Process for adsorptive separation of metaxylene from xylene mixtures
    31.
    发明授权
    Process for adsorptive separation of metaxylene from xylene mixtures 失效
    从二甲苯混合物中吸附分离间二甲苯的方法

    公开(公告)号:US5900523A

    公开(公告)日:1999-05-04

    申请号:US907726

    申请日:1997-08-08

    IPC分类号: C07C7/13 C07C7/12

    CPC分类号: C07C7/13

    摘要: Metaxylene is recovered from admixture with other C.sub.8 aromatic hydrocarbons including orthoxylene by liquid phase adsorptive separation using a sodium exchanged Y zeolite as the adsorbent. Performance is improved by maintaining the adsorbent in a narrow range of temperature and hydration. These conditions allow the metaxylene to be recovered in a single raffinate process without costly prefractionation for orthoxylene removal. A novel desorbent, indane, is also disclosed.

    摘要翻译: 通过使用钠交换的Y沸石作为吸附剂通过液相吸附分离与包括邻二甲苯在内的其它C8芳族烃混合来回收亚甲硅烷。 通过将吸附剂保持在窄的温度和水合范围内来提高性能。 这些条件允许在单次提余工艺中回收间二甲苯,而不需要昂贵的预分馏以进行邻二甲苯去除。 还公开了一种新颖的解吸剂,二氢化茚。

    Adsorptive separation of para-xylene using isopropylbenzene desorbent
    32.
    发明授权
    Adsorptive separation of para-xylene using isopropylbenzene desorbent 失效
    使用异丙苯解吸附剂吸附分离对二甲苯

    公开(公告)号:US5849981A

    公开(公告)日:1998-12-15

    申请号:US882427

    申请日:1997-06-25

    IPC分类号: C07C7/13

    CPC分类号: C07C7/13

    摘要: The cost of separating para-xylene from other xylene isomers and C.sub.9 aromatics by adsorption on zeolitic molecular sieves is reduced by the use of 1,4 diisopropylbenzene as a relatively high boiling desorbent. The desorbent has surprisingly high strength and selectivity characteristics with the preferred desorbent. The preferred adsorbent is an X zeolite containing barium or both barium and potassium ions at exchangeable cationic sites. The para-xylene components are selectively adsorbed onto the adsorbent. The non-adsorbed feed is then removed from the adsorbent and the para-xylene recovered by desorption.

    摘要翻译: 通过使用1,4-二异丙苯作为相对高沸点的解吸剂,降低了通过吸附在沸石分子筛上分离对二甲苯与其它二甲苯异构体和C9芳族化合物的成本。 解吸剂具有令人惊讶的高强度和选择性特征与优选的解吸附剂。 优选的吸附剂是在可交换的阳离子位点含有钡或钡和钾离子的X沸石。 对二甲苯组分选择性地吸附到吸附剂上。 然后从吸附剂中除去未吸附的进料,通过解吸回收对二甲苯。

    Continuous single vessel distillation and adsorption process
    34.
    发明授权
    Continuous single vessel distillation and adsorption process 失效
    连续单容器蒸馏和吸附过程

    公开(公告)号:US5571387A

    公开(公告)日:1996-11-05

    申请号:US304919

    申请日:1994-09-13

    摘要: The present invention is a process for separating at least a first component from a second component of at least a first stream within a single vessel having at least one distillation zone and an adsorption zone. The invention may be applied to separates an alcohol from a mixture of the alcohol and water, such as separating isopropyl alcohol from a mixture of isopropyl alcohol and water. The invention may be applied to more complex systems such as separating isopropyl alcohol and separating diisopropyl ether from the effluents of each reactor of a two-stage diisopropyl ether production process. The benefit of the invention is a high purity separation process at reduced capital equipment costs.

