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    USE OF N-PARAFFIN ADSORPTION TO INCREASE SELECTIVITY AND YIELD OF SYNTHETIC DISTILLATE FUEL
    3.
    发明申请
    USE OF N-PARAFFIN ADSORPTION TO INCREASE SELECTIVITY AND YIELD OF SYNTHETIC DISTILLATE FUEL 审中-公开
    使用N-PARAFFIN吸附增加合成二氧化碳燃料的选择性和产率

    公开(公告)号：US20140005450A1

    公开(公告)日：2014-01-02

    申请号：US13537535

    申请日：2012-06-29

    申请人： Terry L. Marker ,  John A. Petri ,  Charles P. Luebke ,  Tom N. Kalnes ,  Michael J. McCall

    发明人： Terry L. Marker ,  John A. Petri ,  Charles P. Luebke ,  Tom N. Kalnes ,  Michael J. McCall

    IPC分类号： C07C5/13

    CPC分类号： C10G65/043 ,  C10G67/06 ,  C10G2300/1022 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08

    摘要： Methods of making synthetic distillate fuel are described. The methods involve the use of an absorbent bed of molecular sieves which adsorb the n-paraffins from a distillate fuel cut. This allows the distillate fuel true boiling point cut point on the distillation column to increase to a higher temperature to make a distillate fuel which meets all of the synthetic paraffinic kerosene (SPK) or synthetic diesel specifications on distillation as well as the cold flow property specification, such as freeze point for SPK or cloud point, cold filter plugging point and pour point for synthetic diesel. This approach could improve aviation fuel yields by about 5 to about 10% and synthetic diesel yields up to 20%.

    摘要翻译： 描述制造合成馏出物燃料的方法。 该方法涉及使用吸附床的分子筛，其从馏出物燃料切割吸附正构烷烃。 这允许蒸馏塔上的馏出物​​燃料真实沸点切割点增加到更高的温度以制备满足所有合成链烷烃煤油（SPK）或蒸馏合成柴油规格的馏出物燃料以及冷流动性能规格 ，如SPK或浊点的冷冻点，合成柴油的冷滤器堵塞点和倾点。 这种方法可以使航空燃料产量提高约5至10％，合成柴油产量可达20％。

    BUBBLING BED CATALYTIC HYDROPYROLYSIS PROCESS UTILIZING LARGER CATALYST PARTICLES AND SMALLER BIOMASS PARTICLES FEATURING AN ANTI-SLUGGING REACTOR
    4.
    发明申请
    BUBBLING BED CATALYTIC HYDROPYROLYSIS PROCESS UTILIZING LARGER CATALYST PARTICLES AND SMALLER BIOMASS PARTICLES FEATURING AN ANTI-SLUGGING REACTOR 有权
    使用催化剂水解微生物催化剂的方法使用较大的催化剂颗粒和小型生物质颗粒特种抗反应剂

    公开(公告)号：US20120260563A1

    公开(公告)日：2012-10-18

    申请号：US13089010

    申请日：2011-04-18

    申请人： Terry L. Marker ,  Larry G. Felix ,  Martin B. Linck ,  Michael J. Roberts

    发明人： Terry L. Marker ,  Larry G. Felix ,  Martin B. Linck ,  Michael J. Roberts

    IPC分类号： C10L1/18

    CPC分类号： C10G1/06 ,  B01J8/1809 ,  B01J8/34 ,  B01J23/755 ,  B01J23/882 ,  B01J2208/00061 ,  B01J2208/00115 ,  B01J2208/00548 ,  B01J2208/0084 ,  B01J2219/00252 ,  C10G1/002 ,  C10G1/086 ,  C10G1/10 ,  C10G3/45 ,  C10G3/46 ,  C10G3/50 ,  C10G3/57 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/04 ,  C10L2200/0469 ,  C10L2290/02 ,  Y02E50/14 ,  Y02E50/32 ,  Y02P30/20

    摘要： This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

    摘要翻译： 本发明涉及将生物质或其它含氧原料热化学变换成高质量液体烃燃料的方法。 特别地，使用含有流化催化剂颗粒的深层的催化加氢热解反应器来接受显着小于流化床中的催化剂颗粒的生物质或其它含氧原料的颗粒。 反应器具有设置在反应器容器内的插入物或其它结构，其抑制床的压块，从而使催化剂的磨损最小化。 在床内，生物质原料转化为含有烃分子和其他工艺蒸气的气相产物，以及夹带的固体焦炭产物，其在蒸气流已经从蒸汽流的顶部排出之后与蒸气流分离 反应堆。 当产物蒸气流被冷却到环境温度时，产物蒸气流中的相当大比例的烃可作为疏水性烃的液体流回收，其特性与汽油，煤油和柴油燃料的性质一致。 也可以通过每种类型的燃料的选择性冷凝，或通过后来的组合烃液体的蒸馏来获得单独的汽油，煤油和柴油燃料。

    Production of transportation fuel from renewable feedstocks
    5.
    发明授权
    Production of transportation fuel from renewable feedstocks 有权
    从可再生原料生产运输燃料

    公开(公告)号：US08198492B2

    公开(公告)日：2012-06-12

    申请号：US12403024

    申请日：2009-03-12

    申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

    发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

    IPC分类号： C10L1/16 ,  C10L5/00 ,  C07C4/00

    CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

    摘要： A process has been developed for producing a diesel boiling point range product and an aviation boiling point range product from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction which is then isomerized and selectively cracked to form the diesel boiling point range product and the aviation boiling point range product. A portion of the diesel boiling point range product, aviation boiling point range product, naphtha product, LPG, or any combination thereof can be optionally used as a rectification agent in the selective hot high pressure hydrogen stripper to decrease the amount of product carried in the stripper overhead.

