公开(公告)号：US08168369B2

公开(公告)日：2012-05-01

申请号：US13147342

申请日：2010-02-12

Applicant: Chang Ho Cho ,  Sung Hyun Kim ,  Raisa Kharbash ,  Keon Woo Lee ,  Dong Kung Oh ,  Won Jin Chung ,  Sang Kyu Kwak ,  Chang Soon Lee

Inventor： Chang Ho Cho ,  Sung Hyun Kim ,  Raisa Kharbash ,  Keon Woo Lee ,  Dong Kung Oh ,  Won Jin Chung ,  Sang Kyu Kwak ,  Chang Soon Lee

IPC: G03F7/00 ,  G03F7/004 ,  G03F7/028 ,  C07D209/82

CPC classification number: C07F9/5728 ,  C07D209/88 ,  C08F2/50 ,  G03F7/031 ,  Y10S430/106 ,  Y10S430/127

Abstract: The present invention relates to a photoactive compound of a novel structure represented by Chemical Formula 1 below In Chemical Formula 1, R1 and R2, R3, and A are as defined in the specification, and a photosensitive resin composition comprising the same. The photoactive compound of the present invention comprises a nitro group and a phosphonate structure and thus exhibits excellent sensitivity through efficient absorption for UV light, excellent compatibility between the photoactive compound and the alkali-soluble binder resin, and an improved solubility of the photosensitive resin composition. Furthermore, the photosensitive resin composition of the present invention has excellent residual film thickness and mechanical strength characteristics and heat-resistant, chemical-resistant, and development-resistant properties. Accordingly, the photosensitive resin composition of the present invention is advantageous in hardening the column spacers of liquid crystal displays, an overcoat, and passivation materials and also advantageous in a high-temperature process characteristic.

Abstract translation: 本发明涉及由化学式1化学式1表示的新结构的光敏化合物，其中R1，R2，R3，A如说明书中所定义，和含有该化合物的感光性树脂组合物。 本发明的光活性化合物包括硝基和膦酸酯结构，因此通过有效吸收UV光，光活性化合物和碱溶性粘合剂树脂之间的相容性优异，并且改善了感光性树脂组合物的溶解性而显示出极好的灵敏度 。 此外，本发明的感光性树脂组合物具有优异的残留膜厚度和机械强度特性以及耐热，耐化学腐蚀和耐开发性能。 因此，本发明的感光性树脂组合物有利于硬化液晶显示器的列间隔物，外涂层和钝化材料，并且在高温工艺特性中也是有利的。

公开(公告)号：US20100190103A1

公开(公告)日：2010-07-29

申请号：US12671416

申请日：2008-10-08

Applicant: Wook Jang ,  Chang Soon Lee ,  Woo Cheul Jeong ,  Ji Hoon Lee

Inventor： Wook Jang ,  Chang Soon Lee ,  Woo Cheul Jeong ,  Ji Hoon Lee

IPC: G03G9/00

CPC classification number: G03G9/0806 ,  G03G9/08711 ,  G03G9/08722 ,  G03G9/09725

Abstract: Disclosed is a method for producing a polymerized toner. In the method, a mixture of colloidal silica as an aqueous dispersant and a polyvinylpyrrolidone is used during suspension polymerization. The amount of polyvinylpyrrolidone/colloidal silica aggregates having a diameter smaller than 100 nm is also limited to 1% by weight or less, based on the total weight of all aggregates. A polymerized toner produced by the method has a volume average particle diameter (dv) of 5 to 10 μm and a volume average particle diameter/number average particle diameter ratio (dv/dp) of 1.5 or less. The polymerized toner is consumed in a small amount during printing. According to the method, the formation of emulsion particles having a size smaller than 0.5 μm is inhibited.

