Process for the gas-phase polymerization of olefins
    31.
    发明授权
    Process for the gas-phase polymerization of olefins 失效
    烯烃气相聚合方法

    公开(公告)号:US5733987A

    公开(公告)日:1998-03-31

    申请号:US30654

    申请日:1993-03-12

    CPC分类号: C08F10/02 Y10S526/901

    摘要: Process for the gas-phase polymerization of ethylene and ethylene mixtures with .alpha.-olefins CH.sub.2 .dbd.CHR in the presence of a high activity catalyst comprising a titanium compound containing at least one Ti-halogen bond, supported on magnesium dichloride in active form said process comprising the steps of: (a) contacting the catalyst component; (b) prepolymerizing ethylene or ethylene mixtures with .alpha.-olefins in order to produce a polymer amount of from approximately 5 g per g of solid component, up to an amount corresponding to about 10% of the final catalyst yield; (c) polymerizing ethylene or ethylene mixtures with .alpha.-olefins in the gas-phase, in the presence of the prepolymer-catalyst system obtained in (b), while maintaining in the gas phase a molar concentration concentration of the alkane comprised between 20 and 90% with respect to the total gases.

    摘要翻译: 在含活性形式负载在二氯化镁上的含有至少一个Ti-卤键的钛化合物的高活性催化剂存在下,用α-烯烃CH 2 = CHR气相聚合乙烯和乙烯混合物的方法,所述方法包括 步骤:(a)使催化剂组分接触; (b)将乙烯或乙烯混合物与α-烯烃预聚合,以产生约5g / g固体组分的聚合物量,至多相当于最终催化剂产率的约10%的量; (c)在(b)中获得的预聚物 - 催化剂体系的存在下,在气相中与α-烯烃聚合乙烯或乙烯混合物,同时在气相中保持烷烃的摩尔浓度浓度在20和 相对于总气体为90%。

    Highly processable polymeric compositions based on LLDPE
    32.
    发明授权
    Highly processable polymeric compositions based on LLDPE 失效
    基于LLDPE的高度可加工的聚合物组合物

    公开(公告)号:US5561195A

    公开(公告)日:1996-10-01

    申请号:US376024

    申请日:1995-01-20

    摘要: Polymeric compositions based on Linear Low Density Polyethylene (LLDPE) comprising: (A) from 75 to 95% by weight of an ethylene copolymer with an .alpha.-olefin CH.sub.2 =CHR, wherein R is an alkyl radical having from 1 to 10 carbon atoms, and (B) from 5 to 25% by weight of a copolymer of propylene with ethylene and an .alpha.-olefin CH.sub.2 =CHR.sup.I, wherein R.sup.I is an alkyl radical having from 2 to 10 carbon atoms. Copolymer (B) is characterised by a relatively high insolubility in xylene. The polymeric compositions of the invention are endowed with improved processability and improved mechanical properties with respect to the LLDPE of the conventional type.

    摘要翻译: 基于线性低密度聚乙烯(LLDPE)的聚合物组合物包含:(A)75至95重量%的具有α-烯烃CH 2 = CHR的乙烯共聚物,其中R为具有1至10个碳原子的烷基, 和(B)5至25重量%的丙烯与乙烯和α-烯烃CH2 = CHRI的共聚物,其中RI是具有2至10个碳原子的烷基。 共聚物(B)的特征在于二甲苯中相对较高的不溶性。 本发明的聚合物组合物具有相对于常规类型的LLDPE的改进的加工性能和改善的机械性能。