公开(公告)号：US5208209A

公开(公告)日：1993-05-04

申请号：US810095

申请日：1991-12-19

申请人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

发明人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C07D493/10

CPC分类号： B41M5/3275 ,  B41M5/1455 ,  C07D493/10

摘要： Novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl group having from 1 to 4 carbon atoms, preparation process of the fluoran compounds, and a heat-sensitive and a pressure-sensitive recording material comprising the fluoran compound, are disclosed.

摘要翻译： 由式（I）表示的新型氟化合物：其中R1是具有1至4个碳原子的烷基，其中氟化合物的制备方法和热敏记录材料 包括荧烷化合物。

公开(公告)号：US5185453A

公开(公告)日：1993-02-09

申请号：US717568

申请日：1991-06-19

申请人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

发明人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C07D493/10

CPC分类号： B41M5/3275 ,  B41M5/1455 ,  C07D493/10

摘要： Disclosed are novel crystal of the fluoran compound represented by the formula ##STR1## , characterized by a specific X-ray diffraction diagram; preparation process thereof; and recording materials comprising the crystal.

公开(公告)号：US5087706A

公开(公告)日：1992-02-11

申请号：US584219

申请日：1990-09-18

申请人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

发明人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C07D493/10 ,  C09B11/28

CPC分类号： B41M5/1455 ,  B41M5/3275 ,  C07D493/10

摘要： Novel fluoran compounds represented by the formula (I): ##STR1## wherein R.sup.1 is an alkyl group having from 1 to 4 carbon atoms, preparation process of the fluoran compounds, and a heat-sensitive and a pressure-sensitive recording material comprising the fluoran compound, are disclosed.

公开(公告)号：US20100024683A1

公开(公告)日：2010-02-04

申请号：US12441468

申请日：2007-09-26

申请人： Masatoshi Takagi ,  Atsuo Otsuji ,  Akinori Nagatomo ,  Kouji Suesugi

发明人： Masatoshi Takagi ,  Atsuo Otsuji ,  Akinori Nagatomo ,  Kouji Suesugi

IPC分类号： A61K6/00 ,  C07F9/09

CPC分类号： C08F220/60 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/033 ,  A61K6/083 ,  C07F9/12 ,  C08L33/00

摘要： The invention provides a phosphate compound having an unsaturated double bond and a metal salt thereof; a dental material containing a phosphate compound having an unsaturated double bond and/or a metal salt thereof; and a dental composition containing a phosphate compound having an unsaturated double bond and/or a metal salt thereof. The phosphate compound of the invention provides a dental material and a dental composition such as a bonding material, adhesive material and a dental luting agent that are highly stable during storage, convenient for handling, and that exhibit higher adhesiveness and bond durability.

摘要翻译： 本发明提供具有不饱和双键的磷酸酯化合物及其金属盐; 含有具有不饱和双键的磷酸酯化合物和/或其金属盐的牙科材料; 以及含有具有不饱和双键的磷酸酯化合物和/或其金属盐的牙科用组合物。 本发明的磷酸盐化合物提供了一种牙科材料和一种牙科用组合物，例如粘合材料，粘合剂材料和牙科治疗剂，其在储存期间高度稳定，便于处理，并且表现出较高的粘合性和粘结耐久性。

公开(公告)号：US07534909B2

公开(公告)日：2009-05-19

申请号：US10557882

申请日：2004-05-21

申请人： Atsuo Otsuji ,  Masatoshi Takagi ,  Chojiro Higuchi ,  Akinori Nagatomo ,  Kouji Suesugi ,  Tetsuya Toida ,  Narimichi Honda

发明人： Atsuo Otsuji ,  Masatoshi Takagi ,  Chojiro Higuchi ,  Akinori Nagatomo ,  Kouji Suesugi ,  Tetsuya Toida ,  Narimichi Honda

IPC分类号： C07C69/54 ,  C07C43/23 ,  C07C69/63 ,  C07C323/20 ,  C08F20/30 ,  A61C13/087 ,  G02B1/04

CPC分类号： C08F22/105 ,  C07C69/54 ,  C07C317/22 ,  C07C323/20 ,  G02B1/04 ,  C08L33/14

摘要： A (meth)acrylic ester compound represented by the general formula (1) and a dental material containing the compound, wherein, in the formula, R11 represents a divalent aromatic group; R12 represents a hydrogen atom or a methyl group; R13 represents an aryl group; R14 represents a hydrogen atom or a methyl group; and X11, represents an oxygen atom or a sulfur atom. A polymerizable composition containing the (meth)acrylic ester compound and an optical part obtained by polymerizing the polymerizable composition are also provided. The cured composition can provide advantageous physical and optical properties.