Abstract translation: 公开了一种聚合调色剂的制造方法。 在该方法中，在悬浮聚合中使用作为水性分散剂的胶体二氧化硅与聚乙烯吡咯烷酮的混合物。 直径小于100nm的聚乙烯吡咯烷酮/胶体二氧化硅聚集体的量也以所有聚集体的总重量计为1重量％以下。 通过该方法制造的聚合调色剂的体积平均粒径（dv）为5〜10μm，体积平均粒径/数均粒径比（dv / dp）为1.5以下。 聚合调色剂在印刷过程中少量消耗。 根据该方法，抑制了尺寸小于0.5μm的乳液颗粒的形成。

公开(公告)号：US20100160477A1

公开(公告)日：2010-06-24

申请号：US12654583

申请日：2009-12-23

Applicant: Chang Ho Cho ,  Keon Woo Lee ,  Sung Hyun Kim ,  Sang Kyu Kwak ,  Dong Kung Oh ,  Chang Soon Lee

Inventor： Chang Ho Cho ,  Keon Woo Lee ,  Sung Hyun Kim ,  Sang Kyu Kwak ,  Dong Kung Oh ,  Chang Soon Lee

IPC: C08J3/28

CPC classification number: C08J3/28 ,  C08K5/005 ,  G03F7/0007 ,  G03F7/027

Abstract: A composition for forming column spacers is provided. The composition comprises a radical polymerization inhibitor. The use of the composition enables simultaneous formation of a saturated pattern and a semi-transmissive pattern as column spacer patterns having different shapes, whose difference in thickness is controllable as desired although the sensitivity is slightly reduced, through a slit or semi-transmissive mask by varying the kind and amount of the radical polymerization inhibitor. Further provided are column spacers formed using composition and a liquid crystal display using the column spacers.

Abstract translation: 提供了用于形成柱间隔物的组合物。 组合物包含自由基聚合抑制剂。 使用该组合物可以同时形成饱和图案和半透明图案，作为具有不同形状的柱状间隔物图案，其厚度差可以通过狭缝或半透明掩模通过狭缝或半透明掩模通过稍微降低灵敏度来控制，尽管灵敏度略微降低 改变自由基聚合抑制剂的种类和量。 还提供了使用组合物形成的柱间隔物和使用柱间隔物的液晶显示器。

公开(公告)号：US20100112472A1

公开(公告)日：2010-05-06

申请号：US12611342

申请日：2009-11-03

Applicant: Wook JANG ,  Chang Soon LEE

Inventor： Wook JANG ,  Chang Soon LEE

IPC: G03G9/08 ,  G03G9/087

CPC classification number: G03G9/0872 ,  G03G9/0806 ,  G03G9/08704 ,  G03G9/08726 ,  G03G9/08728 ,  G03G9/08793 ,  G03G9/08797

Abstract: A polymerized toner is provided. The polymerized toner has cores containing polyvinylidene fluoride particles. The polyvinylidene fluoride particles have an average particle diameter of 1.1 to 1.5 μm and a melting temperature (Tm) of 140 to 160° C. The polyvinylidene fluoride particles are distributed at a higher concentration near the surface of the cores. This distribution improves the affinity of the cores for silica as an external additive to achieve an increased amount of surface charge and improved transfer efficiency of the polymerized toner. Further provided is a method of producing the polymerized toner.

Abstract translation: 提供聚合调色剂。 聚合的调色剂具有含有聚偏二氟乙烯颗粒的芯。 聚偏二氟乙烯粒子的平均粒径为1.1〜1.5μm，熔融温度（Tm）为140〜160℃。聚偏二氟乙烯粒子分布在芯的表面附近较高的浓度。 这种分布提高了二氧化硅作为外部添加剂的芯的亲和性，以实现增加的表面电荷量和改善聚合调色剂的转印效率。 还提供了生产聚合调色剂的方法。

公开(公告)号：US20090311618A1

公开(公告)日：2009-12-17

申请号：US12457545

申请日：2009-06-15

Applicant: Chang-Soon Lee ,  Hyeung-Jin Lee ,  Je-Sik Jung

Inventor： Chang-Soon Lee ,  Hyeung-Jin Lee ,  Je-Sik Jung

IPC: G03G9/093 ,  G03G9/08 ,  G03G9/097 ,  G03G9/087 ,  G03G5/00

CPC classification number: G03G9/0827 ,  G03G9/0819 ,  G03G9/08708 ,  G03G9/08711 ,  G03G9/0906 ,  G03G9/0924 ,  G03G9/09708 ,  G03G9/09725 ,  G03G9/09733 ,  G03G9/09783

