公开(公告)号：US4536466A

公开(公告)日：1985-08-20

申请号：US594511

申请日：1984-03-29

申请人： Yukihiko Sakaguchi ,  Toshiaki Aono ,  Shinsaku Fujita

发明人： Yukihiko Sakaguchi ,  Toshiaki Aono ,  Shinsaku Fujita

IPC分类号： C07C43/20 ,  G03C1/498 ,  G03C8/40 ,  G03C1/40 ,  G03C1/34 ,  G03C5/54

CPC分类号： C07C43/20 ,  G03C1/49845 ,  G03C8/408

摘要： A method of forming an image comprising heating a light-sensitive material having at least a light-sensitive silver halide, a binder and a dye releasing redoc compound which is capable of reducing the light-sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye on a support, under the condition substantially free from water after or simultaneously with imagewise exposure, in the presence of a compound represented by the general formula (A) described below to form imagewise a mobile dye. ##STR1## wherein R represents an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group; R.sup.1 represents an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group; R.sup.2 represents an alkyl group, an aryl group, an aralkyl group, a halogen atom or a group of R.sup.1 NH; Z represents an atomic group necessary to form a carbon ring condensed to the benzene ring; n represents 0, 1 or 2; m represents 0 or an integer from 1 to 7 and m+n is not more than 7; l represents 0 or 1; and each of R.sup.1 and R.sup.2 may be the same or different when m or n represents 2 or more, respectively.In accordance with the method of the present invention, a clear color image having a high density can be obtained by a simple procedure and the light-sensitive material has an improved stability during preservation before heat-development procedure and the occurrence of fog and the change in the maximum density are restrained.A light-sensitive material comprising a support having thereon at least a light sensitive silver halide, a binder, a dye releasing redox compound which is capable of reducing the light sensitive silver halide and is capable of reacting with the light-sensitive silver halide by heating to release a hydrophilic dye and a compound represented by the general formula (A) above is also disclosed.

摘要翻译： 一种形成图像的方法，包括加热至少具有感光卤化银，粘合剂和释放染料的化合物的感光材料，所述光敏材料能够还原感光卤化银并且能够与光反应 在由下述通式（A）表示的化合物存在下，在基本上不含水的条件下或在成像曝光的同时，通过加热以在载体上释放亲水染料以释放亲水性染料以形成成像的移动 染料。 （A）其中R表示烷基，环烷基，芳基或芳烷基; R1表示烷基，环烷基，芳基或芳烷基; R2表示烷基，芳基，芳烷基，卤原子或R1NH基; Z表示形成与苯环稠合的碳环所必需的原子团; n表示0,1或2; m表示0或1〜7的整数，m + n不大于7; l表示0或1; 当m或n分别表示2或更大时，R 1和R 2各自可以相同或不同。 根据本发明的方法，可以通过简单的程序获得具有高密度的透明彩色图像，并且感光材料在热显影步骤之前的保存期间和雾的发生以及变化中具有改进的稳定性 在最大密度的限制。 一种感光材料，其包括其上具有至少一种光敏卤化银的载体，粘合剂，释放染料的氧化还原化合物，其能够还原感光卤化银并且能够通过加热与感光卤化银反应 还公开了亲水性染料和上述通式（A）表示的化合物。

公开(公告)号：US06790569B2

公开(公告)日：2004-09-14

申请号：US09858398

申请日：2001-05-16

申请人： Xiqiang Yang ,  Zbyslaw R. Owczarczyk ,  David T. Southby ,  Mark E. Irving ,  Paul B. Merkel ,  Lyn M. Irving ,  David H. Levy

发明人： Xiqiang Yang ,  Zbyslaw R. Owczarczyk ,  David T. Southby ,  Mark E. Irving ,  Paul B. Merkel ,  Lyn M. Irving ,  David H. Levy

IPC分类号： G03C516

CPC分类号： G03C8/4013 ,  G03C1/42 ,  G03C1/498 ,  G03C1/49845 ,  G03C7/28 ,  G03C8/402 ,  G03C8/408 ,  G03C2200/43 ,  G03C2200/52 ,  G03C2200/60 ,  Y10S430/165

摘要： A color photothermographic element comprising at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, and a blocked developer in the presence of a thermal solvent represented by the following structure: wherein the groups are as defined in the specification to promote the thermal development of the photothermographic element.