    摘要翻译： 已经开发了用于生产柴油沸点范围产物和来自可再生原料如植物油和动物油的航空沸点范围产物的方法。 该方法包括通过氢化和脱氧来处理可再生原料以提供烃馏分，然后异构化并选择性裂化形成柴油沸点范围产物和航空沸点范围产物。 柴油沸点范围产品，航空沸点范围产品，石脑油产品，LPG或其任何组合的一部分可以任选用作选择性热高压氢气汽提器中的精馏剂，以减少在 汽提塔头顶。

    USE OF A GUARD BED REACTOR TO IMPROVE CONVERSION OF BIOFEEDSTOCKS TO FUEL
    6.
    发明申请
    USE OF A GUARD BED REACTOR TO IMPROVE CONVERSION OF BIOFEEDSTOCKS TO FUEL 有权
    使用防腐剂反应器改善生物燃料转化为燃料

    公开(公告)号：US20110245551A1

    公开(公告)日：2011-10-06

    申请号：US12750057

    申请日：2010-03-30

    申请人： Terry L. Marker ,  Timothy A. Brandvold ,  Charles P. Luebke

    发明人： Terry L. Marker ,  Timothy A. Brandvold ,  Charles P. Luebke

    IPC分类号： C07C1/00

    CPC分类号： C10G3/46 ,  C10G3/00 ,  C10G45/00 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/802 ,  C10L1/04 ,  Y02P30/20

    摘要： The present invention involves a process for processing an acidic biorenewable feedstock comprising olefins, in which the acidic biorenewable feedstock is diluted with a deoxygenated feed to produce a diluted biorenewable feedstock and then is sent through a guard bed comprising a hydroprocessing catalyst to cause the olefins to be saturated with hydrogen and thereby to produce a treated biorenewable feedstock. This treated biorenewable feedstock can then be treated under standard hydroprocessing condition to produce an upgraded feedstock for transportation fuels.

    摘要翻译： 本发明涉及一种用于处理包含烯烃的酸性生物可再生原料的方法，其中酸性生物可再生原料用脱氧原料稀释以产生稀释的生物可再生原料，然后通过包含加氢处理催化剂的保护床送入， 用氢饱和，从而产生经处理的生物可再生原料。 然后可以在标准加氢处理条件下处理经处理的生物可再生原料，以生产用于运输燃料的升级原料。

    Production of diesel fuel from biorenewable feedstocks
    8.
    发明授权
    Production of diesel fuel from biorenewable feedstocks 有权
    生物可再生原料生产柴油

    公开(公告)号：US07999142B2

    公开(公告)日：2011-08-16

    申请号：US12193156

    申请日：2008-08-18

    申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

    发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

    IPC分类号： C07C4/00

    CPC分类号： C10L1/08 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

    摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel or diesel boiling range fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is selectively separated and then recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

    摘要翻译： 已经开发了用于从可再生原料如植物油和动物油，脂肪和油脂生产柴油沸点燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和/或加氢脱氧，以提供可用作柴油沸程燃料或柴油沸程燃料调配组分的烃馏分。 如果需要，烃馏分可以被异构化以改善冷流动性能。 氢化和脱氧原料的一部分被选择性分离，然后再循环到处理区以提高反应混合物的氢溶解度。

    Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen
    9.
    发明授权
    Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen 有权
    从生物可再生原料生产柴油，并选择性分离转化的氧气

    公开(公告)号：US07982078B2

    公开(公告)日：2011-07-19

    申请号：US12193196

    申请日：2008-08-18

    申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

    发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

    IPC分类号： C07C1/00 ,  C07C4/00

    CPC分类号： C10L1/08 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

    摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils, the process providing for sulfur management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. A selective separation such as a hot high pressure hydrogen stripper is used to remove at least the carbon oxides from the first zone effluent before entering the isomerization zone, and to provide liquid recycle to the treating zone at pressure and temperature. A vapor stream is separated from the isomerization effluent and at least carbon dioxide is removed using at least one selective or flexible amine solution absorber. The resulting hydrogen-rich stream is recycled to the deoxygenation reaction zone.

    摘要翻译： 已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法，该方法提供硫管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 在进入异构化区之前，使用诸如热高压氢气汽提器的选择性分离来从第一区流出物中至少除去碳氧化物，并在压力和温度下向处理区提供液体循环。 将蒸汽流与异构化流出物分离，并使用至少一种选择性或柔性的胺溶液吸收剂除去至少二氧化碳。 将所得富氢流循环至脱氧反应区。