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67 条记录 (耗时 0.051 秒)

    Process for producing high diblock content block copolymer compositions
    42.
    发明授权
    Process for producing high diblock content block copolymer compositions 失效
    制备高二嵌段含量嵌段共聚物组合物的方法

    公开(公告)号：US5420203A

    公开(公告)日：1995-05-30

    申请号：US245097

    申请日：1994-05-17

    申请人： Steven H. Dillman ,  David J. St. Clair ,  Mark A. Berggren ,  Michael J. Modic

    发明人： Steven H. Dillman ,  David J. St. Clair ,  Mark A. Berggren ,  Michael J. Modic

    IPC分类号： C08F297/04 ,  C09J153/02 ,  C08L53/02

    CPC分类号： C08F297/044 ,  C09J153/02

    摘要： The present invention is a process for producing high diblock content block copolymer compositions which comprises (a) anionically polymerizing at least one vinyl aromatic hydrocarbon and at least one conjugated diene to form a living block copolymer, (b) coupling the block copolymer with a coupling agent selected from the group consisting of esters of carboxylic acids and asymmetric silanes to create a coupled polymer, (c) combining the coupled polymer with other components to form an enduse composition, and (d) heating the composition at a temperature up to 130.degree. C. for a time sufficient to decouple the coupled copolymer such that the amount of uncoupled copolymer in the composition ranges from 10 to 100% by weight of the total amount of block copolymer.

    摘要翻译： 本发明是一种制备高二嵌段含量嵌段共聚物组合物的方法，其包括（a）阴离子聚合至少一种乙烯基芳族烃和至少一种共轭二烯以形成活性嵌段共聚物，（b）将嵌段共聚物与偶联剂 选自羧酸和不对称硅烷的酯的试剂以产生偶联的聚合物，（c）将偶联的聚合物与其它组分组合以形成末端组合物，和（d）在高达130℃的温度下加热组合物 C.足够的时间使得偶联的共聚物分离，使得组合物中非偶联共聚物的量为嵌段共聚物总量的10-100重量％。

    Epoxy resin coating with COOH-grated hydrogenated block copolymer
    45.
    发明授权
    Epoxy resin coating with COOH-grated hydrogenated block copolymer 失效
    环氧树脂涂层用COOH-格化氢化嵌段共聚物

    公开(公告)号：US5342885A

    公开(公告)日：1994-08-30

    申请号：US448189

    申请日：1989-12-08

    申请人： David J. St. Clair

    发明人： David J. St. Clair

    IPC分类号： C08L63/00 ,  C08L33/14 ,  C08L63/02 ,  C08L63/04

    CPC分类号： C08L63/00

    摘要： A coating composition is provided from about 0.5 to about 80 parts by weight of a modified selectively hydrogenated block copolymer comprising at least one block of predominantly vinyl arene monomer units and at least one block which is, before hydrogenation, predominantly conjugated diolefin monomer units, the modified block copolymers having been modified by grafting predominantly to the conjugated diolefin block a carboxylic acid or acid derivative and 100 parts by weight of an epoxy resin. The blend of the modified block copolymer and epoxy resin is heated to above 150.degree. C. for a time sufficient for the carboxylic acid or acid derivative to form an adduct with the epoxy resin. The modified block copolymer forms a stable suspension in the epoxy after the adduct is formed which greatly enhances storage stability.

    摘要翻译： 提供了约0.5至约80重量份的修饰的选择性氢化嵌段共聚物，其包含至少一个主要为乙烯基芳烃单体单元的嵌段和至少一个在氢化之前为主要共轭二烯烃单体单元的嵌段， 改性嵌段共聚物已经通过主要接枝到共轭二烯嵌段羧酸或酸衍生物和100重量份的环氧树脂上进行了改性。 将改性嵌段共聚物和环氧树脂的共混物加热至150℃以上足以使羧酸或酸衍生物与环氧树脂形成加合物的时间。 改性嵌段共聚物在形成加合物之后在环氧树脂中形成稳定的悬浮液，这大大提高了储存稳定性。

    Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II)
    46.
    发明授权
    Hydroxyl functional derivatives of epoxidized diene block copolymers and process for making them (II) 失效
    环氧二烯嵌段共聚物的羟基官能衍生物及其制备方法（II）

    公开(公告)号：US5300586A

    公开(公告)日：1994-04-05

    申请号：US863648

    申请日：1992-04-03

    申请人： Robert C. Bening ,  James R. Erickson ,  David J. St. Clair ,  Carma J. Gibler ,  Joe J. Flores

    发明人： Robert C. Bening ,  James R. Erickson ,  David J. St. Clair ,  Carma J. Gibler ,  Joe J. Flores

    IPC分类号： C08C19/40 ,  C08F8/00 ,  C08G18/62 ,  C09D175/04

    CPC分类号： C09D175/04 ,  C08C19/40 ,  C08F8/00 ,  C08F8/04 ,  C08F8/12 ,  C08F8/32 ,  C08G18/6208 ,  C08F2810/20

    摘要： A process for making polymers of conjugated dienes which contain hydroxyl groups in the diene blocks which comprises(a) making a precursor polymer by polymerizing at least one conjugated diene which leaves 1,2 disubstituted, 1,1 disubstituted, 1,1,2 trisubstituted or tetrasubstituted olefinic unsaturation in the polymer,(b) optionally partially hydrogenating said precursor polymer,(c) epoxidizing said precursor polymer such that epoxy groups form at said substituted sites and the amount of epoxy functionality in the polymer is from 0.1 to 5 Meq/g polymer, and(d) reacting the epoxidized polymer with an alcohol solution of hydrochloric acid.A diene polymer containing 0.1 to 10 Meq/g polymer of hydroxyl group and comprised of alcohol units of the formula ##STR1## where R.sub.1 and R.sub.2 are hydrogen or alkyl radicals and X and X' are either --OH or --Cl and at least one of them is --OH.

    摘要翻译： 一种在二烯嵌段中含有羟基的共轭二烯的聚合物的方法，其包括（a）通过聚合至少一种共轭二烯制备前体聚合物，所述共轭二烯离开1,2-二取代的1,1,1-二取代的1,1,2三取代 或聚合物中的四取代的烯属不饱和键，（b）任选地部分氢化所述前体聚合物，（c）使所述前体聚合物环氧化，使得环氧基在所述取代部位形成，聚合物中环氧官能度的量为0.1-5Meq / g聚合物，和（d）使环氧化聚合物与盐酸的醇溶液反应。 含有0.1〜10Meq / g羟基的二烯聚合物，由式（* CHEMICAL STRUCTURE *）的醇单元组成，其中R1和R2为氢或烷基，X和X'为-OH或-Cl， 其中至少一个是-OH。

    Encapsulated solar cell assemblage and method of making
    49.
    发明授权
    Encapsulated solar cell assemblage and method of making 失效
    封装太阳能电池组合及制作方法