摘要翻译： 一种彩色光热敏成像元件，其包括至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一种感光卤化银乳剂，粘合剂和染料供应成色剂，以及封闭显影剂 在由以下结构表示的热溶剂的存在下，其中基团如说明书中所定义，以促进光热敏成像元件的热显影。

公开(公告)号：US20030228548A1

公开(公告)日：2003-12-11

申请号：US10387078

申请日：2003-03-12

发明人： Richard P. Szajewski ,  Lyn M. Irving

IPC分类号： G03C007/26 ,  G03C007/32

CPC分类号： G03C8/408 ,  G03C1/42 ,  G03C1/498 ,  G03C5/261 ,  G03C7/30 ,  G03C7/3005 ,  G03C7/30511 ,  G03C7/30541 ,  G03C7/407 ,  G03C2200/21 ,  Y10S430/156 ,  Y10S430/16

摘要： The present invention relates to a novel blocked phenylenediamine developer useful, in reactive association, for enabling, on development, a non-magenta color, for example a cyan color, from a dye-forming coupler. In one embodiment, the developer has the property that the dye color formed with the coupler is distinctly different from the color formed by the same coupler with an oxidized form of the conventional developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine. The invention is also directed to a light-sensitive silver-halide color photographic element comprising the blocked developing agent according to the present invention.

公开(公告)号：US20030228546A1

公开(公告)日：2003-12-11

申请号：US10419218

申请日：2003-04-21

发明人： Tomoaki Nagahara ,  Gen Hayashi

IPC分类号： G03C001/85 ,  G03C008/00

CPC分类号： G03C1/385 ,  B41M5/124 ,  B41M5/30 ,  G03C1/49863 ,  G03C1/85 ,  G03C8/408

摘要： An information recording material which contains a fluorine-containing nonionic surfactant, 1.5null10null5 mol/m2 or more of a polyvalent metal salt, and an anionic surfactant capable of forming a sparingly soluble salt in an aqueous solution with the polyvalent metal, in the outermost layer on a support on the side of an information recording layer. The information recording material is less in static charge and improved in surface deficiencies due to coating.

摘要翻译： 含有1.5×10 -5 mol / m 2以上多价金属盐的含氟非离子表面活性剂和能够在水溶液中形成微溶盐的阴离子表面活性剂的信息记录材料， 多价金属，位于信息记录层一侧的支撑体的最外层。 信息记录材料的静电荷较少，并且由于涂层而改善了表面缺陷。

公开(公告)号：US06570034B2

公开(公告)日：2003-05-27

申请号：US09871522

申请日：2001-05-31

申请人： Richard P. Szajewski ,  Lyn M. Irving

发明人： Richard P. Szajewski ,  Lyn M. Irving

IPC分类号： C07C26100

CPC分类号： G03C8/408 ,  G03C1/42 ,  G03C1/498 ,  G03C5/261 ,  G03C7/30 ,  G03C7/3005 ,  G03C7/30511 ,  G03C7/30541 ,  G03C7/407 ,  G03C2200/21 ,  Y10S430/156 ,  Y10S430/16

摘要： The present invention relates to a novel blocked phenylenediamine developer useful, in reactive association, for enabling, on development, a non-magenta color, for example a cyan color, from a dye-forming coupler. In one embodiment, the developer has the property that the dye color formed with the coupler is distinctly different from the color formed by the same coupler with an oxidized form of the conventional developer 4-(N-ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine. The invention is also directed to a light-sensitive silver-halide color photographic element comprising the blocked developing agent according to the present invention.

