公开(公告)号：US4173591A

公开(公告)日：1979-11-06

申请号：US937281

申请日：1978-08-28

Applicant: William M. Koppes ,  Horst G. Adolph ,  Michael E. Sitzmann

Inventor： William M. Koppes ,  Horst G. Adolph ,  Michael E. Sitzmann

IPC: C07C205/12 ,  C07C79/12

CPC classification number: C07C201/08

Abstract: A process for producing 1,3,5-trifluoro-2,4,6-trinitrobenzene by:(1) forming a mixture of fuming sulfuric acid and potassium nitrate wherein the fuming sulfuric acid is composed of at least 25 percent by weight sulfur trioxide, and wherein the molar ratio of fuming sulfuric acid to potassium nitrate is from about 2:1 to about 3:1;(2) adding 1,3,5-trifluorobenzene to the mixture until the molar ratio of potassium nitrate to 1,3,5-trifluorobenzene is from 6:1 to 10:1, the temperature of the mixture being maintained in the range of from about 30.degree. C. to about 50.degree. C. during the addition;(3) then raising the temperature of the mixture into the range of from about 140.degree. C. to about 160.degree. C. where it is maintained until the optimum yield of 1,3,5-trifluoro-2,4,6-trinitrobenzene has been obtained; and(4) isolating the product, 1,3,5-trifluoro-2,4,6-trinitrobenzene from the reaction mixture.

Abstract translation: 通过以下方法制备1,3,5-三氟-2,4,6-三硝基苯的方法：（1）形成发烟硫酸和硝酸钾的混合物，其中发烟硫酸由至少25重量％的三氧化硫 ，其中发烟硫酸与硝酸钾的摩尔比为约2:1至约3:1; （2）向混合物中加入1,3,5-三氟苯直到硝酸钾与1,3,5-三氟苯的摩尔比为6:1至10:1，混合物的温度保持在 在加入期间约30℃至约50℃; （3）然后将混合物的温度升至约140℃至约160℃的范围，在此保持直到1,3,5-三氟-2,4,6-三硝基苯的最佳产率 已经获得; 和（4）从反应混合物中分离产物1,3,5-三氟-2,4,6-三硝基苯。

公开(公告)号：US06395112B1

公开(公告)日：2002-05-28

申请号：US09497874

申请日：2000-02-04

Applicant: Michael E. Sitzmann ,  Horst G. Adolph

Inventor： Michael E. Sitzmann ,  Horst G. Adolph

IPC: C06B4510

CPC classification number: C06B45/10 ,  C06B21/0091

Abstract: A degradable polymer has an ester component adjacent to a poly(oxyethylene) component in the polymer chain. The hydrophilic nature of the poly(oxyethylene) draws water close to the ester in the polymer chain, which increases the rate of hydrolysis of the ester. The degradable polymer is useful as a binder in for explosive and propellant compositions.

Abstract translation: 可降解聚合物在聚合物链中具有与聚（氧乙烯）组分相邻的酯组分。 聚（氧乙烯）的亲水性质吸收了聚合物链中靠近酯的水，这增加了酯的水解速率。 可降解聚合物可用作炸药和推进剂组合物中的粘合剂。

公开(公告)号：USH78H

公开(公告)日：1986-07-01

申请号：US492276

申请日：1983-05-06

Applicant: Horst G. Adolph ,  Michael E. Sitzmann

Inventor： Horst G. Adolph ,  Michael E. Sitzmann

IPC: C06B25/34 ,  C06B45/10 ,  C07C215/12 ,  C07C219/06 ,  C07C229/12 ,  C07C243/02 ,  C07C261/04

CPC classification number: C07C219/06 ,  C06B25/34 ,  C06B45/105 ,  C07C215/12 ,  C07C229/12 ,  C07C243/02 ,  C07C261/04

Abstract: Energetic diols of the formula ##STR1## wherein R is --H, --NO, --NO.sub.2, --CN, or --CH.sub.2 COOH, and diesters of the formula ##STR2## wherein R is --H, --NO, --NO.sub.2, --CN, --CH.sub.2 COOCH.sub.3, --CH.sub.2 COOCH.sub.2 C(NO.sub.2).sub.2 CH.sub.3, or --CH.sub.2 COOCH.sub.2 C(NO.sub.2).sub.3 and R' is an alkyl, fluoroalkyl, chloroalkyl, aryl, fluoroaryl, chloroalkyl, aralkyl, fluoroaralkyl, chloroaralkyl, or alkene group.

