Preparation of synthetic rubber
    31.
    发明授权
    Preparation of synthetic rubber 失效
    合成橡胶的制备

    公开(公告)号:US3583934A

    公开(公告)日:1971-06-08

    申请号:US3583934D

    申请日:1968-11-27

    申请人: ARIZONA CHEM

    IPC分类号: C08F36/04 C08D9/12

    CPC分类号: C08F36/04 C08F2/00 C08F4/28

    摘要: IN SYNTHETIC RUBBER MANUFACTURING PROCESSES WHREREIN AQUEOUS EMULSIONS OF BUTADIENE AND STYRENE OR BUTADIENE AND ACRYLONITRILE OR OTHER VINYL MONOMER ARE PREPARED WITH AN EMULSIFYING AGEN CONTAINING A WATER-SOLUBLE SOAP OF A DISPROPORTIONATED ROSIN AND ARE POLYMERIZED IN THE PRESENCE OF A FREE RADICAL CATALYST SYSTEM, THE ADVERSE ACTION OF FREE OXYGEN ON THE POLYMERIZATION IS OFFSET BY HEAT-MODIFYING THE DISPROPORTIONATED ROSIN BEFORE IT IS CONVERTED INTO ITS SOAP. THIS IS DONE BY HEATING IT AT ABOUT 250 -300*C. FOR ABOUT 1 TO 4 HOURS IN ADMIXTURE WITH ABOUT 0.5% OF ITS WEIGHT OF ACETIC ANHYDRIDE.

    Adhesive composition
    33.
    发明授权

    公开(公告)号:US3549574A

    公开(公告)日:1970-12-22

    申请号:US3549574D

    申请日:1968-03-15

    申请人: POLYMER CORP

    发明人: HAWKINS COLIN W

    IPC分类号: C09J123/22 C08D9/12

    CPC分类号: C09J123/22 C08L2666/02

    摘要: 1,196,087. Adhesive composition. POLYMER CORP Ltd. 27 March, 1968 [19 April, 1967], No. 14791/68. Heading C3P. An adhesive composition comprises a dispersion in a volatile organic liquid of a mixture of a cross-linked polymer of isobutylene, an elastomer and a tackifying resin, the polymer containing at least 20% by weight of gel. The amount of organic liquid present is preferably not less than 80% by weight of the composition. The proportion of tackifying resin to crosslinked polymer is preferably between 0À25:1 to 10: 1 by weight. The elastomer may be a butadiene-styrene copolymer present in from 1/3 to not more than 5 parts per part of cross-linked copolymer. In the examples, a copolymer of isobutylene, isoprene and divinyl benzene is dispersed in toluene and a butadiene-styrene copolymer, wood rosin and an antioxidant added thereto. Instead of wood rosin, an alkyl phenol aldehyde resin may be used. In some examples, butyl rubber and a butadiene-acrylonitrile copolymer is used instead of the butadiene styrene copolymer.