摘要翻译： 本发明涉及一种新颖的封端苯二胺显影剂，它们具有反应性缔合的作用，可以显影出来自染料形成成色剂的非品红色，例如青色。 在一个实施方案中，显影剂具有由偶联剂形成的染料颜色明显不同于由常规显影剂4-（N-乙基-N-2-羟乙基） - 2-甲基苯二胺。 本发明还涉及包含根据本发明的封闭显影剂的感光卤化银彩色照相元件。

公开(公告)号：US06440618B1

公开(公告)日：2002-08-27

申请号：US09711548

申请日：2000-11-13

申请人： Wojciech K. Slusarek ,  Xiqiang Yang ,  David H. Levy

发明人： Wojciech K. Slusarek ,  Xiqiang Yang ,  David H. Levy

IPC分类号： G03C142

CPC分类号： G03C7/30511 ,  G03C7/305 ,  G03C7/30541 ,  G03C7/30576 ,  G03C8/408 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16 ,  Y10S430/165

摘要： This invention relates to an imaging element comprising an imaging layer having associated therewith a compound of Structure I: In the above Structure I, the substituents are as defined in the application, wherein B is a six-membered heteroaromatic ring. Such compounds have good reactivity and can by used to block photographically useful compounds such as developing agents until thermally activated under preselected conditions. Compounds according to the present invention are especially useful in color photothermographic imaging elements.

摘要翻译： 本发明涉及一种成像元件，其包括具有结构I的化合物的成像层：在上述结构I中，取代基如本申请中所定义，其中B为六元杂芳环。 这些化合物具有良好的反应性，并且可以通过用于阻挡照相用的化合物如显影剂，直到在预选条件下热活化。 根据本发明的化合物在彩色光热敏成像元件中特别有用。

公开(公告)号：US20020022200A1

公开(公告)日：2002-02-21

申请号：US09863595

申请日：2001-05-23

发明人： Mark E. Irving ,  David T. Southby

IPC分类号： G03C001/498

CPC分类号： G03C7/30541 ,  G03C1/42 ,  G03C1/49845 ,  G03C7/30552 ,  G03C7/407 ,  G03C7/4136 ,  G03C8/4013 ,  G03C8/408 ,  G03C2200/43 ,  Y10S430/156 ,  Y10S430/158 ,  Y10S430/16

摘要： The present invention is directed to a method of processing color photographic film that has been imagewise exposed in a camera, said film having at least three light-sensitive units which have their individual sensitivities in different wavelength regions, each of the units comprising at least one light-sensitive silver-halide emulsion, binder, and dye-providing coupler, which method in order comprises: (a) thermally developing the film step without any externally applied developing agent, comprising heating said film to a temperature greater than 80null C. in an essentially dry process, such that an internally located blocked developing agent in reactive association with each of said three light-sensitive units becomes unblocked to form a developing agent, whereby the unblocked developing agent forms dyes by reacting with the dye-providing couplers to form a color negative image; (b) processing the developed film of step (a) by contacting it with a non-blocked developing agent, under agitation at a temperature of 30 to 50null C. under aqueous alkaline conditions, without forming a color negative image in the film by reaction of the non-blocked developing agent with the dye-providing couplers inside the silver-halide emulsions, and (c) desilvering said film in one or more desilvering solutions to remove unwanted silver and/or silver halide, thereby forming a color negative image; and (d) thereafter forming a positive-image color print from the desilvered film.

摘要翻译： 本发明涉及一种在相机中成像曝光的彩色照相胶片的处理方法，所述胶片具有至少三个在不同波长区域具有各自敏感度的光敏单元，每个单元包括至少一个 感光卤化银乳剂，粘合剂和染料提供成色剂，该方法依次包括：（a）不用任何外用显影剂将膜步骤热显影，包括将所述膜加热到大于80℃的温度。 在基本上干燥的过程中，使得与所述三个光敏单元中的每一个反应性相关联的内部定位的阻挡显影剂变得未封闭以形成显影剂，由此未封闭的显影剂通过与提供染料的成色剂反应形成染料 形成彩色负像; （b）在水性碱性条件下，在30〜50℃的温度搅拌下，通过使其与非阻挡显影剂接触来处理显影的步骤（a）的膜，而不会在膜中形成彩色负像， 非阻挡显影剂与染料供应成色剂在卤化银乳剂内部的反应，和（c）在一种或多种脱银溶液中对所述膜进行脱溶剂以除去不需要的银和/或卤化银，从而形成彩色负像 ; 和（d）之后从脱膜膜形成正像彩色印刷品。

