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    Lignin and lignin derivatives as copolymerizable colorants for polyesters
    1.
    发明授权
    Lignin and lignin derivatives as copolymerizable colorants for polyesters 失效
    木质素和木质素衍生物作为聚酯的共聚着色剂

    公开(公告)号：US4803255A

    公开(公告)日：1989-02-07

    申请号：US64646

    申请日：1987-06-22

    申请人： Wayne P. Pruett ,  John A. Hyatt ,  Samuel D. Hilbert

    发明人： Wayne P. Pruett ,  John A. Hyatt ,  Samuel D. Hilbert

    IPC分类号： C08G63/46 ,  C08H5/02 ,  C08G63/02

    CPC分类号： C08H6/00 ,  C08G63/46

    摘要： Colored shapable polyesters having copolymerized therein lignin or lignin derivatives are prepared by condensing the lignin or lignin derivatives into the polyester backbone during the polymerization reaction. The lignin moieties are thermally stable at the polymer processing temperatures and are nonextractable from the polyester backbone. These colored, shapable polyesters are particularly suitable for use in food, beverage, pharmaceutical, or cosmetic container applications.

    摘要翻译： 在其中共聚有木质素或木质素衍生物的着色可成形聚酯通过在聚合反应期间将木质素或木质素衍生物缩合成聚酯主链来制备。 木质素部分在聚合物加工温度下是热稳定的，并且不能从聚酯骨架脱模。 这些有色成型聚酯特别适用于食品，饮料，药物或化妆品容器应用。

    Unsaturated polyesters colored with lignin
    2.
    发明授权
    Unsaturated polyesters colored with lignin 失效
    用木质素着色的不饱和聚酯

    公开(公告)号：US4771101A

    公开(公告)日：1988-09-13

    申请号：US64637

    申请日：1987-06-22

    申请人： Wayne P. Pruett ,  John A. Hyatt ,  Samuel D. Hilbert

    发明人： Wayne P. Pruett ,  John A. Hyatt ,  Samuel D. Hilbert

    IPC分类号： C08G63/52 ,  C08H5/02

    CPC分类号： C08H6/00 ,  C08G63/52

    摘要： Colored unsaturated polyesters having copolymerized therein lignin and lignin derivatives which condense during polymerization into the polyester chain are disclosed. The lignin moieties are thermally stable at the polymer processing temperature and are nonextractable from the polymer making these colored polyesters suitable for use in bathroom fixtures, boats, certain automotive applications and the like.

    摘要翻译： 公开了其中共聚有木质素和在聚合过程中聚合成聚酯链的木质素衍生物的着色不饱和聚酯。 木质素部分在聚合物加工温度下是热稳定的，并且不适于制备适合用于浴室装置，船，某些汽车应用等的着色聚酯的聚合物。

    Methine compounds containing ester group
    7.
    发明授权
    Methine compounds containing ester group 失效
    含酯基的甲基化合物

    公开(公告)号：US5075491A

    公开(公告)日：1991-12-24

    申请号：US454108

    申请日：1989-12-20

    申请人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert

    发明人： Max A. Weaver ,  Wayne P. Pruett ,  Samuel D. Hilbert

    IPC分类号： C07C229/44 ,  C07C255/34 ,  C07C311/35 ,  C07C311/42 ,  C07C317/44 ,  C07C323/60 ,  C08G63/685 ,  C08G64/04 ,  C08K5/00 ,  C08K5/315

    CPC分类号： C07C255/34 ,  C07C229/44 ,  C07C311/35 ,  C07C311/42 ,  C07C317/44 ,  C07C323/60 ,  C08G63/6858 ,  C08G64/045 ,  C08K5/005 ,  C08K5/315

    摘要： A composition useful for incorporation into polymer compositions employed for food packaging or the like comprising a bis- or tris-methine compound having the structural formula ##STR1## wherein A is selected from the radicals ##STR2## wherein R' and R" are each selected from chlorine, bromine, fluorine, alkyl, alkoxy, aryl, aryloxy and arylthio;each n is independently 0, 1, 2;R.sub.1 is selected from a large variety of radicals such as cycloalkyl, phenyl, and straight or branched alkyl which may be substituted;R.sub.2 is alkylene or the like;R.sub.3, R.sub.4, and R.sub.5 are each selected from hydrogen and alkyl; andP and Q and P.sup.1 and Q.sup.1 are selected from cyano, carbalkoxy, carbaryloxy, carbaralkyloxy, or the like.

