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公开(公告)号:US3583934A
公开(公告)日:1971-06-08
申请号:US3583934D
申请日:1968-11-27
申请人: ARIZONA CHEM
摘要: IN SYNTHETIC RUBBER MANUFACTURING PROCESSES WHREREIN AQUEOUS EMULSIONS OF BUTADIENE AND STYRENE OR BUTADIENE AND ACRYLONITRILE OR OTHER VINYL MONOMER ARE PREPARED WITH AN EMULSIFYING AGEN CONTAINING A WATER-SOLUBLE SOAP OF A DISPROPORTIONATED ROSIN AND ARE POLYMERIZED IN THE PRESENCE OF A FREE RADICAL CATALYST SYSTEM, THE ADVERSE ACTION OF FREE OXYGEN ON THE POLYMERIZATION IS OFFSET BY HEAT-MODIFYING THE DISPROPORTIONATED ROSIN BEFORE IT IS CONVERTED INTO ITS SOAP. THIS IS DONE BY HEATING IT AT ABOUT 250 -300*C. FOR ABOUT 1 TO 4 HOURS IN ADMIXTURE WITH ABOUT 0.5% OF ITS WEIGHT OF ACETIC ANHYDRIDE.
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32.
公开(公告)号:US3565841A
公开(公告)日:1971-02-23
申请号:US3565841D
申请日:1968-11-08
申请人: DU PONT
IPC分类号: C08L21/00 , C08L23/16 , C09J155/04 , C09J161/06 , C08D9/12
CPC分类号: C08L23/16 , C08L7/00 , C08L9/00 , C08L9/06 , C08L17/00 , C08L19/003 , C08L21/00 , C08L23/22 , C08L61/00 , C08L93/00 , C08L2312/00 , C09J155/04 , C09J161/06 , C08L2666/26 , C08L2666/02 , C08L2666/16 , C08L2666/08
摘要: AN HYDROCARBON ELASTOMER IS TACKIFIED BY UNIFORMLY MIXING WITH AN ORGANIC CYCLIC RESIN, WHICH HAS AT LEAST ONE POLAR FUNCTIONAL GROUP AND A MOLECULAR WEIGHT OF AT LEAST 200, AGING THE RESULTING MIXTURE IN THE SUBSTANTIAL ABSENCE OF OZONE AND FREE-RADICAL PRODUCING AGENTS UNTIL A PHASE, DIFFERENT FROM THE BULK OF THE MIXTURE, FORMS ON A SURFACE OF THE MIXTURE, FOLLOWED BY EXPOSING SAID SURFACE TO OZONE OR A FREE RADICAL PRODUCING AGENT.
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公开(公告)号:US3549574A
公开(公告)日:1970-12-22
申请号:US3549574D
申请日:1968-03-15
申请人: POLYMER CORP
发明人: HAWKINS COLIN W
IPC分类号: C09J123/22 , C08D9/12
CPC分类号: C09J123/22 , C08L2666/02
摘要: 1,196,087. Adhesive composition. POLYMER CORP Ltd. 27 March, 1968 [19 April, 1967], No. 14791/68. Heading C3P. An adhesive composition comprises a dispersion in a volatile organic liquid of a mixture of a cross-linked polymer of isobutylene, an elastomer and a tackifying resin, the polymer containing at least 20% by weight of gel. The amount of organic liquid present is preferably not less than 80% by weight of the composition. The proportion of tackifying resin to crosslinked polymer is preferably between 0À25:1 to 10: 1 by weight. The elastomer may be a butadiene-styrene copolymer present in from 1/3 to not more than 5 parts per part of cross-linked copolymer. In the examples, a copolymer of isobutylene, isoprene and divinyl benzene is dispersed in toluene and a butadiene-styrene copolymer, wood rosin and an antioxidant added thereto. Instead of wood rosin, an alkyl phenol aldehyde resin may be used. In some examples, butyl rubber and a butadiene-acrylonitrile copolymer is used instead of the butadiene styrene copolymer.
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公开(公告)号:US3538031A
公开(公告)日:1970-11-03
申请号:US3538031D
申请日:1968-05-02
发明人: RICE ALVIST V
IPC分类号: C09J153/02 , C08D9/12
CPC分类号: C09J153/02 , C08L2666/02 , C08L2666/28
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公开(公告)号:US3506602A
公开(公告)日:1970-04-14
申请号:US3506602D
申请日:1968-01-22
发明人: FLOROS JOHN C , WEI CHUNG HWEI
IPC分类号: C08F2/22 , C08F251/00 , C08D9/12
CPC分类号: C08F251/00 , C08F212/08
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