公开(公告)号：US06852182B1

公开(公告)日：2005-02-08

申请号：US09853927

申请日：2001-05-09

Applicant: Horst G. Adolph ,  Michael E. Sitzmann

Inventor： Horst G. Adolph ,  Michael E. Sitzmann

IPC: C06B45/10 ,  C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G18/00

CPC classification number: C08G18/4277 ,  C06B45/10 ,  C08G18/10 ,  C08G18/4833

Abstract: A degradable prepolymer for explosive and propellant compositions having increased hydrolyzability comprising at one —O—CH2—O— linkage within the backbone of the prepolymer. The degradable prepolymer is useful as a binder for explosive and propellant compositions.

Abstract translation: 用于具有增加的水解性的爆炸性和推进剂组合物的可降解预聚物，其包含预聚物主链内的一个-O-CH 2 -O-键。 可降解预聚物可用作爆炸剂和推进剂组合物的粘合剂。

公开(公告)号：USH644H

公开(公告)日：1989-06-06

申请号：US226335

申请日：1988-07-27

Applicant: Michael E. Sitzmann ,  Horst G. Adolph

Inventor： Michael E. Sitzmann ,  Horst G. Adolph

IPC: C07C205/28 ,  C07F7/18

CPC classification number: C07F7/188 ,  C07C201/12 ,  C07C205/28

Abstract: A process for preparing 2,2,2-trinitroethyl 2-nitroxyethyl ether by the fowing reaction sequence: ##STR1## 2,2,2-Trinitroethyl 2-nitroxyethyl ether is useful as an energetic plasticizer in propellants and explosives.

公开(公告)号：US4546200A

公开(公告)日：1985-10-08

申请号：US492277

申请日：1983-05-06

Applicant: Michael E. Sitzmann ,  Horst G. Adolph

Inventor： Michael E. Sitzmann ,  Horst G. Adolph

IPC: C07C205/15 ,  C07C69/52

CPC classification number: C07C205/15

Abstract: 2,2-Dinitrobutane-1,4-diol and 4-monoesters thereof.

Abstract translation: 2,2-二硝基丁烷-1,4-二醇及其4-单酯。

公开(公告)号：US4997499A

公开(公告)日：1991-03-05

申请号：US612838

申请日：1984-05-22

Applicant: Horst G. Adolph

Inventor： Horst G. Adolph

IPC: C06B45/10 ,  C07C205/29

CPC classification number: C07C205/29 ,  C06B45/105

Abstract: A new compound 2,2-dinitrobutyl 2,2-dinitropropyl formal (DNBPF),CH.sub.3 C(NO.sub.2).sub.2 CH.sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.sub.2 CH.sub.3,and a energetic plasticizer which is a 1:1 eutectic mixture of DNBPF and bis(2,2-dinitropropyl) formal.

