Pyridone dyes, a process for the preparation and their use in the production of colored plastics or polymeric color particles
    34.
    发明授权
    Pyridone dyes, a process for the preparation and their use in the production of colored plastics or polymeric color particles 有权
    吡啶酮染料,一种制备方法及其在生产有色塑料或聚合物着色颗粒中的应用

    公开(公告)号:US06906195B2

    公开(公告)日:2005-06-14

    申请号:US10476954

    申请日:2002-04-30

    CPC分类号: C09B35/031 C09B35/30

    摘要: The present invention relates to pyridone dyes of formula (1), wherein R is a radical —(CR′H)n—W, R′ is hydrogen, C1-C2alkyl or phenyl, Y is cyano, —CONH2 or —CH2SO3H, W is hydrogen, a radical —NR1R2 or a radical —OR3, R1 and R2 are each independently of the other hydrogen, unsubstituted or hydroxy- or phenyl-substituted C1-C6-alkyl, it being possible for the alkyl chain from C3 upwards to be interrupted by one or more oxygen atoms, or a radical of formula (3), (4) or (5), or R1 and R2 together with the nitrogen atom in —NR1R2 form a heterocyclic ring, R3 is hydrogen, unsubstituted or hydroxy-substituted C1-C6alkyl, phenyl or a radical of formula (6), R4 is alkyl or aryl, R5 and R6 are each independently of the other alkyl, aryl or heteroaryl, n is an integer from 2 to 6, and m is an integer from 1 to 6, a process for the preparation thereof and their use in the production of coloured plastics or polymeric colour particles

    摘要翻译: 本发明涉及式(1)的吡啶酮染料,其中R是基团 - (CR'H)n -OR,R'是氢,C 1〜 C 2烷基或苯基,Y是氰基,-CONH 2或-CH 2 SO 3 H,W 是氢,基团-NR 1 R 2或基团-NR 3,R 1和R 2, 各自独立地为另一个氢,未取代的或羟基或苯基取代的C 1 -C 6 - 烷基,对于 或者由式(3),(4)或(5)或R 1的基团中的一个或多个氧原子间隔的C 3-3烷基链, R 1和R 2与-NR 1 R 2 R 2中的氮原子一起形成杂环,R 3是 氢,未取代或羟基取代的C 1 -C 6烷基,苯基或式(6)的基团,R 4是烷基或 芳基,R 5和R 6各自独立地为另一个烷基,Ar 芳基或杂芳基,n为2至6的整数,m为1至6的整数,其制备方法及其在着色塑料或聚合物着色颗粒的制备中的用途

    Reactive dyes containing a chloro or fluorotriazine group
    37.
    发明授权
    Reactive dyes containing a chloro or fluorotriazine group 失效
    含有氯或氟代三嗪基团的活性染料

    公开(公告)号:US5268457A

    公开(公告)日:1993-12-07

    申请号:US999184

    申请日:1992-12-28

    CPC分类号: C09B62/04

    摘要: Reactive dyes of the formula ##STR1## are particularly suitable for dyeing or printing cellulosic fibre materials by the exhaust method or by continuous processes and give, with a high color yield, dyeings and prints with good fastness properties, in which D is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R is hydrogen or alkyl having 1 to 4 carbon atoms, which can be substituted by hydroxyl, cyano, carboxyl, sulfo or sulfato; X is fluorine or chlorine; B is a substituted or unsubstituted aliphatic or aromatic bridge member; Y is a substituted or unsubstituted aliphatic, aromatic, araliphatic or heterocyclic radical, which is free from reactive groups; R.sub.2 is hydrogen or alkyl having 1 to 4 carbon atoms, which can be substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, carbamoyl, sulfamoyl, sulfo or sulfato; and R.sub.1, independently of R.sub.2, has the same meaning as R.sub.2 or is a radical of the formula ##STR2## in which B, Y and R.sub.2 are as defined under formula (1), independently of these meanings.

    摘要翻译: 式(1)的活性染料特别适用于通过排气法或连续方法对纤维素纤维材料进行染色或印花,并以较高的色泽产率提供具有良好牢度特性的染色和印花,其中D为 单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,芪,三苯甲烷,呫吨,噻吨酮,硝基芳基,萘醌,芘醌或苝四亚甲基亚胺染料的基团; R是氢或具有1至4个碳原子的烷基,其可以被羟基,氰基,羧基,磺基或硫酸根取代; X是氟或氯; B是取代或未取代的脂族或芳族桥构件; Y是取代或未取代的脂族,芳族,芳脂族或杂环基团,其不含反应性基团; 羟基,氰基,C 1 -C 4烷氧基,C 1 -C 4烷氧基羰基,羧基,氨基甲酰基,氨磺酰基,磺基或硫酸根取代的氢或具有1至4个碳原子的烷基; R 1和R 2独立地表示与R 2相同的含义,也可以是式(1)所示的基团,其中B,Y和R 2如式(1)所定义,与这些含义无关。

    Reactive dyes containing a trisamino-substituted triazinyl moiety which
is further substituted by two vinylsulfonyl-alkyl- or -aryl-groups

