公开(公告)号：US4546200A

公开(公告)日：1985-10-08

申请号：US492277

申请日：1983-05-06

Applicant: Michael E. Sitzmann ,  Horst G. Adolph

Inventor： Michael E. Sitzmann ,  Horst G. Adolph

IPC: C07C205/15 ,  C07C69/52

CPC classification number: C07C205/15

Abstract: 2,2-Dinitrobutane-1,4-diol and 4-monoesters thereof.

Abstract translation: 2,2-二硝基丁烷-1,4-二醇及其4-单酯。

公开(公告)号：US4449000A

公开(公告)日：1984-05-15

申请号：US467714

申请日：1983-02-18

Applicant: Michael E. Sitzmann ,  William H. Gilligan

Inventor： Michael E. Sitzmann ,  William H. Gilligan

IPC: C06B25/00 ,  C07C205/29 ,  C07C79/343 ,  C07C76/02

CPC classification number: C07C205/29 ,  C06B25/00 ,  C07C323/00

Abstract: A 1:1:2 mixed orthocarbonate of the formula ##STR1## wherein R and R" are each one of the following groups--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,--CH.sub.2 C(NO.sub.2).sub.3,--CH.sub.2 CF(NO.sub.2).sub.2,--CH.sub.2 CF.sub.2 (NO.sub.2), and--CH.sub.2 CF.sub.3, andR' is one of the followingCH.sub.2 CF(NO.sub.2).sub.2,CH.sub.2 CF.sub.2 (NO.sub.2), andCH.sub.2 CF.sub.3,provided that R.noteq.R', R.noteq.R", and R'.noteq.R". These 1:1:2 orthoconates are produced by the following reaction sequence: ##STR2## wherein R, R', and R" are as defined above. By choosing R and R" to be the same and either --CH.sub.2 (NO.sub.2).sub.2 CH.sub.3 or --CH.sub.2 C(NO.sub.2).sub.3 in the above reaction, 1:3 mixed orthocarbonates of the formula ##STR3## wherein R.noteq.R', R".noteq.R', R=R", and R and R" are each CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3,CH.sub.2 C(NO.sub.2).sub.3,CH.sub.2 CF.sub.2 (NO.sub.2), orCH.sub.2 CF.sub.3,and R' is CH.sub.2 CF(NO.sub.2).sub.2, CH.sub.2 CF.sub.2 (NO.sub.2) or CH.sub.2 CF.sub.3 may be prepared.

Abstract translation: 其中R和R“分别为以下基团之一的-CH 2 C（NO 2）2 CH 3，-CH 2 C（NO 2）3，-CH 2 CF（NO 2）2，-CH 2 CF 2的1：1：2混合原碳酸酯 （NO 2）和-CH 2 CF 3，并且R'是以下CH 2 CF（NO 2）2，CH 2 CF 2（NO 2）和CH 2 CF 3之一，条件是R NOTEQUAL R'，R NOTEQUAL R“和R'NOTEQUAL R” 。 这些1：1：2原碳酸酯通过以下反应顺序产生：其中R，R'和R“如上所定义。 通过在上述反应中选择R和R“相同并且是-CH 2（NO 2）2 CH 3或-CH 2 C（NO 2）3，具有式”IMAGE“的1:3混合的原碳酸酯，其中R NOTEQUAL R'，R' “R”，R“和R”分别为CH 2 C（NO 2）2 CH 3，CH 2 C（NO 2）3，CH 2 CF 2（NO 2）或CH 2 CF 3，R'为CH 2 CF（NO 2）2， （NO 2）或CH 2 CF 3。