公开(公告)号：US08859788B2

公开(公告)日：2014-10-14

申请号：US13530789

申请日：2012-06-22

Applicant: Lee Reynolds Partin ,  Ashfaq Shaikh ,  Mesfin Ejerssa Janka ,  Kenny Randolph Parker

Inventor： Lee Reynolds Partin ,  Ashfaq Shaikh ,  Mesfin Ejerssa Janka ,  Kenny Randolph Parker

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: A process for the manufacture of dialkyl furan-2,5-dicarboxylate (DAFD) vapor composition by feeding furan-2,5-dicarboxylic acid (“FDCA”) to an esterification reactor and in the presence of an alcohol compound such as methanol, conducting an esterification reaction to form an esterification vapor containing DAFD, unreacted alcohol compound, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and water, and continuously passing the esterification vapor through an ACFC condensing zone, that can be integral with the esterification reactor, in which at least a portion of the ACFC in the esterification vapor is converted to a liquid phase condensate, and continuously discharging the esterification vapor from the ACFC condensing zone as a DAFD vapor. There is also a DAFD vapor composition containing DAFD, water, unreacted alcohol, and by-products.

Abstract translation: 通过将呋喃-2,5-二羧酸（“FDCA”）加入到酯化反应器中并在醇化合物例如甲醇存在下制备呋喃-2,5-二羧酸二烷基酯（DAFD）蒸气组合物的方法， 进行酯化反应以形成含有DAFD，未反应的醇化合物，5-（烷氧羰基）呋喃-2-羧酸（ACFC）和水的酯化蒸气，并连续使酯化蒸气通过ACFC冷凝区，其可以是积分的 酯化反应器中，将酯化蒸气中的至少一部分ACFC转化为液相冷凝物，并且将作为DAFD蒸气的来自ACFC冷凝区的酯化蒸气连续排出。 还有一种含有DAFD，水，未反应的醇和副产物的DAFD蒸汽组合物。

公开(公告)号：US08685334B2

公开(公告)日：2014-04-01

申请号：US13025682

申请日：2011-02-11

Applicant: Alan George Wonders ,  Puneet Gupta ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

Inventor： Alan George Wonders ,  Puneet Gupta ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

IPC: B01J19/24

CPC classification number: B01J8/003 ,  B01J8/1818 ,  B01J8/1872 ,  B01J8/22 ,  B01J8/222 ,  B01J2208/003 ,  B01J2208/00761 ,  B01J2208/0084 ,  B01J2208/00867 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C51/487 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

Abstract translation: 公开了一种用于更有效和经济地进行可氧化化合物的液相氧化的优化方法和装置。 这种液相氧化在气泡塔反应器中进行，其在相对低的温度下提供高效反应。 当氧化的化合物是对二甲苯并且来自氧化反应的产物是粗对苯二甲酸（CTA）时，可以通过更经济的技术将这种CTA产物纯化和分离，如果CTA通过常规的高温 氧化过程。

公开(公告)号：US08470257B2

公开(公告)日：2013-06-25

申请号：US12362815

申请日：2009-01-30

Applicant: Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel deVreede ,  Puneet Gupta

Inventor： Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel deVreede ,  Puneet Gupta

IPC: B01J19/24

CPC classification number: B01J8/222 ,  B01J4/002 ,  B01J8/1818 ,  B01J8/1872 ,  B01J19/006 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

公开(公告)号：US20120302773A1

公开(公告)日：2012-11-29

申请号：US13228816

申请日：2011-09-09

Applicant: Mesfin Ejerssa Janka ,  David Milton Lange ,  Michael C. Morrow ,  Bradford Russell Bowers ,  Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Partin ,  Charles Edwan Sumner, JR.

Inventor： Mesfin Ejerssa Janka ,  David Milton Lange ,  Michael C. Morrow ,  Bradford Russell Bowers ,  Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Partin ,  Charles Edwan Sumner, JR.

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US20120302768A1

公开(公告)日：2012-11-29

申请号：US13228797

申请日：2011-09-09

Applicant: Mesfin Ejerssa Janka ,  David Milton Lange ,  Michael C. Morrow ,  Bradford Russell Bowers ,  Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Partin ,  Jason Christopher Jenkins ,  Paula Moody ,  Thomas Elbert Shanks ,  Charles Edwan Sumner, JR.

