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    FLUOROADAMANTANE DERIVATIVE
    32.
    发明申请
    FLUOROADAMANTANE DERIVATIVE 失效
    荧光素衍生物

    公开(公告)号：US20070129566A1

    公开(公告)日：2007-06-07

    申请号：US11567391

    申请日：2006-12-06

    申请人： Shu-zhong WANG ,  Taiki Hoshino ,  Kimiaki Kashiwagi ,  Takashi Okazoe ,  Eisuke Murotani ,  Masahiro Ito ,  Kunio Watanabe

    发明人： Shu-zhong WANG ,  Taiki Hoshino ,  Kimiaki Kashiwagi ,  Takashi Okazoe ,  Eisuke Murotani ,  Masahiro Ito ,  Kunio Watanabe

    IPC分类号： C07C69/52

    CPC分类号： C07C69/653 ,  C07C29/095 ,  C07C35/52 ,  C07C67/14 ,  C07C67/287 ,  C07C2603/74 ,  C07C69/708

    摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials. A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:

    摘要翻译： 金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。 化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解 得到化合物（2），然后与化合物（15）反应，得到化合物（1）。 这里，A至J为-CFH-或-CF 2 - RF是全氟烷基等; X 10是F等; Y 2是H或OH; Y 3是H或R 0 COO-; Y 4是H，F或R“COO-; H 5是H，F，R F CO或O-; Y 0是H，F，-OCOCR 1 -CH 2或OH：R 1是氢原子 ，甲基等; 并且X 11是OH或卤素原子：

    Process for producing a fluorine atom-containing sulfonyl fluoride compound
    33.
    再颁专利
    Process for producing a fluorine atom-containing sulfonyl fluoride compound 有权
    含氟原子的磺酰氟化合物的制造方法

    公开(公告)号：USRE41357E1

    公开(公告)日：2010-05-25

    申请号：US12234140

    申请日：2008-09-19

    申请人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    发明人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    IPC分类号： C07C69/66 ,  C07C309/00

    CPC分类号： C07C309/82 ,  C07C51/60 ,  C07C303/22 ,  C07C59/135

    摘要： The present invention provides a process whereby fluorine atom-containing sulfonyl fluoride compound(s) useful as e.g. materials for ion-exchange membranes, can be produced efficiently and at low cost without structural limitations while solving the difficulties in production. Namely, the present invention provides a process which comprises reacting XSO2RA-E1 (1) with RB-E2 (2) to form XSO2RA-E-RB (3), then reacting (3) with fluorine in a liquid phase to form FSO2RAF-EF-RBF (4), and further, decomposing the compound to obtain FSO2RAF-EF1 (5), wherein RA is a bivalent organic group, E1 is a monovalent reactive group, RB is a monovalent organic group, E2 is a monovalent reactive group which is reactive with E1, E is a bivalent connecting group formed by the reaction of E1 with E2, RAF is a bivalent organic group formed by the fluorination of RA, etc., RBF is the same group as RB, etc., EF is a bivalent connecting group formed by the fluorination of E, etc., EF1 is a monovalent group formed by the decomposition of EF, and X is a halogen atom.

    摘要翻译： 本发明提供了一种可用于例如氟原子的磺酰氟化合物的方法。 用于离子交换膜的材料可以在没有结构限制的情况下有效且低成本地生产，同时解决生产上的困难。 即，本发明提供了使XSO 2RA-E1（1）与RB-E2（2）反应形成XSO 2RA -E-RB（3），然后使（3）与氟在液相中反应形成FSO 2RAF- EF-RBF（4），进一步分解化合物，得到FSO2RAF-EF1（5），其中RA为二价有机基团，E1为单价反应性基团，RB为一价有机基团，E2为单价反应性基团 E是与E1反应的二价连接基团，E是通过E1与E2的反应形成的二价连接基团，RAF是通过RA的氟化形成的二价有机基团等，RBF与RB等同，EF是 通过E的氟化形成的二价连接基团等，EF1是通过EF的分解形成的一价基团，X是卤素原子。

    Process for producing a fluorine atom-containing sulfonyl fluoride compound
    34.
    再颁专利
    Process for producing a fluorine atom-containing sulfonyl fluoride compound 有权

