摘要:
Disclosed herein is a lithium secondary cell including 20 to 100 wt. % of lithium transition metal oxide represented by a formula of Li1+zNibMncMe1−(b+c)O2, relative to a total amount of a cathode active material, as well as an electrolyte consisting of a lithium salt and a non-aqueous solvent, wherein a first additive to form a protective film (that is, a solid electrolyte interface film: SEI film) over a surface of an anode active material and a second additive to form another SEI film over the surface of the anode active material while inactivating impurities contained in the cathode active material are included in the electrolyte.
摘要:
Disclosed herein is a cathode active material for a lithium secondary battery, in particular, including a lithium transition metal oxide with a layered crystalline structure in which the transition metal includes a transition metal mixture of Ni, Mn and Co, and an average oxidation number of all transition metals other than lithium is more than +3, and specific conditions represented by the following formulae (1) and (2), 1.1
摘要:
Provided is a cathode active material for a lithium secondary battery, including a lithium-transition metal composite oxide represented by the following formula (1), which contains an excess of lithium, so as to exhibit enhanced rate characteristics under high rate charge/discharge conditions: Lii+aNi′bNi″cMndCoeO2 (1) wherein each of a, b, c, d and e has the same meaning as defined in the disclosure. The cathode active material according to the present invention includes an excess of lithium and, different from conventional technologies, a lithium-transition metal composite oxide containing a nickel element with a predetermined oxidation number, so that the active material exhibits a stable crystal structure and excellent rate characteristics under high rate charge/discharge conditions.
摘要:
Provided is a cathode active material composed of lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide contains nickel in an amount of 40% or higher, based on the total weight of transition metals, and the cathode active material comprises a first coating layer provided on the surface thereof and a second coating layer provided on the surface of the first coating layer, wherein the first coating layer is composed of a non-reactive material selected from the group consisting of oxides, nitrides, sulfides and mixtures or complexes thereof and the second coating layer is composed of a carbon-based material.
摘要:
Disclosed herein is an additive for improvement in safety of an electrochemical device, including an inner core and an outer coating layer, wherein the inner core is formed using a volume-expandable material fused at more than a predetermined temperature while the outer coating layer is formed using a conductive material with higher conductivity than that of the inner core and covers an outer face of the inner core.The disclosed additive rapidly increases resistance of the electrochemical device before ignition/explosion of the device caused by temperature rise, thereby effectively preventing ignition/explosion of the electrochemical device without deterioration in performance of the electrochemical device.
摘要:
Disclosed herein are a cathode for a secondary battery, which includes a combination of one or more selected from compounds represented by Formula 1 and or more selected from compounds represented by Formula 2, as illustrated below, and a secondary battery having the same, xLi2MO3*(1−x)LiM′O2 (1) (1−u)LiFePO4*uC (2).
摘要:
Provided is a cathode active material composed of lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide contains nickel in an amount of 40% or higher, based on the total weight of transition metals, and the cathode active material comprises a first coating layer provided on the surface thereof and a second coating layer provided on the surface of the first coating layer, wherein the first coating layer is composed of a non-reactive material selected from the group consisting of oxides, nitrides, sulfides and mixtures or complexes thereof and the second coating layer is composed of a carbon-based material.
摘要:
Provided is a cathode for lithium secondary batteries comprising a combination of one or more compounds selected from Formula 1 and one or more compounds selected from Formula 2. The cathode provides a high-power lithium secondary battery composed of a non-aqueous electrolyte which exhibits long lifespan, long-period storage properties and superior stability at ambient temperature and high temperatures.
摘要:
Disclosed herein is a cathode active material based on lithium nickel-manganese-cobalt oxide represented by Formula 1, wherein the lithium nickel-manganese-cobalt oxide has a nickel content of at least 40% among overall transition metals and is coated with a conductive polymer at a surface thereof. A lithium secondary battery having the disclosed cathode active material has advantages of not deteriorating electrical conductivity while enhancing high temperature stability, so as to efficiently provide high charge capacity.
摘要:
Disclosed herein is a cathode active material based on lithium nickel oxide represented by Formula 1, wherein the lithium nickel oxide has a nickel content of at least 40% among overall transition metals and is coated with a polymer having a melting point of 80 to 300° C. at a surface thereof. A lithium secondary battery having the disclosed cathode active material has advantages of not deteriorating electrical conductivity while maintaining high temperature stability, so as to efficiently provide high charge capacity.