Condensation polymers containing styrylbenzazole ultraviolet
radiation-absorbing residues and shaped articles produced therefrom
    43.
    发明授权
    Condensation polymers containing styrylbenzazole ultraviolet radiation-absorbing residues and shaped articles produced therefrom 失效
    含有苯乙烯基扎唑紫外线吸收残留物和由其制成的成型制品的缩合聚合物

    公开(公告)号:US4803241A

    公开(公告)日:1989-02-07

    申请号:US75374

    申请日:1987-07-20

    IPC分类号: C08K5/3447 C08K5/35 C08K5/46

    CPC分类号: C08K5/35 C08K5/3447 C08K5/46

    摘要: A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein the residue of one or a mixture of styrylbenzazole reactants of the formula: ##STR1## wherein A is the residue of a benzene ring of a benzoxazole, benzothiazole or benzionidazole radical; X is --O--, --S-- or --N(R.sup.2)--; Ph is a phenylene radical; and R.sup.1 is halogen or --Y--R.sup.2 in which Y is --O-- or --N(R.sup.2)-- and each R.sup.2 is hydrogen, alkenyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical.

    摘要翻译: 一种可用于模制成诸如食品容器,软饮料瓶,固化的结构塑料等的制品的组合物,其包含在其中反应或共聚合有级联的线性或不饱和聚酯或聚碳酸酯的组合物,其中所述式或其混合物中的一种或其混合物的苯乙烯基吲唑反应物 :其中A是苯并恶唑,苯并噻唑或苯并噻唑基的苯环的残基; X是-O - , - S-或-N(R 2) - ; Ph是亚苯基; 并且R 1是卤素或-Y-R 2,其中Y是-O-或-N(R 2) - ,每个R 2是氢,烯基或未取代或取代的烷基,环烷基或芳基。

    Condensation polymer containing the residue of a benzodioxylmethine
compound and shaped articles produced therefrom
    44.
    发明授权
    Condensation polymer containing the residue of a benzodioxylmethine compound and shaped articles produced therefrom 失效
    含有苯并二氧杂环己基化合物的残基的缩合聚合物和由其制备的成型制品

    公开(公告)号:US4791188A

    公开(公告)日:1988-12-13

    申请号:US135425

    申请日:1987-12-21

    摘要: Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturaged polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more benzodioxylmethine compounds having the formula: ##STR1## wherein R.sup.1 is cyano, carboxy, alkenyloxycarbonyl or an unsubstituted or substituted alkoxycarbonyl, cycloalkoxycarbonyl or aryloxycarbonyl radical;R.sup.2 is one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or heterocyclic aryl radical;R.sup.3 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;R.sup.4 is hydrogen, alkyl, alkoxy, or halogen;n is 1 or 2; andX is an unsubstituted or substituted methylene or ethylene radical; provided the benzodioxolylmethine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived, said benzodioxylmethine residue absorbing radiation in the range of about 250 nm to 390 nm and being nonextractable from said polymer and stable under polymer processing conditions.The benzodioxylmethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are nonextractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

    Lignin and lignin derivatives as copolymerizable colorants for polyesters
    46.
    发明授权
    Lignin and lignin derivatives as copolymerizable colorants for polyesters 失效
    木质素和木质素衍生物作为聚酯的共聚着色剂

    公开(公告)号:US4803255A

    公开(公告)日:1989-02-07

    申请号:US64646

    申请日:1987-06-22

    IPC分类号: C08G63/46 C08H5/02 C08G63/02

    CPC分类号: C08H6/00 C08G63/46

    摘要: Colored shapable polyesters having copolymerized therein lignin or lignin derivatives are prepared by condensing the lignin or lignin derivatives into the polyester backbone during the polymerization reaction. The lignin moieties are thermally stable at the polymer processing temperatures and are nonextractable from the polyester backbone. These colored, shapable polyesters are particularly suitable for use in food, beverage, pharmaceutical, or cosmetic container applications.

    摘要翻译: 在其中共聚有木质素或木质素衍生物的着色可成形聚酯通过在聚合反应期间将木质素或木质素衍生物缩合成聚酯主链来制备。 木质素部分在聚合物加工温度下是热稳定的,并且不能从聚酯骨架脱模。 这些有色成型聚酯特别适用于食品,饮料,药物或化妆品容器应用。

    Unsaturated polyesters colored with lignin
    47.
    发明授权
    Unsaturated polyesters colored with lignin 失效
    用木质素着色的不饱和聚酯

    公开(公告)号:US4771101A

    公开(公告)日:1988-09-13

    申请号:US64637

    申请日:1987-06-22

    IPC分类号: C08G63/52 C08H5/02

    CPC分类号: C08H6/00 C08G63/52

    摘要: Colored unsaturated polyesters having copolymerized therein lignin and lignin derivatives which condense during polymerization into the polyester chain are disclosed. The lignin moieties are thermally stable at the polymer processing temperature and are nonextractable from the polymer making these colored polyesters suitable for use in bathroom fixtures, boats, certain automotive applications and the like.

    摘要翻译: 公开了其中共聚有木质素和在聚合过程中聚合成聚酯链的木质素衍生物的着色不饱和聚酯。 木质素部分在聚合物加工温度下是热稳定的,并且不适于制备适合用于浴室装置,船,某些汽车应用等的着色聚酯的聚合物。

    Melamine group containing ultraviolet stabilizers and their use in
organic compositions III
    50.
    发明授权
    Melamine group containing ultraviolet stabilizers and their use in organic compositions III 失效
    含有紫外线稳定剂的三聚氰胺基团及其在有机组合物中的应用

    公开(公告)号:US4418001A

    公开(公告)日:1983-11-29

    申请号:US413902

    申请日:1982-09-01

    CPC分类号: C09K15/30 C08K5/34926

    摘要: The invention relates to melamine group containing compounds which have been found to be effective ultraviolet stabilizers. The invention also relates to ultraviolet degradable organic compositions containing an amount of a melamine group containing compounds to prevent such degradation. These stabilizers are effective in the presence of other additives commonly employed in polymeric compositions including, for example, pigments, colorants, fillers, reinforcing agents and the like. These ultraviolet stabilizers may be incorporated into the organic compositions such as polymers by adding to the polymer melt or dissolved in the polymer dope, coated on the exterior of the shaped or molded article, film or extruded fiber.

    摘要翻译: 本发明涉及已发现是有效的紫外线稳定剂的含三聚氰胺基团的化合物。 本发明还涉及含有一定量的含三聚氰胺基团的化合物以防止这种降解的紫外可降解有机组合物。 这些稳定剂在通常用于聚合物组合物中的其它添加剂的存在下是有效的,包括例如颜料,着色剂,填料,增强剂等。 这些紫外线稳定剂可以通过加入到聚合物熔体中或溶解在聚合物涂料中而被包被到有机组合物如聚合物中,涂覆在成形或模塑制品,膜或挤出纤维的外部上。