Abstract: Provided is a non-magnetic mono-component color toner with improved charge properties by surface modification with a charge control agent. The color toner is prepared by spheroidizing toner core particles including a binder and a colorant in the presence of 0.5 to 3 parts by weight of a charge control agent and coating the resultant spherical toner core particles with a first spherical organic powder with an average particle size of 50 to 120 nm, a second spherical organic powder with an average particle size of 600 to 1,000 nm, silica with an average particle size of 5 to 20 nm, and titanium dioxide with an average particle size of 300 to 1,000 nm. The color toner exhibits excellent surface charge properties (e.g., a narrow charge distribution, high chargeability, and good charge maintenance capability), thereby ensuring low image/background contamination, high transfer efficiency, good image density and long-term stability.

Abstract translation: 提供了一种通过用电荷控制剂进行表面改性而具有改进的电荷特性的非磁性单组分彩色调色剂。 彩色调色剂是通过在0.5至3重量份的电荷控制剂存在下将包括粘合剂和着色剂的调色剂芯颗粒球化并用所得的球形调色剂核心颗粒用平均粒度的第一球形有机粉末 50〜120nm的平均粒径为600〜1000nm的二次球状有机粉末，平均粒径为5〜20nm的二氧化硅和平均粒径为300〜1000nm的二氧化钛。 彩色调色剂具有优异的表面电荷性能（例如，窄的电荷分布，高的充电性和良好的电荷维持能力），从而确保低图像/背景污染，高转印效率，良好的图像密度和长期的稳定性。

公开(公告)号：US07378206B2

公开(公告)日：2008-05-27

申请号：US10505914

申请日：2004-01-12

Applicant: Won-Sup Lee ,  Chang-Soon Lee ,  Hyea-Eun Han ,  Kwang-Ho Song

Inventor： Won-Sup Lee ,  Chang-Soon Lee ,  Hyea-Eun Han ,  Kwang-Ho Song

IPC: G03G9/087

CPC classification number: G03G9/08735 ,  G03G9/081 ,  G03G9/0812 ,  G03G9/08704 ,  G03G9/08755 ,  G03G9/08779 ,  G03G9/08782 ,  G03G9/08791 ,  G03G9/08797 ,  G03G9/09716 ,  G03G9/09725 ,  G03G9/09766

Abstract: The present invention relates to a non-magnetic mono-component toner composition, which comprises a) a non-magnetic toner particle comprising a binding resin comprising a binder resin and a copolymer of a cyclic olefin and an acyclic olefin polymerized in the presence of a metallocene catalyst and a cocatalyst, a colorant, and a charge-control agent; b) fine powder of an organic compound containing fluorine that is added to the surface of the non-magnetic toner particle; and c) hydrophobic silica having a specific surface area of 100 to 240 m2/g. The toner composition of the present invention has superior transfer efficiency and charging properties and thus can obtain a stable image, does not show deteriorated image density, and does not generate background contamination of non-image areas and off-set due to deterioration of fixing properties, even if copying or printing is conducted therewith for a long time use.

