Method for producing polyoxyalkylene alkyl ether carboxylic acid or salt thereof
    4.
    发明授权
    Method for producing polyoxyalkylene alkyl ether carboxylic acid or salt thereof 有权
    聚氧化烯烷基醚羧酸或其盐的制备方法

    公开(公告)号:US09233904B2

    公开(公告)日:2016-01-12

    申请号:US14369628

    申请日:2012-11-27

    申请人: Kao Corporation

    摘要: A method for producing polyoxyalkylene alkyl ether carboxylic acid or a salt thereof includes an oxidation reaction process of oxidizing polyoxyalkylene alkyl ether with oxygen by supplying an oxygen-containing gas to a suspension or a solution that has a depth of 200 mm or more and includes polyoxyalkylene alkyl ether. In the oxidation reaction process, a supply rate of the oxygen-containing gas is reduced in a period in which the conversion is greater than or equal to 50% and less than 70%.

    摘要翻译: 聚氧化烯烷基醚羧酸或其盐的制造方法包括通过向悬浮液或深度为200mm以上的溶液中供给含氧气体而使氧化聚氧化烯烷基醚与氧的氧化反应过程,并且包括聚氧化烯 烷基醚。 在氧化反应过程中,在转化率大于或等于50%且小于70%的时段内,含氧气体的供给速率降低。

    Method for manufacturing polyoxyethylene alkyl ether acetic acid
    7.
    发明授权
    Method for manufacturing polyoxyethylene alkyl ether acetic acid 有权
    制备聚氧乙烯烷基醚乙酸的方法

    公开(公告)号:US08901348B2

    公开(公告)日:2014-12-02

    申请号:US14122528

    申请日:2012-06-07

    申请人: Akira Sakaguchi

    发明人: Akira Sakaguchi

    摘要: The invention relates to a method for manufacturing a polyoxyethylene alkyl ether acetic acid, including feeding oxygen into a liquid phase containing polyoxyethylene ether having a hydrocarbon group at the end (hereinafter, it may also be referred to as a polyoxyethylene alkyl ether) and water, and dehydrogenating and oxidizing the polyoxyethylene alkyl ether in the presence of a platinum catalyst, in which the mass ratio between the total mass of the polyoxyethylene alkyl ether and the polyoxyethylene alkyl ether acetic acid and the mass of water in the liquid phase ((polyoxyethylene alkyl ether+polyoxyethylene alkyl ether acetic acid)/water) is 60/40 to 95/5.

    摘要翻译: 本发明涉及一种制备聚氧乙烯烷基醚乙酸的方法,包括将氧进入含有末端具有烃基的聚氧乙烯醚(以下也称为聚氧乙烯烷基醚)和水的液相中, 在聚氧乙烯烷基醚和聚氧乙烯烷基醚乙酸的总质量与液相中的水的质量比((聚氧乙烯烷基 醚+聚氧乙烯烷基醚乙酸)/水)为60/40〜95/5。

    Method for Preparing a Supported Ruthenium Catalyst
    8.
    发明申请
    Method for Preparing a Supported Ruthenium Catalyst 有权
    制备负载型钌催化剂的方法

    公开(公告)号:US20140322622A1

    公开(公告)日:2014-10-30

    申请号:US14118301

    申请日:2012-05-15

    IPC分类号: C01B3/08 H01M8/06

    摘要: In a method of preparing a ruthenium-containing catalyst on a non-conductive metal oxide support comprises dissolving one or more ruthenium precursor compounds in an liquid organic polyol, combining the thus obtained solution with (a) nano-powder(s) of one or more metal oxides in a ratio of moles metal oxide(s) to moles ruthenium atoms in the one or more ruthenium precursor compounds of about 0:1 to about 6:1, the metal oxide nano-powder(s) having a surface area of from about 5 to about 300m2/g and a point of zero charge (PZC) of pH 5.5 or higher, agitating the thus obtained mixture, adding pre-shaped alumina sup port pellets to the agitated mixture, which is than heated at a temperature of about 50° C. to the boiling point of the organic polyol, until the reaction is finished, cooling the mixture and combining it with an aqueous solution of NaNO3 and/or KNO3, agitating the resultant mixture, separating the solvent and the solids, and drying the thus obtained solid pellets of alumina, or alumina and the metal oxide(s) of the nano-powder(s) coated with ruthenium and an additional amount Na and/or K ions. Also disclosed is the sup ported ruthenium-containing catalyst obtainable by the method and the use thereof in decomposing ammonia into nitrogen and oxygen.

    摘要翻译: 在非导电性金属氧化物载体上制备含钌催化剂的方法包括将一种或多种钌前体化合物溶解在液体有机多元醇中,将由此获得的溶液与(a)一种或多种纳米粉末组合, 一种或多种钌前体化合物中的金属氧化物与一种或多种钌前体化合物中钌原子摩尔数的摩尔比为大约0:1至大约6:1的金属氧化物,所述金属氧化物纳米粉末的表面积为 约5至约300m 2 / g和pH 5.5或更高的零电荷点(PZC),搅拌由此获得的混合物,向预先搅拌的混合物中加入预形状的氧化铝支撑颗粒,该混合物在温度为 约50℃至有机多元醇的沸点,直到反应完成,冷却混合物并将其与NaNO 3和/或KNO 3的水溶液混合,搅拌所得混合物,分离溶剂和固体,和 干燥由此获得的氧化铝固体颗粒, 或氧化铝和涂覆有钌的纳米粉末和额外量的Na和/或K离子的金属氧化物。 还公开了通过该方法获得的支持钌的催化剂及其在将氨分解成氮和氧的用途。

    METHOD FOR MANUFACTURING POLYOXYETHYLENE ALKYL ETHER ACETIC ACID
    9.
    发明申请
    METHOD FOR MANUFACTURING POLYOXYETHYLENE ALKYL ETHER ACETIC ACID 有权
    制备聚氧乙烯烷基醚酸的方法

    公开(公告)号:US20140088323A1

    公开(公告)日:2014-03-27

    申请号:US14122528

    申请日:2012-06-07

    申请人: Akira Sakaguchi

    发明人: Akira Sakaguchi

    IPC分类号: C07C51/16

    摘要: The invention relates to a method for manufacturing a polyoxyethylene alkyl ether acetic acid, including feeding oxygen into a liquid phase containing polyoxyethylene ether having a hydrocarbon group at the end (hereinafter, it may also be referred to as a polyoxyethylene alkyl ether) and water, and dehydrogenating and oxidizing the polyoxyethylene alkyl ether in the presence of a platinum catalyst, in which the mass ratio between the total mass of the polyoxyethylene alkyl ether and the polyoxyethylene alkyl ether acetic acid and the mass of water in the liquid phase ((polyoxyethylene alkyl ether+polyoxyethylene alkyl ether acetic acid)/water) is 60/40 to 95/5.

    摘要翻译: 本发明涉及一种制备聚氧乙烯烷基醚乙酸的方法,包括将氧进入含有末端具有烃基的聚氧乙烯醚(以下也称为聚氧乙烯烷基醚)和水的液相中, 在聚氧乙烯烷基醚和聚氧乙烯烷基醚乙酸的总质量与液相中的水的质量比((聚氧乙烯烷基 醚+聚氧乙烯烷基醚乙酸)/水)为60/40〜95/5。