    公开(公告)号：USRE41184E1

    公开(公告)日：2010-03-30

    申请号：US12234109

    申请日：2008-09-19

    申请人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    发明人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    IPC分类号： C07C69/66 ,  C07C69/63 ,  C07C309/00

    CPC分类号： C07C309/82 ,  C07C51/60 ,  C07C303/22 ,  C07C59/135

    摘要： The present invention provides a process whereby fluorine atom-containing sulfonyl fluoride compound(s) useful as e.g. materials for ion-exchange membranes, can be produced efficiently and at low cost without structural limitations while solving the difficulties in production. Namely, the present invention provides a process which comprises reacting XSO2RA-E1 (1) with RB-E2 (2) to form XSO2RA-E-RB (3), then reacting (3) with fluorine in a liquid phase to form FSO2RAF-EF-RBF (4), and further, decomposing the compound to obtain FSO2RAF-EF1 (5), wherein RA is a bivalent organic group, E1 is a monovalent reactive group, RB is a monovalent organic group, E2 is a monovalent reactive group which is reactive with E1, E is a bivalent connecting group formed by the reaction of E1 with E2, RAF is a bivalent organic group formed by the fluorination of RA, etc., RBF is the same group as RB, etc., EF is a bivalent connecting group formed by the fluorination of E, etc., EF1 is a monovalent group formed by the decomposition of EF, and X is a halogen atom.

    Fluoroadamantane derivative
    35.
    发明授权
    Fluoroadamantane derivative 失效
    氟金刚烷衍生物

    公开(公告)号：US07511177B2

    公开(公告)日：2009-03-31

    申请号：US12020863

    申请日：2008-01-28

    申请人： Shu-zhong Wang ,  Taiki Hoshino ,  Kimiaki Kashiwagi ,  Takashi Okazoe ,  Eisuke Murotani ,  Masahiro Ito ,  Kunio Watanabe

    发明人： Shu-zhong Wang ,  Taiki Hoshino ,  Kimiaki Kashiwagi ,  Takashi Okazoe ,  Eisuke Murotani ,  Masahiro Ito ,  Kunio Watanabe

    IPC分类号： C07C35/22

    CPC分类号： C07C69/653 ,  C07C29/095 ,  C07C35/52 ,  C07C67/14 ,  C07C67/287 ,  C07C2603/74 ,  C07C69/708

    摘要： Adamantane derivates which can be material compounds of a polymer excellent in etching resistance and having improved transmittance to light having a short wavelength, are produced by an economically advantageous process from readily available materials.A compound (10) is subjected to esterification reaction with a compound (11) to obtain a compound (12), which is subjected to fluorination in a liquid phase to obtain a compound (13), which is then subjected to hydrolysis or alcoholysis to obtain a compound (2), which is then reacted with a compound (15) thereby to obtain a compound (1). Here, A to J are —CFH— or —CF2—; RF is a perfluoroalkyl group or the like; X10 is F or the like; Y2 is H or OH; Y3 is H or RFCOO—; Y4 is H, F or RFCOO—; Y5 is H, F, RFCOO— or OH; Y0 is H, F, —OCOCR1═CH2 or OH: R1 is a hydrogen atom, a methyl group or the like; and X11 is OH or a halogen atom:

    摘要翻译： 金刚烷衍生物可以通过从容易获得的材料的经济上有利的方法产生耐蚀性优异且具有改善的具有短波长的光的透射率的聚合物的材料化合物。 化合物（10）与化合物（11）进行酯化反应，得到化合物（12），将其进行液相氟化，得到化合物（13），然后进行水解或醇解 得到化合物（2），然后与化合物（15）反应，得到化合物（1）。 这里，A至J为-CFH-或-CF2-; RF是全氟烷基等; X10为F等; Y2是H或OH; Y3为H或RFCOO-; Y4是H，F或RFCOO-; Y5为H，F，RFCOO-或OH; Y0是H，F，-OCOCR1-CH2或OH：R1是氢原子，甲基等; X 11为OH或卤原子：

    Fluorinated adamantane derivative
    36.
    发明授权
    Fluorinated adamantane derivative 失效
    氟化金刚烷衍生物

