摘要:
[Problem] To provide a catalyst which has high oxygen reduction activity, also has excellent durability, and is inexpensive and excellent in electric power generation cost as compared with noble metal catalysts such as platinum.[Solution to problem] A catalyst for a polymer electrolyte fuel cell, including a graphitized carbon powder and a niobium oxycarbonitride or a titanium oxycarbonitride as an active substance, and a polymer electrolyte fuel cell using the catalyst.
摘要:
The invention provides catalysts which are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability. The catalysts include a niobium-containing oxycarbonitride having I2/(I1+I2) of not less than 0.25 wherein I1 is the maximum X-ray diffraction intensity at diffraction angles 2θ of 25.45 to 25.65 degrees and I2 is the maximum X-ray diffraction intensity at diffraction angles 2θ=2θ of 25.65 to 26.0 degrees according to X-ray powder diffractometry (Cu—Kα radiation).
摘要:
[Problem] To provide a catalyst which has high oxygen reduction activity, also has excellent durability, and is inexpensive and excellent in electric power generation cost as compared with noble metal catalysts such as platinum.[Solution to problem] A catalyst for a polymer electrolyte fuel cell, including a graphitized carbon powder and a niobium oxycarbonitride or a titanium oxycarbonitride as an active substance, and a polymer electrolyte fuel cell using the catalyst.
摘要:
The invention provides catalysts which are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability.The catalysts include a niobium-containing oxycarbonitride having I2/(I1+I2) of not less than 0.25 wherein I1 is the maximum X-ray diffraction intensity at diffraction angles 2θ of 25.45° to 25.65° and I2 is the maximum X-ray diffraction intensity at diffraction angles 2θ=2θ of 25.65° to 26.0° according to X-ray powder diffractometry (Cu—Kα radiation).
摘要:
The invention provides processes for producing fuel cell catalysts that are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability.The process for producing fuel cell catalysts includes a step (I) of heating a carbonitride of a transition metal in an inert gas containing oxygen, and a step (II) of heating the product from the step (I) in an inert gas that does not substantially contain oxygen.
摘要:
An electrode for electrolytic capacitors having a large capacitance and having excellent tan δ, heat resistance, humidity resistance and stability. An electrolytic capacitor using the electrode. An electrode obtained by attaching a compound having a siloxane bond onto the surface of an electrode body comprising a valve-acting metal having formed thereon a dielectric film. The compound having a siloxane bond is attached by coating, dipping or vapor deposition. A solid electrolytic capacitor obtained by forming an electrolyte comprising an electrically conducting polymer on the electrode.
摘要:
A solid electrolytic capacitor comprises an electrically conducting polymer composition formed on the surface of an oxide film which is formed on a valve-acting metal, by specifying the viscosity of an oxidizing agent solution and/or a monomer solution, particularly by specifying the viscosity to less than about 100 cp. A solid electrolytic capacitor can comprise an electroconducting polymer composition formed on the surface of an oxide film layer which is formed on a valve-acting metal, wherein a monomer compound or a derivative thereof as a repeating unit is polymerized by setting the humidity in the atmosphere to from about 10% to less than about 60%.
摘要:
The present invention relates to a solid electrolytic capacitor comprising a solid electrolyte layer and an electrically conducting layer comprising metallic powder or an electrically conducting layer comprising an electrically conducting carbon layer and a layer formed thereon and comprising metallic powder in which at least one of said layers contains a rubber-like elastic material; a production process thereof; a solid electrolyte for use in the solid electrolytic capacitor; a production process of the solid electrolyte; an electrically conducting paste for use in the solid electrolytic capacitor; and an electrically carbon conducting paste for use in the solid electrolytic capacitor. The solid electrolytic capacitor of the present invention can be made compact and can be endowed with high-capacitance and low-impedance and is excellent in external force-relaxing properties, productivity, heat resistance and moisture resistance, etc.
摘要:
The present invention relates to a solid electrolytic capacitor having a masking structure in which the insulation between the anode part and the cathode part can be ensured without fail, to its production method, to a method for coating a masking agent on a solid electrolytic capacitor substrate, and to apparatus therefore. According to the present invention, the masking material covers the dielectric film on the metal material having valve action and sufficiently infiltrates into the core metal made of a metal having valve action while the solid electrolyte is masked by the masking material without fail, so that a solid electrolytic capacitor can be produced that has a reduced leakage current and a reduced stress generated at the reflow treatment or the like.
摘要:
A solid electrolytic capacitor includes a valve acting metal having microfine pores, a dielectric film formed on a surface of the valve acting metal, and a solid electrolyte layer provided on the dielectric film, in which at least a portion of the solid electrolyte layer is of a lamellar structure. In particular, a solid electrolytic capacitor includes an electrically conducting polymer having a specified condensed ring structure containing (1) a solid electrolyte layer containing a sulfoquinone anion, and (2) a solid electrolyte layer containing an anthracenesulfonate ion and other anion.