Abstract translation: 非磁性单组分调色剂组合物本发明涉及一种非磁性单组分调色剂组合物，其包含：a）非磁性调色剂颗粒，其包含粘合树脂，所述粘合树脂包含粘合剂树脂和环烯烃与无环烯烃的共聚物， 茂金属催化剂和助催化剂，着色剂和电荷控制剂; b）加入到非磁性调色剂颗粒表面的含氟有机化合物的细粉末; 和c）比表面积为100至240m 2 / g的疏水性二氧化硅。 本发明的调色剂组合物具有优异的转印效率和充电性能，因此可以获得稳定的图像，不会显示劣化的图像浓度，并且不产生非图像区域的背景污染和由于定影特性的劣化而偏移 即使长时间使用复印或打印也是如此。

公开(公告)号：US07252915B2

公开(公告)日：2007-08-07

申请号：US10500067

申请日：2002-12-24

Applicant: Won-Sup Lee ,  Chang-Soon Lee ,  In-Hee Lim

Inventor： Won-Sup Lee ,  Chang-Soon Lee ,  In-Hee Lim

IPC: G03G9/083

CPC classification number: G03G9/09716 ,  G03G9/0832 ,  G03G9/0833 ,  G03G9/09708

Abstract: The present invention relates to a magnetic mono-component toner composition, and more particularly to a mono-component toner composition that comprises magnetic toner particle comprising a binder resin, a magnetic component, and a charge control agent; a hydrophobic treated silica having a specific surface area of 20 to 80 m2/g; a hydrophobic treated silica having a specific surface area of 130 to 230 m2/g; and a metal oxide fine powder. A magnetic mono-component toner composition of the present invention has such good flowability that it provides smooth toner supply even when the developing roller surface has been worn due to long time use, and it has such excellent uniform chargeability that it prevents image deterioration (“wave” patterns of toner may form on developing roller, that is, magnetic sleeve) by forming an uniform toner layer on the developing roller.

Abstract translation: 本发明涉及一种磁性单组分调色剂组合物，更具体地说，涉及包含粘合剂树脂，磁性组分和电荷控制剂的磁性调色剂颗粒的单组分调色剂组合物; 比表面积为20〜80m 2 / g的疏水性处理二氧化硅; 比表面积为130〜230m 2 / g的疏水性处理二氧化硅; 和金属氧化物细粉末。 本发明的磁性单组分调色剂组合物具有这样良好的流动性，即使当显影辊表面由于长时间使用而磨损时也提供平滑的调色剂供应，并且具有如此优异的均匀带电性，从而防止图像劣化（“ 通过在显影辊上形成均匀的调色剂层，可以在显影辊上，即磁性套筒上形成调色剂的“波浪”图案。

公开(公告)号：US20060127787A1

公开(公告)日：2006-06-15

申请号：US10535222

申请日：2005-05-13

Applicant: Hyeung-Jin Lee ,  Joo-Yong Park ,  Chang-Soon Lee

Inventor： Hyeung-Jin Lee ,  Joo-Yong Park ,  Chang-Soon Lee

IPC: G03G9/093

CPC classification number: G03G9/081 ,  G03G9/0819 ,  G03G9/0825 ,  G03G9/08708 ,  G03G9/08711 ,  G03G9/09314 ,  G03G9/09321 ,  G03G9/09335 ,  G03G9/09342 ,  G03G9/09364 ,  G03G9/09378 ,  G03G9/09708 ,  G03G9/09716 ,  G03G9/09725 ,  G03G9/09783 ,  G03G9/09791

Abstract: The present invention relates to a non-magnetic mono-component toner comprising a toner mother particle, and a coating layer formed on the mother particle where the coating layer comprises fatty acid metal salt having average particle size of 0.05 to 3.0 μm, a first organic particle having average particle size of 0.3 to 2.0 μm, a second organic particle having average particle size of 0.05 to 0.25 μm, and silica having average particle size of 0.006 to 0.04 μm. The color toner has narrow charge distribution, high chargeability, a low environmental dependence, and excellent image quality, transfer efficiency, and long-term stability by significantly reducing the contamination of the charging elements.

