公开(公告)号：US07608140B2

公开(公告)日：2009-10-27

申请号：US12031766

申请日：2008-02-15

申请人： Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

发明人： Steven G. Link ,  Joan C. Potenza ,  Paul A. Loncle ,  Donald R. Diehl ,  Shari L. Eiff

IPC分类号： C09D11/02 ,  B41J2/01

CPC分类号： C09D11/32

摘要： The present invention relates to an aqueous ink comprising at least water, and a colorant of Formula 1 wherein A is any substituted or unsubstituted aromatic or heteroaromatic moiety; R is hydrogen or any non-metallic group; R1 is hydrogen, or any substituted or unsubstituted aryl, alkenyl, alkynyl or alkyl group; R2 and R3 are hydrogen or any non-metallic group, and R2 and R3 can be joined to form a ring that may be aromatic, aliphatic or heterocyclic and may be further substituted; or a colorant of Formula 2: wherein R4 is hydrogen or any non-metallic group; n is an integer of 0-4; and, if n is 2-4, the R4 groups may be the same or different from each other, and a printing method for creating an image on an ink compatible substrate using colorants of Formula 1 or Formula 2.

摘要翻译： 本发明涉及至少包含水的水性油墨和式1的着色剂，其中A是任何取代或未取代的芳族或杂芳族部分; R是氢或任何非金属基团; R 1是氢或任何取代或未取代的芳基，烯基，炔基或烷基; R 2和R 3是氢或任何非金属基团，并且R 2和R 3可以连接形成可以是芳族，脂族或杂环并且可以被进一步取代的环; 或式2的着色剂：其中R 4是氢或任何非金属基团; n是0-4的整数; 如果n为2-4，则R4基彼此可以相同或不同，以及使用式1或式2的着色剂在油墨兼容基板上产生图像的印刷方法。

公开(公告)号：US20080125331A1

公开(公告)日：2008-05-29

申请号：US11945484

申请日：2007-11-27

申请人： Krishnan Chari ,  Tiecheng A. Qiao ,  Donald R. Diehl ,  Samuel Chen ,  Kevin W. Williams ,  David A. Stegman

发明人： Krishnan Chari ,  Tiecheng A. Qiao ,  Donald R. Diehl ,  Samuel Chen ,  Kevin W. Williams ,  David A. Stegman

IPC分类号： C40B40/16 ,  C12Q1/68

CPC分类号： C09B45/48 ,  B01J2219/00497 ,  B01J2219/00527 ,  B01J2219/00576 ,  B01J2219/00648 ,  B01J2219/00677 ,  B01J2219/00722 ,  B01J2219/00725 ,  B01J2219/00729 ,  C08K5/0091 ,  C08K5/22 ,  C08K5/3437 ,  C08K9/10 ,  C08L25/06 ,  C09B67/0097 ,  C09D7/41 ,  C09D7/69 ,  C09D7/70

摘要： A coating composition for making a protein microarray, the composition comprising a gelling agent or a precursor to a gelling agent, and microspheres; the microspheres containing a dye represented by the Formula (1): wherein: R1=one or more substitutent selected from the group of H, chloro, alkoxycarbonyl, arylsulfamoyl, or alkylsulfamoyl; R2=one or more substituent selected from the group of H, carboxamido, or alkoxycarbonyl; R3=one or more substituent selected from the group of H, chloro, substituted or unsubstituted alkyl, aryl, carboxamido, or alkoxycarbonyl.

