METHOD FOR DEHYDROGENATING ALCOHOLS
    31.
    发明申请
    METHOD FOR DEHYDROGENATING ALCOHOLS 失效
    脱水醇的方法

    公开(公告)号:US20090312581A1

    公开(公告)日:2009-12-17

    申请号:US12307925

    申请日:2007-07-09

    IPC分类号: C07C45/00

    摘要: A method for dehydrogenating primary or secondary alcohols having 1 to 12 carbon atoms to give the corresponding aldehydes or ketones in which the alcohol is brought into contact with a catalytically active composition comprising an active component of the formula PdaBibYcZd, where Y is selected from the group consisting of Co, Rh, Pt, Ag, Au, and Z is selected from the group consisting of Na, Cs, Mg, Ca, Ba, V, Cr, W, Fe, Ni, Cu, Sb where the indices a, b, c and d give the mass ratios of the respective elements to one another, where a=0.1-3, b=0.1-3, c=0-3, d=0-1.

    摘要翻译: 一种使具有1至12个碳原子的伯醇或仲醇脱氢得到相应的醛或酮,其中醇与包含式PdaBibYcZd的活性组分的催化活性组合物接触,其中Y选自 由Co,Rh,Pt,Ag,Au和Z组成的组分选自Na,Cs,Mg,Ca,Ba,V,Cr,W,Fe,Ni,Cu,Sb, ,c和d给出各元素彼此的质量比,其中a = 0.1-3,b = 0.1-3,c = 0-3,d = 0-1。

    Process for preparing 1-butene
    33.
    发明申请
    Process for preparing 1-butene 有权
    制备1-丁烯的方法

    公开(公告)号:US20070161841A1

    公开(公告)日:2007-07-12

    申请号:US10577198

    申请日:2004-10-27

    IPC分类号: C07C5/327 C07C5/373

    CPC分类号: C07C5/333 C07C5/05 C07C11/08

    摘要: A) Provision of an n-butane-containing feed gas stream a; B) introduction of the n-butane-containing feed gas stream a into at least one dehydrogenation zone and nonoxidative catalytic dehydrogenation of n-butane to give a product gas stream b comprising n-butane, 1-butene, 2-butene, butadiene, low-boiling secondary constituents, hydrogen and possibly water vapor, C) removal of hydrogen, the low-boiling secondary constituents and, if appropriate, water vapor to give a C4 product gas stream c consisting essentially of n-butane, 1-butene, 2-butene and butadiene; D) introduction of the C4 product gas stream c consisting essentially of n-butane, 1-butene, 2-butene and butadiene into a selective hydrogenation zone and selective hydrogenation of butadiene to 1- and/or 2-butene to give a stream d consisting essentially of n-butane, 1-butene and 2-butene; E) separation of the stream d into a desired product stream e1 consisting essentially of 1-butene and a recycle stream e2 consisting essentially of 2-butene and n-butane and recirculation of the recycle stream e2 consisting essentially of 2-butene and n-butane to the dehydrogenation zone.

    摘要翻译: A)提供含正丁烷的进料气流a; B)将含正丁烷的原料气流a引入至少一个脱氢区和正丁烷的非氧化催化脱氢,得到包含正丁烷,1-丁烯,2-丁烯,丁二烯, 低沸点二次成分,氢气和可能的水蒸汽,C)除去氢气,低沸点次级组分,如果合适的话,除去水蒸汽,得到基本上由以下组成的C 4 H 3产物气流c 正丁烷,1-丁烯,2-丁烯和丁二烯; D)将基本上由正丁烷,1-丁烯,2-丁烯和丁二烯组成的C 4 H 4产物气流c引入选择性氢化区,并将丁二烯选择性氢化成1-和/或 得到基本上由正丁烷,1-丁烯和2-丁烯组成的料流d; E)将流d分离成基本上由1-丁烯组成的所需产物流e1和基本上由2-丁烯和正丁烷组成的再循环流e2,再循环流体e2基本上由2-丁烯和正丁烯组成, 丁烷到脱氢区。