公开(公告)号：US20170305823A1

公开(公告)日：2017-10-26

申请号：US15523618

申请日：2015-11-02

Applicant: SHELL OIL COMPANY

Inventor： Kai Jürgen FISCHER ,  Pieter HUIZENGA ,  Wouter KOOT ,  Martin MADERA

IPC: C07C29/86 ,  B01D11/04 ,  C07C41/38

CPC classification number: C07C29/86 ,  B01D11/04 ,  B01D11/0488 ,  B01D11/0492 ,  C07C41/38 ,  C07C31/20 ,  C07C31/202 ,  C07C31/205 ,  C07C31/225

Abstract: A method of recovering an alcohol from an aqueous stream comprising: providing an aqueous stream comprising an alcohol; extracting at least a portion of the alcohol from the aqueous stream with a solvent to form an extracted solvent stream; extracting at least a portion of the solvent from the extracted solvent stream to form an extracted aqueous stream; and recovering at least a portion of the alcohol from the extracted aqueous stream.

公开(公告)号：US20170001932A1

公开(公告)日：2017-01-05

申请号：US15106846

申请日：2014-12-19

Applicant: SHELL OIL COMPANY

Inventor： Evert VAN DER HEIDE ,  Pieter HUIZENGA

IPC: C07C29/132

CPC classification number: C07C29/132 ,  C07C29/74 ,  C07C31/20

Abstract: The invention provides a process for the continuous production of one or more glycols from a saccharide-containing feedstock, said process comprising the steps of: i) contacting the saccharide-containing feedstock with hydrogen in the presence of one or more catalysts in a reactor at a reaction temperature and a reaction pressure in a continuous manner, to provide a reaction effluent stream comprising hydrogen and one or more glycols; ii) separating hydrogen from the reaction effluent stream, without substantial de-pressurisation of said reaction effluent stream to provide a separated hydrogen stream and a liquid effluent stream; and iii) providing at least a portion of the separated hydrogen stream as a hydrogen recycle stream to the reactor for re-use in step i).

Abstract translation: 本发明提供了一种从含糖原料连续生产一种或多种二醇的方法，所述方法包括以下步骤：i）在反应器中在一种或多种催化剂存在下使含糖原料与氢气接触 反应温度和反应压力，以提供包含氢和一种或多种二醇的反应流出料流; ii）从所述反应流出物流中分离氢气，而没有对所述反应流出物流进行实质上的去加压以提供分离的氢气流和液体流出物流; 和iii）将至少一部分分离的氢气流作为氢循环物流提供至反应器，以在步骤i）中重新使用。

公开(公告)号：US20160207856A1

公开(公告)日：2016-07-21

申请号：US14914037

申请日：2014-08-22

Applicant: SHELL OIL COMPANY

Inventor： Evert VAN DER HEIDE ,  Pieter HUIZENGA ,  Govinda Subbanna WAGLE

IPC: C07C29/132 ,  B01J21/08 ,  B01J21/06 ,  B01J23/46 ,  B01J23/89

CPC classification number: C07C29/132 ,  B01J21/066 ,  B01J21/08 ,  B01J23/28 ,  B01J23/30 ,  B01J23/462 ,  B01J23/8993 ,  C07C29/60 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/205 ,  C07C31/207

Abstract: The invention provides a process for the preparation of ethylene glycol and 1, 2-propylene glycol from starting material comprising one or more saccharides, wherein the process comprises the steps of i) providing the starting material and hydrogen to a first reactor, which first reactor operates with mixing; ii) reacting said starting material and hydrogen in the first reactor in the presence of solvent and a catalyst system; iii) continuously removing a first reactor product stream from the first reactor; iv) supplying at least a portion of the first reactor product stream to a second reactor, which reactor operates essentially in a plug flow manner; and v) further reacting the first reactor product stream with hydrogen in the presence of a solvent and optionally a catalyst system in the second reactor.

Abstract translation: 本发明提供了一种由起始原料制备乙二醇和1,2-丙二醇的方法，该原料包括一种或多种糖，其中该方法包括以下步骤：i）将起始原料和氢气提供到第一反应器 混合操作; ii）在溶剂和催化剂体系的存在下使所述起始原料和氢在第一反应器中反应; iii）从第一反应器连续地除去第一反应器产物流; iv）将第一反应器产物流的至少一部分供应到第二反应器，该反应器基本上以插塞流方式操作; 和v）在第二反应器中，在溶剂和任选的催化剂体系的存在下使第一反应器产物流与氢气进一步反应。