    摘要翻译： 可用于掺入用于食品包装等的聚合物组合物中的组合物，其包含具有结构式为“IMAGE”的双或三 - 次甲基化合物，其中A选自基团 其中R'和R“各自选自氯，溴，氟，烷基，烷氧基，芳基，芳氧基和芳硫基; 每个n独立地为0,1,2; R1选自各种基团，例如环烷基，苯基，可被取代的直链或支链烷基; R2是亚烷基等; R3，R4和R5各自选自氢和烷基; 并且P和Q以及P1和Q1选自氰基，烷氧基，碳酰氧基，卡巴尔基氧基等。

    Condensation polymer containing the residue of a poly-methine compound and shaped articles produced therefrom
    8.
    发明授权
    Condensation polymer containing the residue of a poly-methine compound and shaped articles produced therefrom 失效
    含有聚次甲基化合物的残基的聚合物和由其制备的成型制品

    公开(公告)号：US4749774A

    公开(公告)日：1988-06-07

    申请号：US78434

    申请日：1987-07-27

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    IPC分类号： C08F299/04 ,  C08F283/01 ,  C08G63/44 ,  C08G63/46 ,  C08G63/52 ,  C08G63/68 ,  C08G63/685 ,  C08G64/04 ,  C08L67/02 ,  C08G63/76 ,  C08G69/44

    CPC分类号： C07C255/00 ,  C08G63/52 ,  C08G63/6858 ,  C08G64/045

    摘要： Composition useful for molding into articles which as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate having reacted therewith or copolymerized therein the residue of one or more poly-methine compounds having the formula: ##STR1## wherein each R.sup.1 is independently selected from cyano, carboxy, alkenyloxycarbonyl, or a substituted or unsubstituted alkoxycarbonyl, cycloalkoxoycarbonyl or aryloxycarbonyl radical;each R.sup.2 is independently selected from one of the groups specified for R.sup.1 or an unsubstituted or substituted aryl, carbamoyl, alkanoyl, cycloalkanoyl, aroyl, alkylsulfonyl, cycloalkylsulfonyl, arylsulfonyl or aromatic, heterocyclic radical;each R.sup.3 is independently selected from hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical;A.sup.1 and A.sup.2 are independently selected from 1,4-phenylene radicals; andL is an organic linking group bonded by non-oxo carbon atoms to the oxygen atoms adjacent to L; provided the poly-methine compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The polymethine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.

    Polyesters having improved whiteness
    9.
    发明授权
    Polyesters having improved whiteness 失效
    聚酯具有改善的白度

    公开(公告)号：US4745174A

    公开(公告)日：1988-05-17

    申请号：US041512

    申请日：1987-04-23

    申请人： Wayne P. Pruett ,  Samuel D. Hilbert ,  John G. Thompson ,  Max A. Weaver

    发明人： Wayne P. Pruett ,  Samuel D. Hilbert ,  John G. Thompson ,  Max A. Weaver

    IPC分类号： C08L67/00 ,  C08G63/685 ,  C08K5/16 ,  C08K5/3437 ,  C08G69/44 ,  C08G73/16

    CPC分类号： C08G63/6856 ,  C08K5/3437

    摘要： This invention relates to novel fiber forming polyester compositions that exhibit improved whiteness by incorporating derivatives of dibenzoisoquinolinediones of the formula ##STR1## wherein R is hydrogen, cycloalkyl, allyl, alkyl, aralkyl, alkoxyalkyl or cycloalkylalkylene;R.sub.1 is hydrogen, halogen, alkyl, alkoxy, aryloxy, alkylthio or arylthio;R.sub.2 is hydrogen, halogen, alkyl, aryl, alkoxy, aryloxy, alkylthio, arylthio, carbalkoxy, carbaryloxy, carbaralkyloxy, carboxy, sulfamoyl, alkylsulfamoyl, dialkylsulfamoyl, alkylarylsulfamoyl, cycloalkylsulfamoyl, arylsulfamoyl, carbamoyl, alkylcarbamoyl, dialkylcarbamoyl, alkylarylcarbamoyl, cycloalkylcarbamoyl, arylcarbamoyl, 2-pyrrolidono, acylamido or N-alkylacylamido;R.sub.3 is one or more groups selected from the group consisting of hydrogen, halogen, alkyl, and alkoxy; andx is an integer of 1 to 5;wherein one or more alkyl, alkoxy, aryl, aryloxy, alkylthio, arylthio or aralkyl residues may contain one or more reactive groups selected from the group consisting of carboxy, carbalkoxy, carbaryloxy, N-alkyl-carbamoyloxy, carbamoyloxy, acyloxy, chlorocarbonyl, hydroxyl, cycloalkylcarbonyloxy, N-arylcarbamoyloxy, and N,N-dialkylcarbamoyloxy wherein said alkyl and aryl groups may also have common substituents such as alkoxy, acyloxy, cyano, halogen, hydroxy and acylamido.

