    Herbicidal tetrahydropyran-2,4-diones 失效
    除草四氢吡喃-2,4-二酮

    公开(公告)号：US5389602A

    公开(公告)日：1995-02-14

    申请号：US76687

    申请日：1993-06-15

    Applicant: Juergen Kast ,  Dieter Kolassa ,  Norbert Meyer ,  Bruno Wuerzer ,  Karl-Otto Westphalen ,  Wilhelm Rademacher ,  Johann Jung

    Inventor： Juergen Kast ,  Dieter Kolassa ,  Norbert Meyer ,  Bruno Wuerzer ,  Karl-Otto Westphalen ,  Wilhelm Rademacher ,  Johann Jung

    IPC: A01N43/16 ,  A01N43/36 ,  A01N43/50 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D405/04 ,  C07D407/04 ,  C07D409/04 ,  C07D413/04 ,  C07D413/14 ,  C07D417/04 ,  A01N43/74

    CPC classification number: C07D405/04 ,  A01N43/16 ,  A01N43/36 ,  A01N43/50 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D407/04 ,  C07D409/04 ,  C07D413/04 ,  C07D413/14 ,  C07D417/04

    Abstract: Tetrahydropyran-2,4-diones of the formula ##STR1## where R.sup.1 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; substituted or unsubstituted phenyl; C.sub.1 -C.sub.6 -alkylsulfonyl; substituted or unsubstituted benzenesulfonyl; C.sub.3 -C.sub.6 -alkenylcarbonyl; or substituted or unsubstituted benzoyl;R.sup.2 is C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -haloalkyl; or C.sub.3 -C.sub.6 -cycloalkyl;A, B and D are each .dbd.CH-- or .dbd.N--;E is oxygen, sulfur or --NR.sup.7 --.R.sup.7 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkanoyl; substituted or unsubstituted benzoyl; benzyl; or substituted or unsubstituted phenyl;X is halogen; C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -alkoxy; C.sub.2 -C.sub.6 -alkenyloxy; C.sub.1 -C.sub.6 -alkylthio; C.sub.1 -C.sub.6 -alkoxycarbonyl; C.sub.2 -C.sub.6 -alkanoyloxy; substituted or unsubstituted benzyloxy; substituted or unsubstituted NR.sup.5 R.sup.6 ; formyl; C.sub.2 -C.sub.6 -alkanoyl or its imine, oxime or Schiff's base; or substituted or unsubstituted phenyl;n is 0, 1 or 2;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, phenyl, C.sub.2 -C.sub.6 -alkanoyl, benzoyl and/or benzyl;Z is oxygen or --NOR.sup.8 ; andR.sup.8 is substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.2 -C.sub.6 -haloalkynyl; or substituted or unsubstituted thenyl;their environmentally compatible salts, and agents containing them.

    Abstract translation: 其中R 1是氢的式（VI）的四氢吡喃-2,4-二酮： C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; 取代或未取代的苯基; C 1 -C 6烷基磺酰基; 取代或未取代的苯磺酰基; C 3 -C 6 - 烯基羰基; 或取代或未取代的苯甲酰基; R2是C1-C6-烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 1 -C 6 - 卤代烷基; 或C 3 -C 6 - 环烷基; A，B和D各自为= CH-或= N-; E是氧，硫或-NR7-。 R7是氢; C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C 2 -C 6烷酰基; 取代或未取代的苯甲酰基; 苄基; 或取代或未取代的苯基; X是卤素; C 1 -C 6 - 烷基; 取代或未取代的C 3 -C 6 - 环烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C1-C6-烷氧基; C 2 -C 6 - 烯氧基; C1-C6-烷硫基; C1-C6烷氧基羰基; C2-C6-烷酰氧基; 取代或未取代的苄氧基; 取代或未取代的NR5R6; 甲酰基 C2-C6-烷酰基或其亚胺，肟或席夫碱; 或取代或未取代的苯基; n为0,1或2; R 3，R 4，R 5和R 6各自为氢，C 1 -C 6 - 烷基，苯基，C 2 -C 6 - 烷酰基，苯甲酰基和/或苄基; Z是氧或-NOR8; 且R 8为取代或未取代的C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 2 -C 6 - 卤代炔基; 或取代或未取代的噻吩基; 它们与环境相容的盐和含有它们的试剂。

    Cyclohexenone derivatives and their use as herbicides
    7.
    发明授权
    Cyclohexenone derivatives and their use as herbicides 失效
    环己烯酮衍生物及其作为除草剂的用途

    公开(公告)号：US5034047A

    公开(公告)日：1991-07-23

    申请号：US572357

    申请日：1990-08-24

    Applicant: Dieter Kolassa ,  Juergen Kast ,  Thomas Kuekenhoehner ,  Norbert Meyer ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    Inventor： Dieter Kolassa ,  Juergen Kast ,  Thomas Kuekenhoehner ,  Norbert Meyer ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    IPC: A01N43/10 ,  A01N43/14 ,  A01N43/50 ,  A01N43/74 ,  A01N43/80 ,  A01N43/82 ,  C07D261/04 ,  C07D261/08 ,  C07D271/06 ,  C07D271/10 ,  C07D333/22 ,  C07D413/04