Abstract translation: 本发明涉及一种非磁性单组分调色剂，其包含调色剂母体颗粒和形成在母体颗粒上的涂层，其中涂层包含平均粒度为0.05至3.0μm的脂肪酸金属盐，第一有机 平均粒径为0.3〜2.0μm的粒子，平均粒径为0.05〜0.25μm的第二有机粒子，平均粒径为0.006〜0.04μm的二氧化硅。 通过显着减少充电元件的污染，彩色调色剂具有窄的电荷分布，高充电性，低的环境依赖性，以及优异的图像质量，转印效率和长期的稳定性。

公开(公告)号：US20060105260A1

公开(公告)日：2006-05-18

申请号：US10505914

申请日：2004-01-12

Applicant: Won-Sup Lee ,  Chang-Soon Lee ,  Hyea-Eun Han ,  Kwang-Ho Song

Inventor： Won-Sup Lee ,  Chang-Soon Lee ,  Hyea-Eun Han ,  Kwang-Ho Song

IPC: G03G9/087

CPC classification number: G03G9/08735 ,  G03G9/081 ,  G03G9/0812 ,  G03G9/08704 ,  G03G9/08755 ,  G03G9/08779 ,  G03G9/08782 ,  G03G9/08791 ,  G03G9/08797 ,  G03G9/09716 ,  G03G9/09725 ,  G03G9/09766

Abstract: The present invention relates to a non-magnetic mono-component toner composition, which comprises a) a non-magnetic toner particle comprising a binding resin comprising a binder resin and a copolymer of a cyclic olefin and an acyclic olefin polymerized in the presence of a metallocene catalyst and a cocatalyst, a colorant, and a charge-control agent; b) fine powder of an organic compound containing fluorine that is added to the surface of the non-magnetic toner particle; and c) hydrophobic silica having a specific surface area of 100 to 240 m2/g. The toner composition of the present invention has superior transfer efficiency and charging properties and thus can obtain a stable image, does not show deteriorated image density, and does not generate background contamination of non-image areas and off-set due to deterioration of fixing properties, even if copying or printing is conducted therewith for a long time use.

Abstract translation: 非磁性单组分调色剂组合物本发明涉及一种非磁性单组分调色剂组合物，其包含：a）非磁性调色剂颗粒，其包含粘合树脂，所述粘合树脂包含粘合剂树脂和环烯烃与无环烯烃的共聚物， 茂金属催化剂和助催化剂，着色剂和电荷控制剂; b）加入到非磁性调色剂颗粒表面的含氟有机化合物的细粉末; 和c）比表面积为100至240m 2 / g的疏水性二氧化硅。 本发明的调色剂组合物具有优异的转印效率和充电性能，因此可以获得稳定的图像，不会显示劣化的图像浓度，并且不产生非图像区域的背景污染和由于定影特性的劣化而偏移 即使长时间使用复印或打印也是如此。

公开(公告)号：US20050175917A1

公开(公告)日：2005-08-11

申请号：US11049938

申请日：2005-02-04

Applicant: Won-Sup Lee ,  Chang-Soon Lee ,  Joo-Yong Park ,  Hyeung-Jin Lee

Inventor： Won-Sup Lee ,  Chang-Soon Lee ,  Joo-Yong Park ,  Hyeung-Jin Lee

IPC: G03G9/083 ,  G03G9/087 ,  G03G9/097

CPC classification number: G03G9/08711 ,  G03G9/08728 ,  G03G9/097 ,  G03G9/09708 ,  G03G9/09725

Abstract: The present invention relates to a magnetic mono-component toner composition with positive charge comprising i) a magnetic toner particle containing a charge control agent with positive charge; ii) a hydrophobic silica with negative charge; iii) a fluorinated organic fine powder; and iv) a metal oxide fine powder containing 20 to 80 wt % of tin oxide. The toner has an advantageous in the extended life of the drum, reduction of the background contamination, and improvement of long-term reliability, and thus can be used effectively for image forming apparatus.

Abstract translation: 本发明涉及具有正电荷的磁性单组分调色剂组合物，其包含i）含有带正电荷的电荷控制剂的磁性调色剂颗粒; ii）具有负电荷的疏水性二氧化硅; iii）氟化有机细粉; 和iv）含有20〜80重量％的氧化锡的金属氧化物细粉末。 调色剂在滚筒的使用寿命延长，背景污染减少，长期可靠性的提高方面具有优势，因此可有效地用于图像形成装置。