    摘要翻译: 本发明是一种在具有至少一个蒸馏区和吸附区的单个容器内从至少第一流中的第二组分分离至少第一组分的方法。 本发明可以应用于将醇与醇和水的混合物分离,例如从异丙醇和水的混合物中分离异丙醇。 本发明可以应用于更复杂的系统,例如从两步二异丙醚生产过程的每个反应器的流出物中分离异丙醇和分离二异丙醚。 本发明的优点是降低资本设备成本的高纯度分离方法。

    Process for separating glucose and mannose with dealuminated Y zeolites
    35.
    发明授权
    Process for separating glucose and mannose with dealuminated Y zeolites 失效
    用脱铝Y沸石分离葡萄糖和甘露糖的方法

    公开(公告)号:US5000794A

    公开(公告)日:1991-03-19

    申请号:US395009

    申请日:1989-08-17

    IPC分类号: C13B20/12 C13K1/04

    CPC分类号: C13B20/123 C13K1/04

    摘要: Glucose is separated from mixtures with mannose and other saccharides by adsorption on low aluminum Y-type zeolites, i.e., having up to about 50 atoms of aluminum per unit cell and desorbing the adsorbate with water. Glucose is removed from the adsorption process in the raffinate.

    摘要翻译: 通过在低铝Y型沸石上吸附将葡萄糖与甘露糖和其他糖类的混合物分离,即每单元电池具有高达约50个原子的铝并用水解吸附被吸附物质。 从残液中的吸附过程中除去葡萄糖。

    Separation of fluids by means of mixed matrix membranes
    36.
    发明授权
    Separation of fluids by means of mixed matrix membranes 失效
    通过混合基质膜分离流体

    公开(公告)号:US4740219A

    公开(公告)日:1988-04-26

    申请号:US858321

    申请日:1986-05-01

    IPC分类号: B01D53/22 B01D69/14

    CPC分类号: B01D69/141 B01D53/228

    摘要: A fluid feed mixture, either liquid or gaseous in nature, may be subjected to a gas enrichment separation process. The process is effected by contacting the mixture with the upstream face of a mixed matrix membrane which comprises an organic polymer having a solid particulate adsorbent incorporated therein, the permeability coefficient of the organic polymer being compatible with the permeability coefficient of the adsorbent. The permeate which emanates from the downstream face of the membrane comprises a fluid product mixture in which the proportion of the first fluid component of the feed mixture, which possesses a greater steady state permeability in relation to the second fluid component, is greater than the proportion present in the original fluid feed mixture.

    摘要翻译: 本质上液体或气体的流体进料混合物可以进行气体富集分离过程。 该方法通过使混合物与混合基质膜的上游面接触来实现,该混合基质膜包含其中结合有固体颗粒吸附剂的有机聚合物,有机聚合物的渗透系数与吸附剂的渗透系数相适应。 从膜的下游面发出的渗透物包括流体产物混合物,其中相对于第二流体组分具有更大的稳态渗透性的进料混合物的第一流体组分的比例大于比例 存在于原始流体进料混合物中。

    Process for separating isoprene
    37.
    发明授权
    Process for separating isoprene 失效
    异戊二烯分离方法

    公开(公告)号:US4570029A

    公开(公告)日:1986-02-11

    申请号:US707998

    申请日:1985-03-04

    CPC分类号: C07C7/12 C07C7/13

    摘要: A process for separating isoprene from isobutylene, isopentane, and pentene-1. The process uses an adsorbent comprising activated carbon or molecular sieve carbon to selectively adsorb isoprene from the other hydrocarbons. High purity isoprene is recovered by desorption using desorbent materials which include olefinic hydrocarbons. The process is particularly suited for a simulated moving bed apparatus.

    摘要翻译: 从异丁烯,异戊烷和戊烯-1分离异戊二烯的方法。 该方法使用包含活性炭或分子筛碳的吸附剂从其它烃中选择性吸附异戊二烯。 通过使用包括烯烃的解吸剂材料的解吸来回收高纯度异戊二烯。 该方法特别适用于模拟移动床装置。

    Process for separating unsaponifiables from fatty acids
    38.
    发明授权
    Process for separating unsaponifiables from fatty acids 失效
    从脂肪酸中分离不皂化物的方法