    CPC classification number: C07D271/06 ,  A01N43/10 ,  A01N43/14 ,  A01N43/50 ,  A01N43/74 ,  A01N43/80 ,  A01N43/82 ,  C07D261/04 ,  C07D261/08 ,  C07D271/10 ,  C07D333/22 ,  C07D413/04

    Abstract: Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 : hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl or substituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 : hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A: a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m: 0 or 1;B: a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n: 1, 2 or 3;Y: not denoting hydrogen when m is O, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    Abstract translation: 通式I的环己烯酮衍生物，其中取代基具有以下含义：R 1：取代或未取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，苯基，苄基或异丁基; R2：取代或未取代的C1-C6-烯基，C3-C6-烯基，C3-C6-炔基或苯基; R3：氢，C1-C6-烷基，C1-C10-烷基羰基，C1-C6-烷基磺酰基，C1-C4-三烷基甲硅烷基，C1-C4-二烷基膦酰基，C1-C4-二烷基硫代膦酰基，C3-C6-烯基，C3-C6- 烯基羰基，C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R4：氢，氰基，卤素，C1-C6-烷基或C1-C6-烷氧基羰基; A：取代或未取代的亚甲基可被氧或硫原子代替的C 1 -C 4 - 亚烷基链; m：0或1; B：含有至多2个氮原子和/或至多一个氧或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n：1,2或3; Y：当m为O时不表示氢，B为异唑-5-基，X为3-（C 3 -C 6环烷基），其环保可接受的盐，其制备方法及其作为除草剂的用途。

    Cyclohexenone compounds, their preparation and their use for controlling undesirable plant growth
    8.
    发明授权
    Cyclohexenone compounds, their preparation and their use for controlling undesirable plant growth 失效
    环己烯酮化合物，它们的制备及其用于控制​​不期望的植物生长的用途

    公开(公告)号：US4994106A

    公开(公告)日：1991-02-19

    申请号：US321063

    申请日：1989-03-09

    Applicant: Dieter Kolassa ,  Juergen Kast ,  Michael Keil ,  Ulrich Schirmer ,  Norbert Meyer ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    Inventor： Dieter Kolassa ,  Juergen Kast ,  Michael Keil ,  Ulrich Schirmer ,  Norbert Meyer ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    IPC: A01N35/10 ,  A01N43/10 ,  A01N43/80 ,  C07C45/45 ,  C07C45/67 ,  C07C45/74 ,  C07C251/42 ,  C07D275/02 ,  C07D333/28

    CPC classification number: C07D275/02 ,  A01N35/10 ,  A01N43/10 ,  A01N43/80 ,  C07C251/42 ,  C07C45/455 ,  C07C45/673 ,  C07C45/676 ,  C07C45/74 ,  C07D333/28 ,  C07C2101/16

    Abstract: Cyclohexenone compounds of the formula I ##STR1## where the substituents have the following meanings: R.sup.1 is C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkenyl, C.sub.2 -C.sub.4 -alkoxyalkyl or a radical CH.sub.2 --R.sup.3, whereR.sup.3 is a 5 ring heterocycle with one to three nitrogen atoms and/or one to two oxygen atoms and/or one sulfur atom as hetero-atoms, which may bear up to two double bonds and one or two of the following substituents: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, halogen, trifluoromethyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkylthiomethyl and/or vinyl, or phenyl which may bear one to three of the following groups: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, halogen, trifluoromethyl, nitro and/or C.sub.1 -C.sub.4 -dialkylamino, andR.sup.2 is C.sub.1 -C.sub.4 -alkyl,and their agriculturally acceptable salts, processes for their manufacture, and their use.

    Abstract translation: 式I的环己烯酮化合物其中取代基具有以下含义：R 1为C 3 -C 4 - 烯基，C 3 -C 4 - 炔基，C 2 -C 4 - 卤代烷基，C 2 -C 4 - 卤代烯基，C 2 -C 4 - 烷氧基烷基或 基团CH 2 -R 3，其中R 3是具有一至三个氮原子和/或一个至两个氧原子和/或一个硫原子作为杂原子的5环杂环，其可以带有多达两个双键和一个或两个 以下取代基：C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，卤素，三氟甲基，C 1 -C 4 - 烷氧基甲基，C 1 -C 4 - 烷硫基甲基和/或乙烯基，或可以具有一至三个 的C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，卤素，三氟甲基，硝基和/或C 1 -C 4 - 二烷基氨基，R 2是C 1 -C 4烷基， 盐，其制造方法及其用途。

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