摘要:
Oligomeric and/or polymeric polyoxazole and polythiazole precursors can be prepared with high purity, i.e., especially without chloride, in a simple manner if an aromatic and/or heterocyclic dihydroxy, dialkoxy or diaryloxydiamino compound or a corresponding dithio compound is reacted with a dicarboxylic acid in the presence of a carbodiimide. The precursors prepared in this manner are suitable, for instance, for the manufacture of protection and insulating layers.
摘要:
New crosslinked 1,2,4-oxadiazole elastomers have been prepared by thermally condensing (a) monomer having the formula H.sub.2 N(HON)C-R-Q, wherein Q is a triazine ring-forming group such as nitrile or amidine, or (b) a mixture of said monomer with R[C(NOH)NH.sub.2 ].sub.2, with R in these formulas standing for a bivalent organic radical having the formula--(CX.sub.2).sub.p --, or --CFY(OCF.sub.2 CFY).sub.m O(CX.sub.2).sub.p O(CFYCF.sub.2 O).sub.n CFY--wherein X is fluorine or hydrogen, Y is fluorine or trifluoromethyl, p ranges from 1 to 18, and m+n ranges from 2 to 7. In the monomer charge, the overall proportions of amidoxime groups to triazine ring-forming groups varies depending on the extent of crosslinking desired in the final polymer.The heat and chemical resistant elastomers disclosed can serve, for instance, as adhesives, caulking compounds, channel sealants, fuel tank liners.
摘要:
Diamidoxime monomers having the formula: ##STR1## are intermolecularly and thermally condensed to form a heat and chemical resistant polymer containing 1,2,4-oxadiazole linkages and having the formula: ##STR2## wherein R represents identical bivalent organic radicals or any combination of bivalent organic radicals selected from the group consisting of --(CX.sub.2).sub.p --, wherein p ranges from 2 to 8 when X is fluorine and 2 to 18 when X is hydrogen, chlorine, nitro or aryl; arylene; and an oligometric or polymeric radical prepared by reacting a dicarboxylic acid halide with a fluorinated epoxide and having the formula: CFY(OCF.sub.2 CFY).sub.m O(CX.sub.2).sub.p O(CFYCF.sub.2 O).sub.n CFY wherein Y is fluorine or trifluoromethyl, X is nitro, aryl, hydrogen, chlorine or fluorine, preferably the latter, p ranges from 1 to 18 and m+n ranges from 2 to 7.
摘要:
An economical process for continuously producing shaped articles of aromatic oxadiazole or aromatic oxadiazole/N-alkylhydrazide polymers from certain monomer solutions is provided. The process involves continuously feeding monomer solution into a heated, pressurized continuous reactor to provide dope which is continuously extruded into an aqueous medium to provide a shaped article.
摘要:
Permselective membranes comprising hydrazide-containing aromatic polymers complexed with selected metals that form square planar coordination complexes therewith; the membranes being prepared by reacting the polymer with a salt solution of the selected metal so that the metal is incorporated into the resulting membranes; the membranes being useful, among other things, for the reverse osmosis separation of a salt solute from an aqueous solvent.
摘要:
POLYAMIDES MADE BY REACTING, 1-, AND 2-LOWER ALKYL1,2,3,-TRIAZOLE-4,5-DICARBONYL HALIDES WITH DIAMINES WHICH ARE USEFUL FOR MAKING FIBERS AND FILMS.
摘要:
Described and claimed are polymers containing 1,2,5-thiadiazole rings in the polymer chain and their preparations. The polymers are capable of being made into films, fibers, coatings and molded objects.
摘要:
A COMPOUND OF THE FORMULA: R-CO-AR-O-(CH2)N-O-AR''-O-(CH2)M-O-AR"-CO-R
WHERE AR,AR'' AND AR" ARE EACH OF ANY ONE OF THE FOLLOWING DIRADICALS:
1,4-PHENYLENE, NAPHTHALENE, PHENYLENE-X-PHENYLENE, AND BIPHENYLENE
X IS -O-, -CO-, -S-, -SO-, -SO2-, -C(-A)(-B)-,
-C(-D)(-E)-, OR -(CH2)P-
A, B, D AND E ARE EACH ANY ONE OF THE SUBSTITUENTS -H, -CH3 AND -CH2H5, R IS HYDROXY, HALOGEN OR ALKOXY M, N, AND P ARE EACH AN INTEGER WHICH IS NOT LESS THAN 2 AND NOT MORE THAN 6, AND THE AROMATIC RING, OR EITHER OR BOTH OF THE AROMATIC RINGS, OF THE DIRADICALS MAY OPTIONALLY BE SUBSTITUTED IN AT LEAST ONE OF THE FREE POSITIONS, EACH SUCH SUBSTITUENT BEING A METHYL, ETHYL, METHOXY, ETHOXY OR HALOGEN SUBSTITUENT, AND POLYMERIC PRODUCTS PREPARED THEREFROM. SHAPED ARTICLES CAN BE PREPARED FROM SUCH POLYMERIC PRODUCTS.
摘要:
NOVEL HIGH TEMPERATURE RESISTANT RESIN HAVING N-ALKYLHYDRAZIDE UNITS WHOSE ALKYL GROUP HAS 2 TO 4 CARBON ATOMS, IS PREPARED BY REACTING POLYOXADIAZOLE WITH ALKYL SULFATE WHOSE ALKYL GROUP HAS 2 TO 4 CARBON ATOMS IN CONCENTRATED SULFURIC ACID. THUS OBTAINED RESIN IS FUSIBLE AND SOLUBLE OR INSOLUBLE IN ORGANIC SOLVENTS AND CAN BE CONVERTED INTO POLYOXADIAZOLE AGAIN BY HEAT-TREATMENT WHICH HAS HIGHER TEMPERATURE RESISTANCE.
摘要:
THERMALLY STABLE FIBERS AND FILMS HAVE BEEN PREPARED BY REACTION OF EQUIMOLAR QUANTITIES OF AN AMINO AROYL HYDRAZIDE AND AN ACID DICHLORIDE. THE POLYMERS CAN BE CONVERTED TO THE CORRESPONDING AMIDE-OXADIAZOLE POLYMERS BY DEHYDRATION.