摘要翻译： 由通式（1）表示的（甲基）丙烯酸酯化合物和含有该化合物的牙科材料，式中，R11表示二价芳香族基团; R12表示氢原子或甲基; R 13表示芳基; R14表示氢原子或甲基; X 11表示氧原子或硫原子。 还提供了含有（甲基）丙烯酸酯化合物和通过聚合可聚合组合物而获得的光学部件的可聚合组合物。 固化的组合物可以提供有利的物理和光学性质。

公开(公告)号：US5302571A

公开(公告)日：1994-04-12

申请号：US075935

申请日：1993-06-14

申请人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

发明人： Atsuo Otsuji ,  Masakatsu Nakatsuka ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C09B11/24 ,  B41M5/30

CPC分类号： C09B11/24 ,  B41M5/1455 ,  B41M5/3275

摘要： Disclosed are a crystal and crystalline solvate of a fluoran compound represented by the formula ##STR1## wherein R.sub.1 is ##STR2## and which are useful as chromogenic compounds in recording materials such as pressure-sensitive and heat-sensitive recording materials, a process for preparation of said crystal and said crystalline solvate, and recording materials comprising said crystal or said crystalline solvate.

摘要翻译： 公开了由下式表示的荧烷化合物的晶体和结晶溶剂化物，其中R1是，其可用作记录材料如压敏和热敏记录材料中的显色化合物， 所述晶体和所述结晶溶剂化物的制备方法，以及包含所述晶体或所述结晶溶剂合物的记录材料。

公开(公告)号：US5300473A

公开(公告)日：1994-04-05

申请号：US28911

申请日：1993-03-08

申请人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

发明人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Kazuyoshi Kikkawa ,  Akihiro Yamaguchi

IPC分类号： B41M5/145 ,  B41M5/327 ,  C09B11/24 ,  C09B67/48 ,  B41M5/30 ,  B41M5/32

CPC分类号： C09B67/0025 ,  B41M5/1455 ,  B41M5/3275 ,  C09B11/24

摘要： Disclosed are a crystal of a fluoran compound having the formula comprising exhibiting high peaks at diffraction angles (2.theta.) of 7.5.degree. and 17.0.degree. and relatively high peaks at diffraction angles (2.theta.) of 15.1.degree., 19.1.degree., 21.5.degree. and 25.3.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam and a crystal of a fluoran compound having the formula (II) comprising exhibiting high peaks at diffraction angles (2.theta.) of 5.5.degree. and 19.2.degree. in an X-ray diffraction diagram by the CU-K.alpha. beam, which is useful as a color forming compound in recording materials. ##STR1##

摘要翻译： 公开了具有以下通式的荧烷化合物的晶体，其包括在7.5度和17.0度的衍射角（2（θ））处呈现高峰，并且在15.1度，19.1度的衍射角（2（θ））处具有相对高的峰， 通过CU-K（α）光束在X射线衍射图中为21.5度和25.3度，并且具有式（II）的荧烷化合物的晶体包括在5.5度的衍射角（2（θ））处表现出高峰 在通过CU-K（α）光束的X射线衍射图中为19.2度，其可用作记录材料中的成色化合物。 （*化学结构*）（I）（*化学结构*）（II）

公开(公告)号：US5194632A

公开(公告)日：1993-03-16

申请号：US560909

申请日：1990-07-31

申请人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

发明人： Masakatsu Nakatsuka ,  Atsuo Otsuji ,  Kiyoharu Hasegawa ,  Masatoshi Takagi ,  Akihiro Yamaguchi

IPC分类号： B41M5/327 ,  C07D493/10

CPC分类号： B41M5/3275 ,  C07D493/10

摘要： Disclosed are a novel fluoran compound represented by the formula (I): ##STR1## and a heat-sensitive recording paper which is obtained by using the fluoran compound as a chromogenic compound and is excellent in preserving stability.