HOST MATERIALS FOR ELECTROLUMINESCENT DEVICES

    公开(公告)号:US20200168811A1

    公开(公告)日:2020-05-28

    申请号:US16683485

    申请日:2019-11-14

    Abstract: A compound of Formula I wherein at least one of R1 or R2 includes a polycyclic group selected from the group consisting of Formula A, Formula B, and Formula C: wherein X1, X2, X3, and X4 are independently CRA or N; X5, X6, X7, and X8 are independently CRB or N; X9, X10, X11, and X12 are independently CRC or N; X13, X14, X15, and X16 are independently CRD or N; X17, X18, X19, and X20 are independently CRE or N; X21, X22, X23, and X24 are independently CRF or N; X25, X26, X27, and X28 are independently CRG or N; X29, X30, X31, and X32 are independently CRH or N; Y is selected from the group consisting of O, S, NR, and CRR′; the maximum number of N atoms that can connect to each other within each ring is two; with the proviso that R1 does not connect to ring B, and R2 does not connect to ring A, and wherein at least one of RC and RD of Formula A is a direct bond or an organic linker, one of RE and RF of Formula B is a direct bond or an organic linker, or one of RG, RH, and RN of Formula C is a direct bond or an organic linker.

    Organic electroluminescent materials and devices

    公开(公告)号:US12167678B2

    公开(公告)日:2024-12-10

    申请号:US18065193

    申请日:2022-12-13

    Abstract: A compound of Formula I: wherein: X1-X8 are each independently C or N, wherein two adjacent X1-X8 are carbon-fused to a structure of Formula II: X9-X12 are each independently C or N; A1, A2, and A3 are each independently selected from the group consisting of O, S, Se, N, NR, CR, CRR′, SiR, SiRR′, GeR, and GeRR′, with at least one of A1 and A2 being N or NR; each occurrence of is independently a single bond or a double bond, wherein one occurrence of is a single bond and one occurrence of is a double bond; each of RA, RB, and RC independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each of occurrence R, R′, RA, RB, and RC is independently a hydrogen or a substituent selected from the group consisting of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, Formula IX, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, with at least one of R, R′, RA, RB, and RC comprising a group of Formula III, Formula IV, Formula V, Formula VI, Formula VII, Formula VIII, or Formula IX: each occurrence of Y1, Y2, and Y3 is independently absent, O, S, Se, NR, CRR′, SiRR′, or GeRR′; each occurrence of Ar1, and Ar2 is independently an optionally substituted aryl group or an optionally substituted heteroaryl group, wherein Ar1 and Ar2 are optionally joined or fused together to form a ring; each occurrence of X13-X20 is independently C or N, with the proviso that at least one of X13-X20 is N; each occurrence of A4 is selected from the group consisting of O, S, Se, NR, CRR′, SiRR′, and GeRR′; each occurrence of RX independently represents zero, mono, or up to a maximum allowed substitution to its associated ring; each occurrence of RX is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; each occurrence of RY is independently a hydrogen or a substituent selected from the group consisting of Formula III, Formula IV, Formula V, Formula VI, Formula IX, deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; the maximum number of N atoms that are connected to each other within a ring is two; and any two substituents are optionally joined or fused together to form a ring.

    Organic electroluminescent materials and devices

    公开(公告)号:US12167673B2

    公开(公告)日:2024-12-10

    申请号:US16703991

    申请日:2019-12-05

    Abstract: An improved organic light emitting device is disclosed that includes an emissive layer between an anode and a cathode, where the emissive layer has an aggregate of one or more neutral transition metal complexes having a square planar geometry. At least one of the one or more neutral transition metal complexes has a coordination metal selected from Ni, Pd, and Au. When a voltage is applied across the anode and cathode at room temperature, the emissive layer emits a luminescent radiation that has a first luminescent radiation component produced from exciplex formation by the transition metal complexes present in the emissive layer, and the first luminescent radiation component has a peak maximum wavelength λmax that is ≤500 nm at room temperature.

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