    公开(公告)号:US4568496A

    公开(公告)日:1986-02-04

    申请号:US695645

    申请日:1985-01-28

    IPC分类号: C11C1/08 C09F5/10

    CPC分类号: C11C1/08

    摘要: A process for separating an unsaponifiable compound from a feed mixture including fatty acids. The process comprises: (a) forming an emulsion with the feed mixture, an organic solvent in which the feed mixture is soluble and an emulsifying liquid capable of forming an emulsion with the feedstock and organic solvent, the polarity index of the emulsifying liquid being at least 2.4 higher than the polarity index of the organic solvent; (b) effecting the formation of three phases from the emulsion, an organic solvent phase containing the major portion of the fatty acids, an emulsifying liquid phase and a semi-solid sludge phase containing the major portion of the unsaponifiable compound; and (c) separating the three phases.

    摘要翻译: 从包含脂肪酸的进料混合物中分离不皂化合物的方法。 该方法包括:(a)与进料混合物形成乳液,其中可混合进料混合物的有机溶剂和能够与原料和有机溶剂形成乳液的乳化液,乳化液体的极性指数为 比有机溶剂的极性指数低2.4; (b)从乳液形成三相,含有主要部分脂肪酸的有机溶剂相,乳化液相和含有主要部分的不皂化合物的半固体污泥相; 和(c)分离三相。

    Low temperature process for separating hydrocarbons
    39.
    发明授权
    Low temperature process for separating hydrocarbons 失效
    用于分离碳氢化合物的低温工艺

    公开(公告)号:US4455444A

    公开(公告)日:1984-06-19

    申请号:US441142

    申请日:1982-11-12

    IPC分类号: C07C7/13 C10G25/00 C07C7/12

    CPC分类号: C10G25/003 C07C7/13

    摘要: A process for separating a normal paraffin hydrocarbon from a mixture of the same with a cyclic and/or branched chain paraffin hydrocarbon. The process comprises contacting the mixture at a temperature of from about 120.degree. C. to about 140.degree. C. with a zeolite free molecular sieve comprising silicalite. The normal paraffin hydrocarbon is selectively retained and will preferably be recovered from the molecular sieve by displacement with a displacement material.

    摘要翻译: 将正链烷烃与其与环烷烃和/或支链链烷烃烃的混合物分离的方法。 该方法包括使混合物在约120℃至约140℃的温度下与不含沸石的分子筛包含硅沸石接触。 正常的链烷烃被选择性地保留,并且优选通过用置换材料置换从分子筛中回收。

    Separation of bi-alkyl substituted monocyclic aromatic isomers with
pyrolyzed adsorbent
    40.
    发明授权
    Separation of bi-alkyl substituted monocyclic aromatic isomers with pyrolyzed adsorbent 失效
    用热解吸附剂分离双烷基取代的单环芳族异构体

    公开(公告)号:US4423279A

    公开(公告)日:1983-12-27

    申请号:US352395

    申请日:1982-02-25

    IPC分类号: C07C7/13 C07C7/12

    CPC分类号: C07C7/13

    摘要: A process for the separation of the para-isomer from a hydrocarbon feed mixture comprising at least two bi-alkyl substituted monocyclic aromatic isomers, including the para-isomer, said isomers having from 8 to about 18 carbon atoms per molecule, which process employs an adsorbent comprising a zeolite which has been contacted at pyrolyzing conditions with a pyrolyzing agent to preferentially adsorb the para-isomer. The para-isomer thereafter is removed from the adsorbent by contacting it with a desorbent material and is recovered as a product stream. In a preferred embodiment the process uses a simulated moving-bed countercurrent flow system.

    摘要翻译: 一种从含有至少两个双烷基取代的单环芳族异构体(包括对位异构体)的烃进料混合物分离对位异构体的方法,所述异构体每分子具有8至约18个碳原子,该方法采用 吸附剂包括已经在热解条件下与热解剂接触以优先吸附对位异构体的沸石。 其后的对位异构体通过使其与解吸材料接触而从吸附剂中除去并作为产物流回收。 在优选实施例中,该方法使用模拟移动床逆流流动系统。