摘要:
Provided is a process for producing a fuel cell electrode catalyst with high catalytic activity that is alternative to a noble metal catalyst, through a heat treatment at a relatively low temperature. A process for producing a fuel cell electrode catalyst includes a step (I) of obtaining a catalyst precursor, including a step (Ia) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), and a fluorine-containing compound (3), and a step (II) of heat-treating the catalyst precursor at a temperature of 500 to 1300° C. to obtain an electrode catalyst, a portion or the entirety of the metal compound (1) being a compound containing an atom of a metal element M1 selected from the group consisting of iron, cobalt, chromium, nickel, copper, zinc, titanium, niobium and zirconium, and at least one of the compounds (1), (2) and (3) containing an oxygen atom.
摘要:
The present invention provides a catalyst which is not corroded in an acidic electrolyte or at a high potential, is excellent in durability and has high oxygen reduction ability. The catalyst of the present invention is characterized by including a niobium oxycarbonitride. The catalyst of the invention is also characterized by including a niobium oxycarbonitride represented by the composition formula NbCxNyOz, wherein x, y and z represent a ratio of the numbers of atoms and are numbers satisfying the conditions of 0.01≦x≦2, 0.01≦y≦2, 0.01≦z≦3 and x+y+z≦5.
摘要翻译:本发明提供一种在酸性电解质中没有腐蚀或高电位的催化剂,其耐久性优异,氧还原能力高。 本发明的催化剂的特征在于包括铌碳氮氧化物。 本发明的催化剂的特征还在于包含由组成式NbC x N y O z表示的铌碳氮氧化物,其中x,y和z表示原子数的比例,并且是满足条件为0.01≦̸ x≦̸ 2,0.01&nlE ; y≦̸ 2,0.01≦̸ z≦̸ 3和x + y + z≦̸ 5。
摘要:
Provided is a process for producing a fuel cell electrode catalyst with high catalytic activity that is alternative to a noble metal catalyst, through a heat treatment at a relatively low temperature. A process for producing a fuel cell electrode catalyst includes a step (I) of obtaining a catalyst precursor, including a step (Ia) of mixing at least a metal compound (1), a nitrogen-containing organic compound (2), and a fluorine-containing compound (3), and a step (II) of heat-treating the catalyst precursor at a temperature of 500 to 1300° C. to obtain an electrode catalyst, a portion or the entirety of the metal compound (1) being a compound containing an atom of a metal element M1 selected from the group consisting of iron, cobalt, chromium, nickel, copper, zinc, titanium, niobium and zirconium, and at least one of the compounds (1), (2) and (3) containing an oxygen atom.
摘要:
Catalysts of the invention are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability. A catalyst includes a metal oxycarbonitride containing niobium and at least one metal M selected from the group consisting of tin, indium, platinum, tantalum, zirconium, copper, iron, tungsten, chromium, molybdenum, hafnium, titanium, vanadium, cobalt, manganese, cerium, mercury, plutonium, gold, silver, iridium, palladium, yttrium, ruthenium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and nickel. A process for making the catalyst involves a heat treatment.
摘要:
The invention provides catalysts that are not corroded in acidic electrolytes or at high potential and have excellent durability and high oxygen reducing ability, and processes for producing the catalysts and uses of the catalysts. The catalyst of the invention includes a metal oxycarbonitride that contains at least one metal selected from tantalum, vanadium, molybdenum and zirconium (hereinafter, also referred to as “metal M” or simply “M”) and does not contain any of platinum, titanium and niobium.
摘要:
Electrocatalyst layers include an electrocatalyst having high oxygen reduction activity that is useful as an alternative material to platinum catalysts. Uses of the electrocatalyst layers are also disclosed.The electrocatalyst layer includes an electrocatalyst that is formed of a metal oxide obtained by thermally decomposing a metal organic compound. The metal element forming the electrocatalyst is preferably one selected from the group consisting of niobium, titanium, tantalum and zirconium.
摘要:
A method for producing an aluminum foil for solid electrolytic capacitors, comprising the steps of cutting an aluminum foil into a shape of a capacitor element, etching a cut end part formed by said cutting, and then electrochemically forming the etched aluminum foil, aluminum foil for solid electrolytic capacitors obtained by the method, solid electrolytic capacitor using the aluminum foil, and method for producing such a solid electrolytic capacitor are disclosed. By use of the aluminum foil for solid electrolytic capacitors according to the present invention, capacitor characteristics such as an increase in the capacitor capacitance and a decrease in the leakage current from the cut end part of a stacked type aluminum solid electrolytic capacitor can be efficiently improved, the anode moieties can be efficiently connected without fail on stacking elements and the productivity of stacked type aluminum solid electrolytic capacitor can be elevated.
摘要:
The present invention relates to a solid electrolytic capacitor having a masking structure in which the insulation between the anode part and the cathode part can be ensured without fail, to its production method, to a method for coating a masking agent on a solid electrolytic capacitor substrate, and to apparatus therefore. According to the present invention, the masking material covers the dielectric film on the metal material having valve action and sufficiently infiltrates into the core metal made of a metal having valve action while the solid electrolyte is masked by the masking material without fail, so that a solid electrolytic capacitor can be produced that has a reduced leakage current and a reduced stress generated at the reflow treatment or the like.
摘要:
A solid electrolytic capacitor comprises a porous valve acting metal having formed thereon a dielectric film and a solid electrolyte formed on the dielectric film. The solid electrolyte occupies from 10 to 95% of the space within a pore of the porous metal.
摘要:
A solid electrolytic capacitor includes a valve acting metal having microfine pores, a dielectric film formed on a surface of the valve acting metal, and a solid electrolyte layer provided on the dielectric film, in which at least a portion of the solid electrolyte layer is of a lamellar structure. In particular, a solid electrolytic capacitor includes an electrically conducting polymer having a specified condensed ring structure containing (1) a solid electrolyte layer containing a sulfoquinone anion having a sulfo anion group and a quinone structure and other anion, and (2) a solid electrolyte layer containing an anthracenesulfonate ion and other anion.