公开(公告)号：US20230277980A1

公开(公告)日：2023-09-07

申请号：US18317652

申请日：2023-05-15

Applicant: Saudi Arabian Oil Company

Inventor： Junyan Yang

IPC: B01D53/22 ,  B01D69/02 ,  B01D67/00 ,  B01D71/16 ,  B01D71/18 ,  C10L3/10 ,  B01D71/62

CPC classification number: B01D53/228 ,  B01D69/02 ,  B01D67/0083 ,  B01D71/16 ,  B01D71/18 ,  C10L3/104 ,  B01D67/0093 ,  B01D71/62 ,  B01D2325/023 ,  C10L2290/548

Abstract: A gas separation membrane, methods of forming the membrane, and methods of using the membrane for gas separation are provided. An exemplary gas separation membrane includes a cellulosic matrix and a polymer of intrinsic microporosity (PIM). The PIM includes chains coupled by a heat-treating under vacuum.

公开(公告)号：US09975092B2

公开(公告)日：2018-05-22

申请号：US15093961

申请日：2016-04-08

Applicant: FUJIFILM Corporation

Inventor： Kenji Kano ,  Kenichi Ishizuka ,  Satoshi Sano

IPC: B01D53/22 ,  B01D69/12 ,  B01D69/02 ,  B01D71/64 ,  B01D71/70 ,  B01D71/80 ,  B01D53/62 ,  B01D71/16 ,  B01D71/52 ,  B01D71/56 ,  B01D71/62

CPC classification number: B01D69/12 ,  B01D53/228 ,  B01D53/62 ,  B01D69/02 ,  B01D71/16 ,  B01D71/52 ,  B01D71/56 ,  B01D71/62 ,  B01D71/64 ,  B01D71/70 ,  B01D71/80 ,  B01D2053/221 ,  B01D2256/10 ,  B01D2256/16 ,  B01D2256/20 ,  B01D2256/24 ,  B01D2256/245 ,  B01D2257/302 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/404 ,  B01D2257/502 ,  B01D2257/504 ,  B01D2258/0233 ,  B01D2258/025 ,  B01D2258/0283 ,  B01D2258/05 ,  B01D2325/04 ,  B01D2325/20 ,  Y02C10/04 ,  Y02C10/10

Abstract: Provided is a gas separation membrane 10 including a separation layer 1 which comprises a block copolymer having at least a first segment and a second segment, in which the separation layer 1 has a phase separation structure that has at least a first structure 11 derived from the first segment and a spherical second structure 12 derived from the second segment. The gas separation membrane in which the spherical second structure satisfies Formula 1, the first structure and the spherical second structure satisfy the following Formula 2, and the first structure 11 has a structure that is continuous in the thickness direction over the entire thickness of the separation layer 1 has high gas permeability and high gas separation selectivity. Also provided is a gas separation membrane module. R/L

公开(公告)号：US20180021740A1

公开(公告)日：2018-01-25

申请号：US15679160

申请日：2017-08-17

Applicant: FUJIFILM Corporation

Inventor： Koji HIRONAKA ,  Keisuke KODAMA ,  Satoshi SANO

IPC: B01D71/64 ,  C08G77/455 ,  C10L3/10 ,  C08G73/12 ,  B01D71/80 ,  B01D61/36

CPC classification number: B01D71/64 ,  B01D53/1475 ,  B01D53/228 ,  B01D61/364 ,  B01D69/02 ,  B01D69/12 ,  B01D71/62 ,  B01D71/70 ,  B01D71/80 ,  B01D2256/22 ,  B01D2256/245 ,  B01D2257/504 ,  B01D2257/7025 ,  B01D2258/05 ,  B01D2325/023 ,  C01B32/55 ,  C07C9/04 ,  C08G73/1085 ,  C08G73/128 ,  C08G73/22 ,  C08G77/455 ,  C09D183/04 ,  C10L3/104 ,  C10L2290/548 ,  Y02C10/10 ,  Y02C20/20 ,  Y02P20/152 ,  Y02P20/156

Abstract: A gas separation membrane has a gas separation layer containing a poly(benzoxazole-imide) compound in which the poly(benzoxazole-imide) compound having structural units represented by General formulae (I) and (II), or structural units represented by General formulae (I), (II) and (III) satisfies a specific molar quantity condition. In the formulae, X and Y each represent a single bond or a specific divalent linking group; L represents a specific divalent linking group including a phenylene group; and R represents a specific group. A gas separation module and a gas separation method use the gas separation membrane. A gas separation apparatus includes the gas separation module.