Abstract translation: 新型化合物2,2-二硝基丁基2,2-二硝基丙基（DNBPF），CH 3 C（NO 2）2 CH 2 CH 2 OCH 2 OCH 2 C（NO 2）2 CH 3，以及能量增塑剂，其为DNBPF和双（2,2-二硝基丙基 ）正式。

公开(公告)号：US4988397A

公开(公告)日：1991-01-29

申请号：US892622

申请日：1986-04-30

Applicant: Horst G. Adolph ,  Judah Goldwasser ,  G. William Lawrence

Inventor： Horst G. Adolph ,  Judah Goldwasser ,  G. William Lawrence

IPC: C06B45/10 ,  C08G2/18 ,  C08G18/56

CPC classification number: C08G2/18 ,  C06B45/105 ,  C08G18/56

Abstract: An energetic uncured binder composite mixture comprising(1) a hydroxy-terminated polyfluoroformal prepolymer of the general formulaHOCH.sub.2 (CF.sub.2).sub.n CH.sub.2 [OCH.sub.2 OCH.sub.2 (CF.sub.2).sub.nH.sub.2 ].sub.m OH wherein n is 3 or 4 and m is selected to provide a number average molecular weight of from about 1,000 to about 10,000 for the prepolymer; and(2) an energetic plasticizer which isbis(2,2-dinitropropyl)formal,bis(2,2-trinitroethyl)formal,bis(2-fluoro-2,2-dinitroethyl)formal,bis(2,2-difluoro-2-nitroethyl)formal,2,2-dinitropropyl 2-fluoro-2,2-dinitroethyl formal, or mixtures thereof;wherein the weight ratio of energetic plasticizer to prepolymer is from about 2:1 to about 5:1. This binder composite mixture is useful for preparing energetic plastic bonded explosives having high chemical and thermal stabilities.

Abstract translation: 一种能量未固化的粘合剂复合材料混合物，其包含（1）通式为HOCH 2（CF 2）n CH 2 [OCH 2 OCH 2（CF 2）n CH 2] m OH的羟基封端的多氟代预聚物，其中n为3或4并且m被选择以提供数均分子量 对于预聚物为约1,000至约10,000; 和（2）能量增塑剂，其为双（2,2-二硝基丙基）甲醛，双（2,2-三硝基乙基）甲醛，双（2-氟-2,2-二硝基乙基）甲醛，双（2,2-二氟 -2-硝基乙基）甲醛，2,2-二硝基丙基2-氟-2,2-二硝基乙基甲醛或其混合物; 其中能量增塑剂与预聚物的重量比为约2:1至约5:1。 该粘合剂复合混合物可用于制备具有高化学和热稳定性的高能塑料粘结炸药。

公开(公告)号：USH351H

公开(公告)日：1987-10-06

申请号：US43269

申请日：1987-04-27

Applicant: Kyung E. Kim ,  Horst G. Adolph

Inventor： Kyung E. Kim ,  Horst G. Adolph

IPC: C06B45/10 ,  C07C205/29 ,  C07C205/51 ,  C08G18/56 ,  C08G65/34

CPC classification number: C08G18/56 ,  C06B45/105 ,  C07C205/29 ,  C07C205/51 ,  C08G65/34

Abstract: 4,4,10,10-tetranitro-6,8-dioxatridecane-1,13-diol polyformal, HO(CH.sub.2ub.3 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 (CH.sub.2).sub.3 O[CH.sub.2 O(CH.sub.2).sub.3 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 (CH.sub.2).sub.3 O].sub.n H, which has high energy, high thermal stability, and which is useful as a prepolymer for plastic-bonded explosive compositions.

公开(公告)号：US4593110A

公开(公告)日：1986-06-03

申请号：US752704

申请日：1985-07-08

Applicant: Judah M. Goldwasser ,  Horst G. Adolph ,  Cynthia L. Ebner

Inventor： Judah M. Goldwasser ,  Horst G. Adolph ,  Cynthia L. Ebner

IPC: C07D321/12

CPC classification number: C07D321/12

Abstract: One mole of 2,2,3,3,4,4-hexafluoropentane-1,5-diol is reacted with one molef formaldehyde in the presence of an excess of trifluoromethanesulfonic acid to produce 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane.

Abstract translation: 在过量的三氟甲磺酸存在下，将1摩尔的2,2,3,3,4,4-六氟戊烷-1,5-二醇与1摩尔甲醛反应，得到1,3-二氧杂-5,5， 6,6,7,7-六氟环辛烷。