摘要翻译： 一种用于制备蛋白质微阵列的组合物，所述组合物包含胶凝剂或胶凝剂的前体，和微球; 含有由式（1）表示的染料的微球体：其中：R1 =选自H，氯，烷氧基羰基，芳基氨磺酰基或烷基氨磺酰基的一种或多种取代基; R2 =选自H，甲酰氨基或烷氧基羰基的一个或多个取代基; R3 =一个或多个选自H，氯，取代或未取代的烷基，芳基，甲酰胺基或烷氧基羰基的取代基。

公开(公告)号：US07312012B1

公开(公告)日：2007-12-25

申请号：US11610582

申请日：2006-12-14

申请人： Donald R. Diehl ,  Shari L. Eiff ,  Ramanuj Goswami ,  Christine J. Landry-Coltrain ,  Gary M. Russo

发明人： Donald R. Diehl ,  Shari L. Eiff ,  Ramanuj Goswami ,  Christine J. Landry-Coltrain ,  Gary M. Russo

IPC分类号： G03F7/34 ,  G03C8/10 ,  C09B67/00 ,  B41M5/20

CPC分类号： B41M5/392 ,  B41M5/385 ,  B41M5/3852 ,  B41M5/3854 ,  B41M5/3858 ,  B41M5/388 ,  B41M5/39 ,  B41M5/395 ,  C09B67/0033 ,  C09B67/0034 ,  C09B67/0051

摘要： The present invention relates to a thermal donor comprising a dye mixture and a urea light-stabilizing compound, wherein the light-stabilizing compound is represented by structure I: wherein: R1, R2 and R3 represent a hydrogen atom, alkyl group, cycloalkyl group, alkenyl group, aralkyl group, aryl group or heterocyclic group, provided that at least one of R1, R2, and/or R3 is a hydrogen atom; R4-R8 represent a hydrogen atom, hydroxyl group, alkyl group, cycloalkyl group, alkenyl group, aralkyl group, aryl group, heterocyclic group, aryloxy group, or alkoxy group; and R3 forms a heterocyclic ring with either R4 or R8, and an imaging system comprising a donor sheet having a layer containing a dye and an image receiving sheet having a dye receiving layer, wherein either the donor sheet or the image receiving sheet comprises a dye mixture and a urea light-stabilizing compound of structure I.

摘要翻译： 本发明涉及一种包含染料混合物和尿素光稳定化合物的热供体，其中光稳定化合物由结构I表示：其中：R 1，R 2， R 3和R 3表示氢原子，烷基，环烷基，烯基，芳烷基，芳基或杂环基，条件是R 1〜/ >，R 2和/或R 3是氢原子; R 4 -R 8表示氢原子，羟基，烷基，环烷基，烯基，芳烷基，芳基，杂环基，芳氧基或烷氧基 组; R 3和R 3形成具有R 4或R 8的杂环，并且成像系统包括具有含有染料的层的供体片 以及具有染料接收层的图像接收片，其中供体片或图像接收片包括染料混合物和结构I的脲稳定化合物。

公开(公告)号：US06521397B1

公开(公告)日：2003-02-18

申请号：US10122284

申请日：2002-04-12

申请人： Mbiya Kapiamba ,  Donald R. Diehl ,  James L. Edwards ,  David G. Lincoln ,  Gary M. Russo

发明人： Mbiya Kapiamba ,  Donald R. Diehl ,  James L. Edwards ,  David G. Lincoln ,  Gary M. Russo

IPC分类号： G03C146

CPC分类号： G03C7/381 ,  G03C7/3815 ,  G03C7/382

摘要： Disclosed is a photographic element comprising a support bearing a light sensitive silver halide emulsion layer having associated therewith a dye forming coupler having a formula I, wherein: Ballast is a group containing at least 6 aliphatic carbon atoms, V represents a chain of three or four atoms, which may be substituted, selected from C, N, O and S sufficient to form an aromatic ring fused to the azole ring and n is 0 or 1, provided that if n is 0, Y and Ballast are directly attached to the 5-membered azole ring, W is an electron withdrawing group selected from the group consisting of —CN, —CONR1R2, —CO2R1, —NO2, and —SO2R1 where R1 and R2 are H or substituents; X is H or a coupling-off group; Y is H or a substituent; Z is an atom or group selected from >N—R, —O—, and —S—.