公开(公告)号：US09862801B2

公开(公告)日：2018-01-09

申请号：US14933412

申请日：2015-11-05

Applicant: THE UNIVERSITY COURT OF THE UNIVERSITY OF EDINBURGH

Inventor： Neil Bruce McKeown ,  Mariolino Carta

IPC: C08G73/06 ,  C08G73/10 ,  B01D71/62 ,  B01D71/64 ,  C08L79/04 ,  C08L79/08 ,  C08G69/40 ,  C08G73/02 ,  C08G69/00

CPC classification number: C08G73/0694 ,  B01D71/62 ,  B01D71/64 ,  C08G73/1039 ,  C08G73/1085 ,  C08L79/04 ,  C08L79/08

Abstract: A method for the manufacture of a polymer is provided, the method comprising: Providing a first monomer, the first monomer comprising a bicyclic diamine moiety, a first nucleophilic group provided on a carbon atom of an aromatic moiety, and a second nucleophilic group provided on a carbon atom of an aromatic moiety; Providing a bridging compound comprising at least two sites vulnerable to nucleophilic attack; and Contacting the first monomer with the bridging compound. Polymers made by said method and uses of such polymers are also disclosed.

公开(公告)号：US20170165614A1

公开(公告)日：2017-06-15

申请号：US15342424

申请日：2016-11-03

Applicant: IMPERIAL INNOVATIONS LIMITED

Inventor： Andrew Guy LIVINGSTON ,  Yogesh Suresh BHOLE

IPC: B01D71/62 ,  B01D69/14 ,  B01D69/12 ,  B01D61/02 ,  B01D67/00

CPC classification number: B01D71/62 ,  B01D61/027 ,  B01D67/0011 ,  B01D67/0079 ,  B01D67/0097 ,  B01D69/02 ,  B01D69/125 ,  B01D69/141 ,  B01D2323/30 ,  B01D2325/022

Abstract: Improved integrally skinned asymmetric membranes for organic solvent nanofiltration, and their methods of preparation and use are disclosed. Membranes are formed from polybenzimidazoles by phase inversion and are then crosslinked by addition of crosslinking agents. These stabilise the membranes and allow solvent nanofiltration to be maintained even in the solvents from which the membranes were formed by phase inversion, and in strongly acidic and strongly basic solvents.

公开(公告)号：US20170114196A1

公开(公告)日：2017-04-27

申请号：US15318225

申请日：2015-06-12

Applicant: Thomas HÄRING ,  UNIVERSITÄT STUTTGART - INSTITUT FÜR CHEMISCHE VERFAHRENSTECHNIK ,  UNIVERSITÄT STUTTGART

Inventor： Thomas HÄRING ,  Jochen KERRES ,  Carlo MORANDI

IPC: C08J5/22 ,  H01M8/1027 ,  H01M2/16 ,  C08J3/24 ,  H01M8/1034 ,  H01M8/1039 ,  C25B13/08 ,  B01D71/62 ,  H01M8/1032

CPC classification number: C08J5/2262 ,  B01D71/62 ,  B01D71/76 ,  B01D2325/40 ,  B01D2325/42 ,  C08J3/246 ,  C08J5/2256 ,  C08J2371/10 ,  C08J2371/12 ,  C08J2379/04 ,  C08J2379/08 ,  C08J2381/06 ,  C08J2425/04 ,  C08J2471/10 ,  C08J2471/12 ,  C08J2479/04 ,  C08J2481/06 ,  C25B13/08 ,  H01M2/145 ,  H01M2/1653 ,  H01M8/1018 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M8/1081 ,  H01M8/1088 ,  Y02P70/56

Abstract: Described is a method for producing covalently and/or ionically cross-linked blend membranes from a halomethylated polymer, a polymer comprising tertiary N-basic groups, preferably polybenzimidazole, and, optionally, a polymer comprising cation exchanger groups such as sulfonic acid groups or phosphonic acid groups. The membranes can be tailor-made in respect of the properties thereof and are suitable, for example, for use as cation exchanger membranes or anion exchanger membranes in low-temperature fuel cells or low-temperature electrolysis or in redox flow batteries, or—when doped with proton conductors such as phosphoric acid or phosphonic acid—for use in medium-temperature fuel cells or medium-temperature electrolysis.

公开(公告)号：US09616395B2

公开(公告)日：2017-04-11

申请号：US14645615

申请日：2015-03-12

Applicant: PALL CORPORATION

Inventor： Khaled Abdel-Hakim Helmy Aamer ,  Amarnauth Singh ,  Selina Shi

IPC: B01D71/80 ,  B01D67/00 ,  B01D71/62 ,  B01D71/52 ,  B01D71/72

CPC classification number: B01D71/80 ,  B01D67/0016 ,  B01D71/52 ,  B01D71/62 ,  B01D71/72 ,  B01D2323/00

Abstract: Disclosed are membranes formed from self-assembling diblock copolymers of the formula (I): wherein R1-R4, n, and m are as described herein, which find use in preparing porous membranes. Embodiments of the membranes contain the diblock copolymer self-assembled into a cylindrical morphology. Also disclosed is a method of preparing such membrane which involves spray coating a polymer solution containing the diblock copolymer to obtain a thin film, followed by annealing the thin film in a solvent vapor and/or soaking in a solvent or mixture of solvents to form a nanoporous membrane.