    公开(公告)号:US5084562A

    公开(公告)日:1992-01-28

    申请号:US422861

    申请日:1989-10-17

    IPC分类号: C09B62/503 D06P3/66

    CPC分类号: C09B62/503

    摘要: Reactive dyes which particularly suitable for dyeing or printing cellulose fiber material by the exhaust method or by continuous methods, which produce dyeing having good fastness properties in a high coloristic yield, having the formula ##STR1## where D is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye, R.sub.1 and R.sub.2 are independently of each other hydrogen or alkyl having 1 to 4 carbon atoms which may be substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato, B is a direct bond or a radical --(CH.sub.2)--.sub.n or --O--(CH.sub.2)--.sub.n, n is 1, 2, 3, 4, 5 or 6, R is a radical of the formula ##STR2## where R' is hydrogen or C.sub.1 -C.sub.6 alkyl, alk is alkylene having 1 to 7 carbon atoms or a branched isomer thereof, T is hydrogen, halogen, hydroxyl, sulfato, carboxyl, cyano, C.sub.2 -C.sub.4 alkanoyloxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carbamoyl or a radical --SO.sub.2 --Z, V is hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or a radical of the formula --(alk)--CH.sub.2 --SO.sub.2 --Z, where (alk) is as defined above, each alk' is indepedently of the other polymethylene having 2 to 6 carbon atoms or a branched isomer thereof, Z is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl, p, q, r and t are each independently of the others 1, 2, 3, 4, 5 or 6, s is 2, 3, 4, 5 or 6, and A is a radical of the formula ##STR3## where R.sub.2, B and R are as defined above, X is a radical --SO.sub.2 --Z or --N(R.sub.3)--SO.sub.2 Z, where Z is as defined above, and R.sub.3 is hydrogen, methyl or ethyl, or where A is a radical which is bonded directly to the triazine ring and has the formula (2a), (2b), (2c), (2d), (2e) or (2f) where R', T, alk, V, alk', Z, p, q, r, s and t are as defined above; if it is a radical of the formula (3a), A can be different from the corresponding radical in the formula (1) which includes the benzene nucleus I, and the benzene nuclei I and II or the benzene or naphthalene nucleus III may contain independently of one another further substituents.

    Reactive dyes, their preparation and their use
    39.
    发明授权
    Reactive dyes, their preparation and their use 失效
    活性染料,它们的制备及其用途

    公开(公告)号:US5026847A

    公开(公告)日:1991-06-25

    申请号:US422862

    申请日:1989-10-17

    IPC分类号: C09B62/503

    CPC分类号: C09B62/5033

    摘要: Compounds of the formula ##STR1## in which A, B, R.sub.1, R.sub.2, R.sub.3 and X are as defined in claim 1 are suitable for use as dyes for dyeing and printing cellulose-containing fibre materials, and produce dyeings and prints having good fastness properties.

    摘要翻译: 其中A,B,R 1,R 2,R 3和X如权利要求1中所定义的式(1)的化合物适用于染色和印刷含纤维素纤维材料的染料,并产生染色和印花 具有良好的牢度特性。

    Fiber-reactive dyes containing chromophoric system bound to a bridging
member consisting of two or three triazinyl radicals

    公开(公告)号:US4963659A

    公开(公告)日:1990-10-16

    申请号:US323455

    申请日:1989-03-14

    CPC分类号: C09B62/4403

    摘要: Reactive dyes which are particularly suitable for the dyeing or printing of cellulose-containing fiber materials by the exhaust process or by the continuous process and give, at a high color yield, dyeings and prints having good fastness properties, having the formula ##STR1## in which D.sub.1 and D.sub.2, independently of one another, are each a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; R.sub.1, R.sub.2, B.sub.1 and B.sub.2, independently of one another, are hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; X is fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.4 alkylsulfonyl, phenylsulfonyl or carboxypyridinium, and E is a radical of the formula ##STR2## in which A.sub.1 and A.sub.2, independently of one another, are each a radical of the formula ##STR3## or X is a radical of the formula ##STR4## and E is a radical of the formula (3a), (3b), (3c) or (3d); and R.sub.3 is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato; R.sub.4 and R.sub.5, independently of one another, are 0 to 3 substituents from the group consisting of C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo; B is a direct bond or --(CH.sub.2).sub.n --or --O--(CH2).sub.n --, n is 1 to 6; R is a radical of the formula ##STR5## Z is a .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-halogenoethyl or vinyl; alk is alkylene having 1 to 6 carbon atoms or branced isomers thereof; T is hydrogen, chlorine, bromine, fluorine, hydroxyl, sulfato, alkanoyloxy having 2 to 4 carbon atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 carbon atoms, carbamoyl, or --SO.sub.2 --Z in which Z is as defined above;V is hydrogen or alkyl having 1 to 4 carbon atoms, which is unsubstituted or substituted by carboxyl, sulfo, carbamoyl, N-methylcarbamoyl, N-ethylcarbamoyl, N,N-dimethylcarbamoyl, N,N-diethylcarbamoyl, cyano, acetyl, propionyl, butyryl, methoxycarbonyl, ethoxycarbonyl, propyloxycarbonyl, sulfamoyl, N-methylsulfamoyl, N-ethylsulfamoyl, N,N-dimethylsulfamoyl, N,N-diethylsulfamoyl, methylsulfonyl, ethylsulfonyl, propylsulfonyl, alkoxy having 1 or 2 carbon atoms, halogen or hydroxyl; or is ##STR6## in which Z, alk and T are as defined above; R' is hydrogen or C.sub.1 -C.sub.6 alkyl; alk', independently of one another, is polymethylene having 2 to 6 carbon atoms or branched isomers thereof; and m is 1 to 6, p is 1 to 6 and q is 1 to 6.