摘要翻译： 公开了一种照相元件，其包括带有光敏卤化银乳剂层的载体，其具有式I的染料形成成色剂，其中：镇流器是含有至少6个脂族碳原子的基团，V表示三或四条链 原子，其可以被选自C，N，O和S，足以形成与唑环稠合的芳环，n为0或1，条件是如果n为0，则Y和镇流器直接连接到5 W是选自-CN，-CONR1R2，-CO2R1，-NO2和-SO2R1的吸电子基团，其中R 1和R 2是H或取代基; X是H或偶联离去基团 Y为H或取代基; Z为选自NR，-O-和-S-的原子或基团。

公开(公告)号：US5683860A

公开(公告)日：1997-11-04

申请号：US768544

申请日：1996-12-18

申请人： Donald R. Diehl ,  Linda J. Beattie ,  Gary N. Barber

发明人： Donald R. Diehl ,  Linda J. Beattie ,  Gary N. Barber

IPC分类号： G03C1/83 ,  G03C7/30 ,  G03C1/40

CPC分类号： G03C1/83 ,  G03C7/3041 ,  G03C7/3029

摘要： A silver halide light sensitive photographic element comprising a support bearing on one side thereof at least one light-sensitive silver halide emulsion layer, wherein the emulsion layer or a separate hydrophilic colloid layer of the element comprises a soluble absorber dye of the following formula (I): ##STR1## wherein each M is H or a counterion; each R.sup.1 and R.sup.2 independently represents H or a photographically acceptable substituent; m+p equals from 1 to 4; n+q equals from 1 to 4; and each of r and t represents from 0 to 3. In preferred embodiments of the invention, the element comprises at least one red-sensitive silver halide emulsion layer, and a dye of formula (I) is coated on the same side of the support as the red-sensitive emulsion layer. In particularly preferred embodiments, the element comprises a support bearing on the same side at least one blue-sensitive silver halide emulsion yellow-image forming layer, at least one red-sensitive silver halide emulsion cyan-image forming layer, at least one green-sensitive silver halide emulsion magenta-image forming layer, and a dye of the formula (I) is coated in at least one of the emulsion layers or a separate hydrophilic colloid layer on the same side of the support. Dyes of formula (I) typically provide substantial absorption at short red wavelengths below about 630 nm, and photographic elements in accordance with the invention accordingly exhibit effective safelight performance for commonly used safelights emitting in the range of 560-630 nm, such as those using a Kodak Safelight Filter No. 8.

摘要翻译： 一种卤化银感光照相材料，其包含一个支承体，该支撑体的一侧具有至少一个感光卤化银乳剂层，其中所述乳液层或所述元件的分开的亲水胶体层包含下式（I ）：其中每个M是H或抗衡离子; 每个R 1和R 2独立地表示H或照相可接受的取代基; m + p等于1至4; n + q等于1至4; 并且r和t中的每一个表示0至3.在本发明的优选实施方案中，元件包含至少一种感红卤化银乳剂层，并且将式（I）染料涂覆在载体的同一侧 作为感红乳剂层。 在特别优选的实施方案中，元件包括在同一侧上承载至少一种感蓝卤化银乳剂黄色图像形成层，至少一种感红卤化银乳剂青色图像形成层，至少一种绿 - 敏感的卤化银乳剂品红色图像形成层和式（I）的染料涂覆在载体的同一侧的至少一个乳剂层或单独的亲水胶体层中。 式（I）的染料通常在低于约630nm的短红色波长下提供实质吸收，因此根据本发明的照相元件相应地显示出在560-630nm范围内发射的常用安全灯的有效安全性能，例如使用 Kodak Safelight过滤器8号。