Inventor： Mesfin Ejerssa Janka ,  David Milton Lange ,  Michael C. Morrow ,  Bradford Russell Bowers ,  Kenny Randolph Parker ,  Ashfaq Shaikh ,  Lee Reynolds Partin ,  Jason Christopher Jenkins ,  Paula Moody ,  Thomas Elbert Shanks ,  Charles Edwan Sumner, JR.

IPC: C07D307/68

CPC classification number: C07D307/68

Abstract: Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

公开(公告)号：US07977505B2

公开(公告)日：2011-07-12

申请号：US12105389

申请日：2008-04-18

Applicant: Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede ,  Puneet Gupta

Inventor： Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede ,  Puneet Gupta

IPC: C07C51/16

CPC classification number: B01J8/22 ,  B01J4/002 ,  B01J8/1818 ,  B01J8/1872 ,  B01J8/222 ,  B01J2208/00079 ,  B01J2208/003 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

公开(公告)号：US07910769B2

公开(公告)日：2011-03-22

申请号：US11153994

申请日：2005-06-16

Applicant: Alan George Wonders ,  Puneet Gupta ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

Inventor： Alan George Wonders ,  Puneet Gupta ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

IPC: C07C51/16

CPC classification number: B01J8/003 ,  B01J8/1818 ,  B01J8/1872 ,  B01J8/22 ,  B01J8/222 ,  B01J2208/003 ,  B01J2208/00761 ,  B01J2208/0084 ,  B01J2208/00867 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C51/487 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

Abstract translation: 公开了一种用于更有效和经济地进行可氧化化合物的液相氧化的优化方法和装置。 这种液相氧化在气泡塔反应器中进行，其在相对低的温度下提供高效反应。 当氧化的化合物是对二甲苯并且来自氧化反应的产物是粗对苯二甲酸（CTA）时，可以通过更经济的技术将这种CTA产物纯化和分离，如果CTA通过常规的高温 氧化过程。

公开(公告)号：US20090257930A1

公开(公告)日：2009-10-15

申请号：US12490442

申请日：2009-06-24

Applicant: Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

Inventor： Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel de Vreede

IPC: B01J19/24

CPC classification number: B01J8/22 ,  B01J4/002 ,  B01J8/1818 ,  B01J8/1872 ,  B01J8/222 ,  B01J8/226 ,  B01J19/006 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/16 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

公开(公告)号：US07563926B2

公开(公告)日：2009-07-21

申请号：US11154220

申请日：2005-06-16

Applicant: Marcel de Vreede ,  Lee Reynolds Partin ,  Wayne Scott Strasser

Inventor： Marcel de Vreede ,  Lee Reynolds Partin ,  Wayne Scott Strasser

IPC: C07C51/16

CPC classification number: B01J8/222 ,  B01J4/002 ,  B01J8/1818 ,  B01J8/1872 ,  B01J8/22 ,  B01J2208/00079 ,  B01J2208/003 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

公开(公告)号：US20090136398A1

公开(公告)日：2009-05-28

申请号：US12362815

申请日：2009-01-30

Applicant: Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel deVreede ,  Puneet Gupta

Inventor： Alan George Wonders ,  Lee Reynolds Partin ,  Wayne Scott Strasser ,  Marcel deVreede ,  Puneet Gupta

IPC: B01J19/00

CPC classification number: B01J8/222 ,  B01J4/002 ,  B01J8/1818 ,  B01J8/1872 ,  B01J19/006 ,  B01J2219/00006 ,  B01J2219/0004 ,  C07C51/265 ,  C07C63/26

Abstract: Disclosed is an optimized process and apparatus for more efficiently and economically carrying out the liquid-phase oxidation of an oxidizable compound. Such liquid-phase oxidation is carried out in a bubble column reactor that provides for a highly efficient reaction at relatively low temperatures. When the oxidized compound is para-xylene and the product from the oxidation reaction is crude terephthalic acid (CTA), such CTA product can be purified and separated by more economical techniques than could be employed if the CTA were formed by a conventional high-temperature oxidation process.

Abstract translation: 公开了一种用于更有效和经济地进行可氧化化合物的液相氧化的优化方法和装置。 这种液相氧化在气泡塔反应器中进行，其在相对低的温度下提供高效反应。 当氧化的化合物是对二甲苯并且来自氧化反应的产物是粗对苯二甲酸（CTA）时，可以通过更经济的技术将这种CTA产物纯化和分离，如果CTA通过常规的高温 氧化过程。