    公开(公告)号：US4692557A

    公开(公告)日：1987-09-08

    申请号：US919918

    申请日：1986-10-16

    申请人： Gay M. Samuelson ,  David J. St. Clair

    发明人： Gay M. Samuelson ,  David J. St. Clair

    IPC分类号： H01L31/048 ,  H01L25/02 ,  H01L21/56 ,  H01L31/18

    CPC分类号： B32B17/10761 ,  B32B17/10678 ,  B32B17/10788 ,  H01L31/048 ,  Y02E10/50 ,  Y10T156/1092

    摘要： A solar cell assemblage and method of making, comprising:(a) a pre-treated silanized transparent substrate;(b) a layer of semiconductor material;(c) an electrical contact on the surface of said layer of semiconductor material;(d) an extruded transparent film encapsulating the assemblage which comprises 75 to 91 parts by weight of a blend of:65 to 75 parts by weight of a selectively hydrogenated two-block polymer wherein(1) each A is a polymer block of a monovinyl or alpha alkyl monovinyl arene and the A blocks are from 10 to 40% by weight of the total block copolymer, and(2) each B is a polymer block formed by polymerizing a conjugated diene, and the B blocks are 90 to 60% weight of the total block copolymer, and25 to 35 parts by weight of a selectively hydrogenated multiblock copolymer wherein:(1) each A is a polymer endblock of a monovinyl or alpha alkyl monovinyl arene and the A blocks are 10 to 40% by weight of the total block copolymer, and(2) each B is a polymer midblock is formed by polymerizing a conjugated diene and the B blocks are 90 to 10% weight of the total block copolymer,about 8.5 to about 23.5 parts by weight of an (alpha) methyl styrene polymer tackifying resin; andabout 0.5 to about 1.5 parts by weight of a mixture of a phenolic antioxidant, a UV absorber with benzotriazole functionality and a UV absorber with hindered amine functionality;(e) a carbon filled polymer frame; and(f) sealant.

    摘要翻译： 一种太阳能电池组件及其制造方法，包括：（a）预处理的硅烷化透明基板; （b）半导体材料层; （c）在所述半导体材料层的表面上的电接触; （d）封装组合物的挤出透明膜，其包含75至91重量份的以65至75重量份的选择性氢化的二嵌段聚合物的共混物，其中（A）每个A是单乙烯基的聚合物嵌段 或α-烷基单乙烯基芳烃，并且A嵌段占总嵌段共聚物的10〜40重量％，（2）各B是通过使共轭二烯聚合而形成的聚合物嵌段，B嵌段为90〜60重量％ 的总嵌段共聚物和25至35重量份的选择性氢化的多嵌段共聚物，其中：（1）每个A是单乙烯基或α-烷基单乙烯基芳烃的聚合物端嵌段，并且A嵌段是10至40重量％ 总嵌段共聚物和（2）每个B是聚合物中间嵌段通过聚合共轭二烯而形成，并且B嵌段是总嵌段共聚物的90至1​​0重量％，约8.5至约23.5重量份的（α ）甲基苯乙烯聚合物增粘树脂; 和约0.5至约1.5重量份的酚类抗氧化剂，具有苯并三唑官能团的UV吸收剂和具有受阻胺官能团的UV吸收剂的混合物; （e）碳填充聚合物框架; 和（f）密封剂。

    Sealant
    50.
    发明授权
    Sealant 失效
    密封剂

    公开(公告)号：US3984369A

    公开(公告)日：1976-10-05

    申请号：US577578

    申请日：1975-05-15

    申请人： James T. Harlan, Jr. ,  David J. St. Clair

    发明人： James T. Harlan, Jr. ,  David J. St. Clair

    IPC分类号： C09J153/02 ,  C09K3/10 ,  C08K5/01 ,  C08K5/07 ,  C08K5/11

    CPC分类号： C09K3/10 ,  C09J153/025 ,  C09K2200/0239 ,  C09K2200/06 ,  C09K2200/061 ,  C09K2200/0642

    摘要： Sealant compositions exhibiting good substrate/sealant adhesion comprise 3 to 30 percent by weight of a block copolymer, 2 to 40 percent by weight butyl rubber, 10 to 70 percent by weight of a plasticizing oil having a solubility parameter ranging from 6 to 8, about 1 to about 50 percent by weight of an adhesion promoting resin having a solubility parameter ranging from about 8 to about 12, about 1 to about 70 percent by weight of an inorganic filler and about 0.01 to about 2.0 percent by weight of a UV/oxidation stabilizer or a mixture of UV/oxidation stabilizers.

    摘要翻译： 表现出良好的基质/密封剂粘合剂的密封剂组合物包含3至30重量％的嵌段共聚物，2至40重量％的丁基橡胶，10至70重量％的溶解度参数范围为6至8的增塑油，约 1至约50重量％的粘合促进树脂，其溶解度参数为约8至约12，约1至约70重量％的无机填料和约0.01至约2.0重量％的UV /氧化 稳定剂或UV /氧化稳定剂的混合物。