公开(公告)号：US5260179A

公开(公告)日：1993-11-09

申请号：US945804

申请日：1992-09-16

申请人： Donald R. Diehl ,  Margaret J. Helber ,  Hugh Williamson

发明人： Donald R. Diehl ,  Margaret J. Helber ,  Hugh Williamson

IPC分类号： C09B23/00 ,  C09B23/16 ,  C09B55/00 ,  G03C1/83 ,  G03C1/84

CPC分类号： G03C1/832 ,  C09B23/162

摘要： Imine dyes useful in photographic materials have the formula ##STR1## wherein D is selected from ##STR2## and wherein E.sup.1, E.sup.2, E.sup.3, and E.sup.4 each individually represents strongly electron-withdrawing groups; R.sup.1 and R.sup.6 each individually represents an alkyl group of 1 to about 8 carbon atoms, or an aralkyl or cycloalkyl group of 5 to about 10 carbon atoms, or an aryl group of 6 to about 14 carbon atoms; R.sup.2, R.sup.3, and R.sup.11 each individually represents an alkyl group of 1 to about 8 carbon atoms, or an alkenyl group of 2 to about 8 carbon atoms, or an aryl, aralkyl, or cycloalkyl group of 5 to about 14 carbon atoms; or R.sup.2 and R.sup.3 individually represent the non-metallic atoms necessary to form a 5- or 6-membered fused ring with the phenyl ring to which the nitrogen is attached, or together represent the non-metallic atoms required to form a 5- or 6-membered ring with each other; R.sup.4, R.sup.7, R.sup.8, R.sup.9, and R.sup.10 each individually represents hydrogen, or an alkyl , aralkyl, cycloalkyl, alkoxy, alkylamino, or alkylthio group of 1 to about 10 carbon atoms; R.sup.5 represents an alkyl group of 1 to about 8 carbon atoms, or an aralkyl or cycloalkyl group of 5 to about 10 carbon atoms; R.sup.12 represents cyano, or an aryl, aminocarbonyl, or alkoxycarbonyl group of 2 to about 8 carbon atoms, or an alkylsulfonyl, arylsulfonyl, or sulfamoyl group of 1 to about 8 carbon atoms; or R.sup.11 and R.sup.12 together represent the non-metallic atoms necessary to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic or unsaturated alicyclic nucleus; G represents O or C(CN).sub.2 ; Y and Z each individually represents the non-metallic atoms necessary to complete a substituted or unsubstituted ring system containing at least one 5- or 6-membered heterocyclic nucleus; M.sup.+ is a cation; L.sup.1 through L.sup.6 each individually represents unsubstituted or substituted methine groups; m is 0, 1, 2, or 3; n is 0 or 1; p is 0, 1, 2, 3, or 4; q is 0, 1, 2, or 3; and r is 0, 1, 2, 3, 4, or 5.Solid particle dispersions of dyes of formula (I) that contain at least one base-ionizable functional group such as carboxy, sulfonamido, or sulfamoyl are useful as filter dyes in photographic elements.

公开(公告)号：US5213956A

公开(公告)日：1993-05-25

申请号：US733929

申请日：1991-07-22

申请人： Donald R. Diehl ,  Glenn M. Brown ,  Margaret J. Helber

发明人： Donald R. Diehl ,  Glenn M. Brown ,  Margaret J. Helber

IPC分类号： C09B23/01 ,  C09B23/14 ,  G03C1/83

CPC分类号： G03C1/832 ,  C09B23/0008 ,  C09B23/0066 ,  C09B23/0091 ,  C09B23/14

摘要： Solid particle dispersions of dyes according to the formula: ##STR1## wherein D is selected from the group consisting of ##STR2## and ketomethylene nuclei are disclosed as filter dyes for photographic elements.In this formula, E.sup.1 and E.sup.2 are each independently electron withdrawing groups R.sup.1 and R.sup.6 are each independently R or NHR, where R is substituted or unsubstituted aryl. R.sup.2 and R.sup.3 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or represent the carbon atoms necessary to form a fused ring with the phenyl ring to which the N atom is attached. R.sup.4 and R.sup.7 are each independently hydrogen, substituted or unsubstituted alkyl or substituted or unsubstituted aryl. R.sup.5 is substituted or unsubstituted alkyl Z represents the atoms necessary to complete a substituted or unsubstituted 5 or 6 membered heterocyclic nucleus. M.sup.+ is a cation. L.sup.1 through L.sup.7 are each independently substituted or unsubstituted methine groups. m is 0, 1, 2, or 3. n is 0 or 1. p is 0, 1, 2, 3, or 4. q is 0, 1, 2, or 3. At least one of R.sup.1 or D includes an aryl ring substituted with a carboxy or sulfonamido substituent.