公开(公告)号：US20170081477A1

公开(公告)日：2017-03-23

申请号：US15269101

申请日：2016-09-19

Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM ,  Virginia Tech Intellectual Properties, Inc.

Inventor： James E. McGrath ,  Judy S. Riffle ,  Benny D. Freeman

IPC: C08G73/06 ,  B01D53/22 ,  B01D71/68 ,  C07C315/04

CPC classification number: B01D71/68 ,  B01D53/228 ,  B01D71/62 ,  B01D2256/16 ,  B01D2256/18 ,  B01D2257/104 ,  B01D2257/108 ,  B01D2257/11 ,  B01D2257/504 ,  C07C315/04 ,  C08G73/18 ,  Y02C10/10 ,  Y02P20/152 ,  C07C317/14 ,  C07C317/36

Abstract: Disclosed are polybenzimidazoles containing sulfonyl groups. The polymers can be synthesized in Eaton's reagent from 3,3′,4,4′-tetraaminodiphenylsulfone, which itself can be synthesized from 4,4′-dichlorodiphenylsulfone. Methods of synthesizing the polymers are disclosed. The disclosed polymers can be used for high temperature H2/CO2 separation membranes and other uses.

公开(公告)号：US20170073251A1

公开(公告)日：2017-03-16

申请号：US15309016

申请日：2014-05-06

Applicant: GENERAL ELECTRIC COMPANY

Inventor： Zijun XIA ,  Caroline Chihyu SUI ,  Qunjian HUANG ,  Yida XU ,  Jeffrey I. Melzer ,  Wei LU ,  Xing ZHANG ,  Yanju WANG ,  Xiaoan XIE

IPC: C02F1/461 ,  D01D5/00 ,  B01D71/62 ,  D04H1/4326 ,  B01D69/02 ,  B01D69/10 ,  C02F1/467 ,  D04H1/728

CPC classification number: C02F1/46109 ,  B01D69/02 ,  B01D69/10 ,  B01D71/62 ,  B01D2323/39 ,  B01D2325/20 ,  C02F1/461 ,  C02F1/4674 ,  C02F1/4676 ,  C02F2001/46138 ,  C02F2001/46161 ,  C02F2201/46115 ,  C02F2303/04 ,  C25B9/203 ,  C25B11/0405 ,  D01D5/0007 ,  D04H1/4326 ,  D04H1/728

Abstract: A water treatment system comprises at least one electrolytic cell comprising at least one electrode and a power source for powering the electrode. The electrode may be a metal electrode comprising a coating of polymer comprising structural units of formula I (I) wherein R1 is independently at each occurrence a C1-C6 alkyl radical or —SO3M wherein M is independently at each occurrence a hydrogen or an alkali metal a hydrogen or an alkali metal, R2 is independently at each occurrence a C1-C6 alkyl radical, a is independently at each occurrence an integer ranging from 0 to 4, and b is independently at each occurrence an integer ranging from 0 to 3. An associated method is also described.

Abstract translation: 水处理系统包括至少一个包括至少一个电极和用于为电极供电的电源的电解池。 电极可以是包含聚合物涂层的金属电极，其包含式I（I）的结构单元，其中R 1在每次出现时独立地为C1-C6烷基或-SO3M，其中M在每次出现时独立地为氢或碱金属 氢或碱金属，R 2在每次出现时独立地为C 1 -C 6烷基，a在每次出现时独立地为0至4的整数，b在每次出现时独立地为0至3的整数。 还描述了相关联的方法。

公开(公告)号：US09469733B2

公开(公告)日：2016-10-18

申请号：US14292255

申请日：2014-05-30

Applicant: PALL CORPORATION

Inventor： Khaled Abdel-Hakim Helmy Aamer ,  Selina Shi

IPC: C08G81/00 ,  B01D71/64 ,  B01D71/80 ,  C08J5/22 ,  B01D71/62 ,  C08F222/40 ,  C08F234/02 ,  C08G61/12 ,  B82Y30/00

CPC classification number: C08G81/00 ,  B01D71/62 ,  B01D71/64 ,  B01D71/80 ,  B82Y30/00 ,  C08F222/40 ,  C08F234/02 ,  C08G61/12 ,  C08G61/124 ,  C08G61/125 ,  C08G2261/126 ,  C08G2261/1424 ,  C08G2261/148 ,  C08G2261/149 ,  C08G2261/3342 ,  C08G2261/614 ,  C08G2261/724 ,  C08J5/2256

Abstract: Disclosed are self-assembled structures prepared from block copolymers, for example, diblock copolymers of the formula (I): wherein R1-R4, n, and m are as described herein, which find use in preparing nanoporous membranes. In an embodiment, the block copolymer self-assembles into a cylindrical morphology. Also disclosed is a method of preparing such self-assembled structures which involves spin coating a polymer solution containing the block copolymer to obtain a thin film, followed by solvent annealing of the film. Further disclosed is a method of preparing porous membranes from the self-assembled structures.