    公开(公告)号：US07425646B2

    公开(公告)日：2008-09-16

    申请号：US11611183

    申请日：2006-12-15

    申请人： Kazuya Oharu ,  Takashi Okazoe ,  Eisuke Murotani ,  Kunio Watanabe ,  Masahiro Ito

    发明人： Kazuya Oharu ,  Takashi Okazoe ,  Eisuke Murotani ,  Kunio Watanabe ,  Masahiro Ito

    IPC分类号： C07C69/63

    CPC分类号： C07C61/15 ,  C07C51/58 ,  C07C2603/74

    摘要： A compound represented by the formula AF(—COF)n, provided that AF and n have the following meanings.AF: a fluorinated adamantane residue which is an n-valent group having an n number of hydrogen atoms removed from adamantane (provided that when n is at least 2, the removed hydrogen atoms are hydrogen atoms bonded to different carbon atoms), wherein at least one of the remaining hydrogen atoms is substituted by a fluorine atom, and the remaining hydrogen atoms may be substituted by a C1-6 alkyl group or fluoroalkyl group, and n: an integer of from 1 to 4, provided the when n is 1, AF has at least one hydrogen atom.

    摘要翻译： 由式A -F（ - COF）n N表示的化合物，条件是A和N具有下列含义。 氟化金刚烷残基，其是从金刚烷中除去n个氢原子的n价基团（条件是当n至少为2时，除去的氢原子是与氢原子键合的氢原子 不同的碳原子），其中剩余的氢原子中的至少一个被氟原子取代，剩余的氢原子可以被C 1-6烷基或氟代烷基取代，n ：1〜4的整数，n为1时，A为至少1个氢原子。

    Process for producing a fluorine atom-containing sulfonyl fluoride compound
    38.
    发明授权
    Process for producing a fluorine atom-containing sulfonyl fluoride compound 有权
    含氟原子的磺酰氟化合物的制造方法

    公开(公告)号：US07105697B2

    公开(公告)日：2006-09-12

    申请号：US10808274

    申请日：2004-03-25

    申请人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    发明人： Masahiro Ito ,  Kunio Watanabe ,  Takashi Okazoe ,  Isamu Kaneko ,  Daisuke Shirakawa

    IPC分类号： C07C309/00

    CPC分类号： C07C309/82 ,  C07C51/60 ,  C07C303/22 ,  C07C59/135

    摘要： The present invention provides a process whereby fluorine atom-containing sulfonyl fluoride compound(s) useful as e.g. materials for ion-exchange membranes, can be produced efficiently and at low cost without structural limitations while solving the difficulties in production. Namely, the present invention provides a process which comprises reacting XSO2RA-E1 (1) with RB-E2 (2) to form XSO2RA-E-RB (3), then reacting (3) with fluorine in a liquid phase to form FSO2RAF-EF-RBF (4), and further, decomposing the compound to obtain FSO2RAF-EF1 (5), wherein RA is a bivalent organic group, E1 is a monovalent reactive group, RB is a monovalent organic group, E2 is a monovalent reactive group which is reactive with E1, E is a bivalent connecting group formed by the reaction of E1 with E2, RAF is a bivalent organic group formed by the fluorination of RA, etc., RBF is the same group as RB, etc., EF is a bivalent connecting group formed by the fluorination of E, etc., EF1 is a monovalent group formed by the decomposition of EF, and X is a halogen atom.

    摘要翻译： 本发明提供了一种可用于例如氟原子的磺酰氟化合物的方法。 用于离子交换膜的材料可以在没有结构限制的情况下有效且低成本地生产，同时解决生产上的困难。 也就是说，本发明提供了一种方法，其包括使XSO 2 - （R） - （1）与R B， （2）以形成XSO 2 R A，A，B B（3），然后 使（3）与氟在液相中反应以形成FSO 2 R AF，从而形成FSO 2 - （4），并且进一步分解化合物以获得FSO 2 R 1 AF 1 F 1（5），其中R A 是二价有机基团，E 1是一价反应性基团，R B是一价有机基团，E 2是 与E 1反应的一价反应性基团，E是通过E 1和E 2反应形成的二价连接基团，R 2 AFO是通过R A A等的氟化形成的二价有机基团，R BF是与R B相同的基团 等等，E是通过E等氟化形成的二价连接基团， SUP>是通过分解形成的一价基团，X是卤素原子。