公开(公告)号：US5055387A

公开(公告)日：1991-10-08

申请号：US492147

申请日：1990-03-13

申请人： Donald R. Diehl ,  Michael C. Malec

发明人： Donald R. Diehl ,  Michael C. Malec

IPC分类号： C09B23/00 ,  C09B23/01 ,  G03C1/22

CPC分类号： C09B23/0091 ,  G03C1/22

摘要： Sensitizing dyes for photographic materials are disclosed. The dyes have the formula: ##STR1## R.sub.2 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl, andR.sub.1 and R.sub.3 are each independently substituted or unsubstituted alkyl, at least one of R.sub.1 and R.sub.3 having at least about 5 carbon atoms.

公开(公告)号：US4988611A

公开(公告)日：1991-01-29

申请号：US481850

申请日：1990-02-20

申请人： Richard B. Anderson ,  Ronda E. Factor ,  Anthony Adin ,  Donald R. Diehl

发明人： Richard B. Anderson ,  Ronda E. Factor ,  Anthony Adin ,  Donald R. Diehl

IPC分类号： G03C1/83

CPC分类号： G03C1/83

摘要： A photographic element is disclosed for handling under a first radiation source and imagewise exposure to a second radiation source having a solid particle dispersion filter dye layer that absorbs radiation emitted to which the element is sensitive emitted by the first source.

摘要翻译： 公开了用于在第一辐射源下进行处理的成像元件，并且成像地暴露于具有固体颗粒分散过滤染料层的第二辐射源，所述固体颗粒分散过滤器染料层吸收由第一源发射的元件敏感的辐射。

公开(公告)号：US4948718A

公开(公告)日：1990-08-14

申请号：US372142

申请日：1989-06-27

申请人： Ronda E. Factor ,  Donald R. Diehl

发明人： Ronda E. Factor ,  Donald R. Diehl

IPC分类号： C09B23/10 ,  G03C1/83

CPC分类号： G03C1/832 ,  C09B23/105 ,  C09B23/107

摘要： Solid particle dispersions of dyes according to the formula: ##STR1## are useful as filter dyes in photographic elements. In this formula, R.sub.1 and R.sub.2 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or together represent the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered ring.R.sub.3 and R.sub.4 each independently represents H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, CO.sub.2 H, or NHSO.sub.2 R.sub.6. R.sub.5 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, carboxylate, or substituted or unsubstituted acyl, R.sub.6 and R.sub.7 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, and n is 1 or 2. R.sub.8 is either substituted or unsubstituted alkyl, or is part of a double bond between the ring carbon atoms to which R.sub.1 and R.sub.2 are attached. At least one of the aryl rings of the dye molecule must have at least one substituent that is CO.sub.2 H or NHSO.sub.2 R.sub.6.

摘要翻译： 根据下式的染料的固体颗粒分散体：可用作照相元件中的滤光染料。 在该式中，R 1和R 2各自独立地为取代或未取代的烷基或取代或未取代的芳基，或一起代表完成取代或未取代的5元或6元环所必需的原子。 R 3和R 4各自独立地表示H，取代或未取代的烷基，取代或未取代的芳基，CO 2 H或NHSO 2 R 6。 R5是H，取代或未取代的烷基，取代或未取代的芳基，羧酸酯或取代或未取代的酰基，R6和R7各自独立地是取代或未取代的烷基或取代或未取代的芳基，n是1或2.R 8是被取代的或 或者是R 1和R 2所连接的环碳原子之间的双键的一部分。 染料分子的至少一个芳环必须具有至少一个为CO 2 H或NHSO 2 R 6的取代基。