Organic electroluminescent materials and devices comprising benzimidazole-containing metal complexes

    公开(公告)号:US11613550B2

    公开(公告)日:2023-03-28

    申请号:US16854193

    申请日:2020-04-21

    摘要: A compound comprising a first ligand LA of Formula I or Formula II: wherein A1 and A2 are each independently C or Si; wherein each RA, and RB independently represents mono to the maximum allowable substitution, or no substitution; wherein each X1, X2, and X3 is independently C or N; wherein each R, R1, R2, R3, R4 and RA is independently a hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; wherein LA is complexed to a metal M; wherein M is optionally coordinated to one or more other ligands; wherein the ligand LA is optionally linked with the one or more other ligands to form a tridentate, tetradentate, pentadentate, or hexadentate ligand; and wherein any two substituents are optionally joined or fused together to form a ring.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:US20220069241A1

    公开(公告)日:2022-03-03

    申请号:US17409396

    申请日:2021-08-23

    IPC分类号: H01L51/00 C07F15/00 C09K11/06

    摘要: A compound of Formula I is disclosed. In the structure of Formula I, ring A and ring B are 5- or 6-membered rings; L1, L2, L3, and Z are each linking groups; a, b, and c are each 0 or 1, and a+b+c=2 or 3; K1, K2, K3, and K4 are each a direct bond, O, or S; Z1 to Z6 and X1 to X5 are each C or N; W is a linking group comprising 3 to 5 linking atoms, which can be further substituted; M is Pd or Pt; each RA, RB, RC, RD, RE, R, and R′ is selected from H or a variety of substituents, and can be joined to another substituent for form a ring. Organic light emitting devices, consumer products, formulations, and chemical structures containing the compounds are also disclosed.