摘要:
Method of simulating mass and heat transfer-controlled separation processes using a core-film approach to describe a transfer taking place at a phase boundary (P) in which, for iteratively solving a suitable implicit differential equation system, discretisation of a transitional area (10) of the core-film approach under consideration is carried out, thereby resulting in a differential equation system.
摘要:
Disclosed is a method for deacidifying a fluid stream containing acidic gases as contaminants, according to which the fluid stream is brought into intimate contact with a washing liquid in at least one absorption step. Said washing liquid represents an aqueous solution containing a) tertiary aliphatic alkanolamines (alkanolamine A), at least 30 percent by weight of said tertiary aliphatic alkanolamines being 3-dimethylamino-1-propanol, and b) secondary aliphatic amines (activator B), at least 20 percent by weight of said secondary aliphatic amines being piperazin. The fluid stream which has been essentially purified of the acidic gases is then separated from the washing liquid that is loaded with acidic gases.
摘要:
A process is described for removing acid gases from a gas stream in which an acid-gas-containing gas stream in which the sum of the partial pressures of the acid gases does not exceed 1,500 mbar is brought into contact with an aqueous absorbent in an absorption step and an absorbent is used which contains methyldiethanolamine and piperazine at a concentration of at least 8% by weight of the absorbent, an acid-gas-depleted gas stream and an acid-gas-loaded absorbent being obtained.
摘要:
A method is proposed for removing acid gases and ammonia from a fluid stream, according to which 1. in an absorption step the fluid stream comprising the acid gases and ammonia is brought into contact with an aqueous absorption medium, obtaining a fluid stream which is depleted of acid gases and ammonia, and also an absorption medium stream which is charged with acid gases and ammonia and 2. is regenerated in a desorption step, the acid gases and the ammonia being stripped out of the absorption medium and the condensable fractions thereof condensed, obtaining a condensate and also a purified absorption medium stream, which comprises ejecting in part or completely the condensate from the desorption step, or feeding it in part or completely to a distillation column in which ammonia is separated off overhead as aqueous solution or in the pure state and an aqueous bottom stream is obtained which is recycled to the absorption step or the desorption step.
摘要:
A description is given of the use of an alkylenediamine of the type R1HN—X—NHR2, where X is an alkylene radical having from 2 to 9 carbons, R1 is a hydrocarbon radical having from 1 to 6 carbons and R2 is a hydrocarbon radical having from 1 to 6 carbons or is hydrogen (H) for removing sour gases from a sour-gas-containing fluid stream, and of a process for deacidifying a fluid stream of this type and a wash liquid or absorption liquid for use in such a process. According to the invention, in at least one absorption step, the fluid stream is brought into intimate contact with a wash liquid, the wash liquid comprising an aqueous amine solution which comprises at least one tertiary aliphatic alkanolamine having from 2 to 12 carbons and an activator of the above type R1HN—X—NHR2. The fluid stream which is substantially freed from sour gases and the sour-gas-loaded wash liquid are then separated from one another.
摘要:
A process for removing acidic gas constituents, of the group consisting of CO2, H2S, COS, CS2 and mercaptans, from gases, in which, in an absorption step, a dirty gas rich in acidic gas constituents is brought into contact with an absorption medium, as a result of which a clean gas low in acidic gas constituents and an absorption medium laden with acidic gas constituents are obtained, the absorption medium used being a mixture comprising a) from 0.1 to 50% by weight of one or more mono-cyclic or bicyclic nitrogen heterocycles which are unsubstituted and/or monosubstituted or poly-substituted on the carbon by OH, C1-C3 alkyl and/or C1-C3 hydroxyalkyl and which have from 5 to 14 ring atoms and 1 or 2 heterocyclically bound nitrogen atoms per ring as component A, b) from 1 to 60% by weight of a monohydric and/or polyhydric alcohol as component B, c) from 0 to 60% by weight of an aliphatic aminoalcohol as component C, d) from 0 to 98.9% by weight of water as component D, e) from 0 to 35% by weight of K2CO3 as component E, where the sum of components A, B, C, D and E is 100% by weight.
摘要:
A description is given of a process for removing carbon dioxide from gas streams in which the partial pressure of the carbon dioxide is less than 200 mbar, in particular flue gases, the gas stream being contacted with a liquid absorption medium which comprises an aqueous solution (A) of a tertiary aliphatic alkanolamine and (B) an activator of the formula R1—NH—R2—NH2, where R1 is C1-C6-alkyl and R2 is C2-C6-alkylene, the sum of the concentrations of A and B being 2.5 to 7 mol/l, and the molar ratio of B to A being in the range of 1:3 to 1.5:1. The activator is, for example, 3-methylaminopropylamine, the tertiary aliphatic amine methyldiethanolamine, methyldiisopropanolamine or n-butyldiethanolamine. The process permits substantial removal of carbon dioxide and the regeneration of the absorption medium is possible with relatively low energy consumption.
摘要:
A method for bringing into contact two phases which are not completely miscible with one another, and whose contact is accompanied by heat development owing to mass transfer and/or chemical reaction, in which a first phase is introduced into the lower region of a contactor and a second phase is introduced into the upper region of the contactor and passed in countercurrent flow to the first phase in the contactor, a treated first phase and an exhausted second phase being obtained, which comprises recirculating a part of the exhausted second phase to the contactor at least one point situated between the upper region and the lower region. In the preferred embodiment, the first phase is a fluid stream comprising acid gases such as CO2, H2S, SO2, CS2, HCN, COS or mercaptans, and the second phase is an absorption medium which comprises an aqueous solution of at least one organic and/or inorganic base.
摘要:
A method for obtaining an acid gas stream having a pressure of from 3 to 30 bar by removal of acid gases from a fluid stream containing H2S, the molar fraction of H2S based on the total amount of acid gases being at least 50 mol %, the method comprising bringing the fluid stream into intimate contact with a liquid absorption medium, thus producing a fluid stream substantially freed from acid gases and an acid-gas-loaded liquid absorption medium; separating the fluid stream and the liquid absorption medium; separating, by heating and optionally by expansion or stripping, the liquid absorption medium into an acid gas stream and a regenerated liquid absorption medium; passing the regenerated liquid absorption medium into a heat exchanger and cooling it there by using part of its thermal energy to heat up the acid-gas-loaded liquid absorption medium; and recirculating the regenerated liquid absorption medium.
摘要:
The invention relates to a method for the removal of carbon dioxide from a gas flow, in which the partial pressure of the carbon dioxide in the gas flow is less than 200 mbar, whereby the gas flow is brought into contact with a liquid absorption agent, comprising an aqueous solution (A) of a tertiary aliphatic amine and (B) an activator of general formula R1-NH-R2-NH2, where R1=C1-C6 alkyl and R2=C2-C6 alkylene. The method is particularly suitable for treatment of flue gases and also relates to an absorption agent.