公开(公告)号：US06303261B1

公开(公告)日：2001-10-16

申请号：US09525946

申请日：2000-03-15

申请人： Jun Arakawa ,  Toshio Kawagishi

发明人： Jun Arakawa ,  Toshio Kawagishi

IPC分类号： G03C7305

CPC分类号： G03C8/408 ,  Y10S430/158 ,  Y10S430/159 ,  Y10S430/16

摘要： Disclosed are a silver halide color photographic material having on a support a photographic element in which silver halide grains, a developing agent and a coupler capable of forming a dye by reaction with an oxidation product of the developing agent are incorporated, the photographic element further comprising at least one color stain inhibitive compound represented by the following formula (SC-1) or (SC-2) and at least one photographically useful group-releasing compound represented by the following formula (II); and a method of forming color images by the use of the foregoing material: A—[(L1)a—(B)m]p—(L2)n—PUG  (II)

摘要翻译： 公开了一种卤化银彩色照相材料，其在载体上具有照相元件，其中并入卤化银颗粒，显影剂和能够通过与显影剂的氧化产物反应形成染料的成色剂，所述照相元件还包含 由下式（SC-1）或（SC-2）表示的至少一种着色剂抑制化合物和由下式（II）表示的至少一种照相用的释药化合物; 以及通过使用上述材料形成彩色图像的方法：

公开(公告)号：US06177227B1

公开(公告)日：2001-01-23

申请号：US09366652

申请日：1999-08-04

申请人： Hajime Nakagawa

发明人： Hajime Nakagawa

IPC分类号： G03C820

CPC分类号： G03C8/408

摘要： There is disclosed a heat-development color photographic light-sensitive material which has on a base at least two applied silver halide emulsion layers different in color sensitivity from each other and at least one applied non-light-sensitive layer, wherein the silver halide emulsion layer or the non-light-sensitive layer contains a dye providing compound and at least one specific diffusible electron transport agent, and wherein the non-light-sensitive layer contains a compound capable of reacting with an oxidized product of the electron transport agent. The light-sensitive material can provide an image excellent in discrimination even by subjecting to development for a short period of time, and is excellent in color separation.

摘要翻译： 公开了一种热显影彩色照相感光材料，其在基底上具有彼此不同颜色灵敏度的至少两个施加的卤化银乳剂层和至少一种施加的非感光层，其中卤化银乳剂 层或非感光层含有提供染料的化合物和至少一种特定的可扩散电子传递剂，并且其中非感光层含有能够与电子传输剂的氧化产物反应的化合物。 感光材料即使在短时间内显影也能够提供优异的鉴别图像，并且分色性优异。

公开(公告)号：US6010819A

公开(公告)日：2000-01-04

申请号：US138670

申请日：1998-08-24

申请人： Hiroshi Arakatsu ,  Nobuo Seto ,  Yoshisada Nakamura ,  Hironori Hiyoshi ,  Hiroyuki Watanabe ,  Takayoshi Kamio

发明人： Hiroshi Arakatsu ,  Nobuo Seto ,  Yoshisada Nakamura ,  Hironori Hiyoshi ,  Hiroyuki Watanabe ,  Takayoshi Kamio

IPC分类号： C09B29/46 ,  G03C7/392 ,  G03C8/40 ,  G03C8/26 ,  G03C7/46 ,  G03C8/10

CPC分类号： G03C8/408 ,  G03C7/39248

摘要： A method for improving light fastness of an image, which comprises releasing or forming an image forming dye or a precursor thereof corresponding or counter-corresponding to silver development and allowing an image formed by transferring said image forming dye or precursor thereof to coexist with a compound represented by general formula (I) in an image forming material ##STR1## The symbols in formula (I) are defined in the description. Also disclosed is an image forming material for use in the method.

摘要翻译： 一种用于提高图像的耐光性的方法，包括释放或形成与银显影相对应或对应于银显影的图像形成染料或其前体，并允许通过转印所述成像染料或其前体形成的图像与化合物共存 在图像形成材料中由通式（I）表示在说明书中定义式（I）中的符号。 还公开了用于该方法的成像材料。