    UV-absorbing condensation polymeric composition
    10.
    发明授权
    UV-absorbing condensation polymeric composition 失效
    紫外线吸收缩合聚合物组合物

    公开(公告)号：US4661566A

    公开(公告)日：1987-04-28

    申请号：US826645

    申请日：1986-02-06

    申请人： Wayne P. Pruett ,  Richard H. S. Wang ,  Samuel D. Hilbert ,  Max A. Weaver

    发明人： Wayne P. Pruett ,  Richard H. S. Wang ,  Samuel D. Hilbert ,  Max A. Weaver

    IPC分类号： C08L67/00 ,  C08G63/685 ,  C08G64/00 ,  C08K5/16 ,  C08K5/20 ,  C08K5/34 ,  C08K5/36 ,  C08K5/43 ,  C08K5/47 ,  C08L69/00 ,  C08G63/46 ,  C08G63/62

    CPC分类号： C08G64/00 ,  C08G63/685

    摘要： Compositions comprising polyester or polycarbonate having reacted therein a total of from about 1.0 to about 5,000 parts by weight per million parts by weight of polyester of at least one UV absorbing compound of the formula ##STR1## wherein R is alkyl or the like, X is carbonyl or sulfonyl, R.sup.1 is hydrogen or a substituent, and Y and Z are hydrogen or substituents such as cyano or alkoxycarbonyl, with the provision that at least one of R, R.sup.1, Y, and Z is, or forms part of, or contains one or more reactive groups capable of undergoing a condensation reaction under polyester forming conditions, such that the UV absorbing compound is reacted into the polymer. The compound has a maximum light absorbance within the range of from about 320 nm to about 380 nm, which is nonextractable from the polyester and stable under the polyester processing conditions, for imparting UV screening properties to the polymer. Many products such as fruit juices, soft drinks, wines, food products, cosmetics and shampoos are deleteriously affected by UV light when packaged in clear plastic containers which pass significant portions of the available light at any wavelength from approximately 250 to 390 nm. By use of the present compounds polymeric containers can be manufactured which absorb these harmful wavelengths and therefore reduce or eliminate the UV light degradation of products packaged therein. A further advantage of the present polymeric compositions is that conventional polyester dyes and other additives such as pigments, fillers, brighteners and the like may be incorporated therein, and the UV screening properties of the methine compounds impart significant stabilization to both the polyester and the dyes.

    摘要翻译： 包含聚酯或聚碳酸酯的组合物，其中总共具有约1.0至约5,000重量份/百万重量份的至少一种下式的UV吸收化合物的聚酯：其中R是烷基等，X是 羰基或磺酰基，R 1是氢或取代基，并且Y和Z是氢或取代基如氰基或烷氧基羰基，条件是R，R 1，Y和Z中的至少一个是或形成一部分或包含 一种或多种在聚酯形成条件下能够进行缩合反应的反应性基团，使得UV吸收化合物反应成聚合物。 该化合物的最大吸光度在约320nm至约380nm的范围内，其从聚酯是不可剥离的并且在聚酯加工条件下稳定，用于赋予聚合物UV屏蔽性能。 许多产品如果汁，软饮料，葡萄酒，食品，化妆品和洗发水在包装在透明塑料容器中时受到紫外线的有害影响，透明塑料容器将可见光的大部分通过大约250至390 nm的任何波长传播。 通过使用本发明化合物，可以制造吸收这些有害波长的聚合物容器，从而减少或消除包装在其中的产品的紫外光降解。 本发明的聚合物组合物的另一个优点是可以引入常规的聚酯染料和其它添加剂，例如颜料，填料，增白剂等，并且次甲基化合物的UV屏蔽性能赋予聚酯和染料两者显着的稳定性 。